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US6200847B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Method of manufacturing capacitor of semiconductor device

Assignee: Oki Electric Industry Co Ltd
•
Filing: 1997-12-03
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Granted: 2001-03-13
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Expires: 2017-12-03
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Abstract

Abstract A method of manufacturing a capacitor of a semiconductor device, according to the present invention comprises the steps of heat-treating a Ta 2 O 5 film formed on a metal or metal oxide electrode corresponding to a lower electrode of the capacitor at a temperature lower than a temperature at which the Ta 2 O 5 film is crystallized, and thereafter heat-treating the Ta 2 O 5 film at a temperature higher than or equal to the crystallizing temperature of the Ta 2 O 5 film.

Inventors

  • 👤 Koichi Kishiro

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 01:16
CPC Classifications
H; H10; H10D; H10D1/00; H10D1/60; H10D1/68; H10P; H10P14/00; H10P14/60; H10P14/65; H10P14/6516; H10P14/6529; H10B; H10B12/00; H10B12/01; H10B12/02; H10B12/03; H10B12/033; H10B12/0335; H10P14/6544; H10P14/69; H10P14/692; H10P14/6938; H10P14/6939; H10P14/69393; H10P95/00

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 125 words
A method of manufacturing a capacitor of a semiconductor device, comprising: forming a metal or metal oxide electrode over a semiconductor substrate; forming a Ta 2 O 5 film on the metal or metal oxide electrode; heat-treating the Ta 2 O 5 film at a temperature lower than a crystallizing temperature of the Ta 2 O 5 film to compensate for oxygen deficiencies and remove impurities; and heat-treating the Ta 2 O 5 film having been subjected to said heat-treating at the temperature lower than the crystallizing temperature of the Ta 2 O 5 film at a temperature higher than or equal to the crystallizing temperature of the Ta 2 O 5 film after said heat-treating step to crystallize the Ta 2 O 5 film.
Claim 2
Independent Claim 125 words
A method of manufacturing a capacitor of a semiconductor device, comprising: forming a metal or metal oxide electrode over a semiconductor substrate; forming a Ta 2 O 5 film on the metal or metal oxide electrode; heat-treating the Ta 2 O 5 film at a temperature lower than a crystallizing temperature of the Ta 2 O 5 film to compensate for oxygen deficiencies and remove impurities; and heat-treating the Ta 2 O 5 film having been subjected to said heat-treating at the temperature lower than the crystallizing temperature of the Ta 2 O 5 film at a temperature higher than or equal to the crystallizing temperature of the Ta 2 O 5 film after said heat-treating step to crystallize the Ta 2 O 5 film.
Claim 3
Dependent Claim 38 words
A method according to claim 1 , wherein said heat-treating the Ta 2 O 5 film at the temperature lower than the crystallizing temperature of the Ta 2 O 5 film is carried out in an oxidative atmosphere.
Claim 4
Dependent Claim 39 words
A method according to claim 2 , wherein said heat-treating the Ta 2 O 5 film at the temperature higher than or equal to the crystallizing temperature of the Ta 2 O 5 film is a rapid heat-treating step.
Claim 5
Dependent Claim 56 words
A method according to claim 1 , wherein said heat-treating the Ta 2 O 5 film at the temperature higher than or equal to the crystallizing temperature of the Ta 2 O 5 film is carried out through a diffusion furnace so as to obtain the Ta 2 O 5 film having less crystal grain boundary.
Claim 6
Dependent Claim 44 words
A method according to claim 1 , wherein said heat-treating the Ta 2 O 5 film at the temperature lower than the crystallizing temperature of the Ta 2 O 5 film is carried out in an atmosphere of O 3 or N 2 O.
Claim 7
Dependent Claim 44 words
A method according to claim 1 , wherein said heat-treating the Ta 2 O 5 film at the temperature lower than the crystallizing temperature of the Ta 2 O 5 film is carried out in an oxidative atmosphere activated by light or plasma excitation.
Claim 8
Dependent Claim 25 words
A method according to claim 1 , wherein said heat treating at the temperature lower than the crystallizing temperature does not include rapid thermal annealing.
Claim 9
Dependent Claim 30 words
A method according to claim 1 , wherein said heat treating at the temperature lower than the crystallizing temperature produces substantially no crystallization of the Ta 2 O 5 .
Claim 10
Independent Claim 117 words
A method of manufacturing a capacitor of a semiconductor device, comprising: forming a metal or metal oxide electrode over a semiconductor substrate; forming a Ta 2 O 5 film on the metal or metal oxide electrode; heat-treating the Ta 2 O 5 film at a temperature lower than a crystallizing temperature of the Ta 2 O 5 film; and heat-treating the Ta 2 O 5 film having been subjected to said heat-treating at the temperature lower than the crystallizing temperature of the Ta 2 O 5 film at a temperature higher than or equal to the crystallizing temperature of the Ta 2 O 5 film after said heat-treating step to crystallize the Ta 2 O 5 film.
Claim 11
Independent Claim 117 words
A method of manufacturing a capacitor of a semiconductor device, comprising: forming a metal or metal oxide electrode over a semiconductor substrate; forming a Ta 2 O 5 film on the metal or metal oxide electrode; heat-treating the Ta 2 O 5 film at a temperature lower than a crystallizing temperature of the Ta 2 O 5 film; and heat-treating the Ta 2 O 5 film having been subjected to said heat-treating at the temperature lower than the crystallizing temperature of the Ta 2 O 5 film at a temperature higher than or equal to the crystallizing temperature of the Ta 2 O 5 film after said heat-treating step to crystallize the Ta 2 O 5 film.
Claim 12
Dependent Claim 38 words
A method according to claim 9 , wherein said heat-treating the Ta 2 O 5 film at the temperature lower than the crystallizing temperature of the Ta 2 O 5 film is carried out in an oxidative atmosphere.
Claim 13
Dependent Claim 39 words
A method according to claim 9 , wherein said heat-treating the Ta 2 O 5 film at the temperature higher than or equal to the crystallizing temperature of the Ta 2 O 5 film is a rapid heat-treating step.
Claim 14
Dependent Claim 56 words
A method according to claim 9 , wherein said heat-treating the Ta 2 O 5 film at the temperature higher than or equal to the crystallizing temperature of the Ta 2 O 5 film is carried out through a diffusion furnace so as to obtain the Ta 2 O 5 film having less crystal grain boundary.
Claim 15
Dependent Claim 44 words
A method according to claim 9 , wherein said heat-treating the Ta 2 O 5 film at the temperature lower than the crystallizing temperature of the Ta 2 O 5 film is carried out in an atmosphere of O 3 or N 2 O.
Claim 16
Dependent Claim 44 words
A method according to claim 9 , wherein said heat-treating the Ta 2 O 5 film at the temperature lower than the crystallizing temperature of the Ta 2 O 5 film is carried out in an oxidative atmosphere activated by light or plasma excitation.
Claim 17
Dependent Claim 25 words
A method according to claim 9 , wherein said heat treating at the temperature lower than the crystallizing temperature does not include rapid thermal annealing.
Claim 18
Dependent Claim 30 words
A method according to claim 9 , wherein said heat treating at the temperature lower than the crystallizing temperature produces substantially no crystallization of the Ta 2 O 5 film.

References Cited (Backward Citations)

US5079191A Cited
US5508221A Cited
US5726083A Cited
US5663088A Cited
US5837593A Cited
US5851841A Cited
US6010927A Cited

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