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US6180328B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic element for color imaging

Assignee: Eastman Kodak Co
•
Filing: 1999-12-28
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Granted: 2001-01-30
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Expires: 2019-12-28
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Abstract

Abstract Disclosed is a color photographic element comprising at least five imaging layers including: a first light sensitive silver halide imaging layer having associated therewith a cyan image dye-forming coupler; a second light sensitive silver halide imaging layer having associated therewith a magenta image dye-forming coupler; a third light sensitive silver halide imaging layer having associated therewith a yellow image dye-forming coupler; and a fourth light sensitive silver halide imaging layer having associated therewith a fourth image dye-forming coupler for which the normalized spectral transmission density distribution curve of the dye formed by the fourth image dye-forming coupler upon reaction with color developer has a CIELAB hue angle, h ab , from 225 to 310°; and a fifth light sensitive silver halide imaging layer having associated therewith a fifth image dye-forming coupler for which the normalized spectral transmission density distribution curve of the dye formed by the fifth image dye-forming coupler upon reaction with color developer has a CIELAB hue angle, h ab , from not less than 355 to not more than 75°. Such an element enables an increase in the color gamut for silver halide imaging.

Inventors

  • 👤 James L. Edwards
  • 👤 William J. Begley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 14:38
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/3029; G03C7/3041; G03C1/00; G03C1/005; G03C1/035; G03C2001/03517; G03C2001/03541; G03C2001/0357; G03C1/06; G03C1/08; G03C1/09; G03C2001/091; G03C2001/093; G03C2001/095; G03C2200/00; G03C2200/19; G03C2200/20; G03C7/3022

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 171 words
A color photographic element comprising at least five imaging layers including: a first light sensitive silver halide imaging layer having associated therewith a cyan image dye-forming coupler; a second light sensitive silver halide imaging layer having associated therewith a magenta image dye-forming coupler; a third light sensitive silver halide imaging layer having associated therewith a yellow image dye-forming coupler; and a fourth light sensitive silver halide imaging layer having associated therewith a fourth image dye-forming coupler for which the normalized spectral transmission density distribution curve of the dye formed by the fourth image dye-forming coupler upon reaction with color developer has a CIELAB hue angle, h ab , from 225 to 310°; and a fifth light sensitive silver halide imaging layer having associated therewith a fifth image dye-forming coupler for which the normalized spectral transmission density distribution curve of the dye formed by the fifth image dye-forming coupler upon reaction with color developer has a CIELAB hue angle, h ab , from not less than 355 to not more than 75°.
Claim 2
Dependent Claim 171 words
A color photographic element comprising at least five imaging layers including: a first light sensitive silver halide imaging layer having associated therewith a cyan image dye-forming coupler; a second light sensitive silver halide imaging layer having associated therewith a magenta image dye-forming coupler; a third light sensitive silver halide imaging layer having associated therewith a yellow image dye-forming coupler; and a fourth light sensitive silver halide imaging layer having associated therewith a fourth image dye-forming coupler for which the normalized spectral transmission density distribution curve of the dye formed by the fourth image dye-forming coupler upon reaction with color developer has a CIELAB hue angle, h ab , from 225 to 310°; and a fifth light sensitive silver halide imaging layer having associated therewith a fifth image dye-forming coupler for which the normalized spectral transmission density distribution curve of the dye formed by the fifth image dye-forming coupler upon reaction with color developer has a CIELAB hue angle, h ab , from not less than 355 to not more than 75°.
Claim 3
Dependent Claim 31 words
The element of claim 1 wherein the wavelength of maximum spectral sensitivity for the silver halide emulsions in the at least five imaging layers are separated by at least 30 nm.
Claim 4
Dependent Claim 23 words
The element of claim 1 wherein the hue angle of the dye formed by the fourth dye-forming coupler is from 228 to 305°.
Claim 5
Dependent Claim 23 words
The element of claim 1 wherein the hue angle of the dye formed by the fourth dye-forming coupler is from 230 to 290°.
Claim 6
Dependent Claim 23 words
The element of claim 1 wherein the hue angle of the dye formed by the fifth dye-forming coupler is from 5 to 75°.
Claim 7
Dependent Claim 23 words
The element of claim 1 wherein the hue angle of the dye formed by the fifth dye-forming coupler is from 15 to 75°.
Claim 8
Dependent Claim 23 words
The element of claim 4 wherein the hue angle of the dye formed by the fourth dye-forming coupler is from 25 to 45°.
Claim 9
Dependent Claim 26 words
The element of claim 1 wherein the fourth or fifth light sensitive silver halide emulsion layer is located below all of the other light sensitive layers.
Claim 10
Dependent Claim 21 words
The element of claim 1 wherein the fourth light sensitive layer is located above all of the other light sensitive layers.
Claim 11
Dependent Claim 32 words
The element of claim 1 wherein the fourth or fifth light sensitive layer is located above one of the other light sensitive layers and below another of the other light sensitive layers.
Claim 12
Dependent Claim 26 words
The element of claim 1 wherein there is a non-light sensitive layer between the fourth or fifth light sensitive layer and any adjacent light sensitive layer.
Claim 13
Dependent Claim 38 words
The element of claim 2 wherein the fourth and fifth light sensitive layers have a maximum spectral sensitivity that is at least 30 nm away from the maximum spectral sensitivity of any of the other light sensitive layers.
Claim 14
Dependent Claim 24 words
The element of claim 1 wherein the fourth or fifth light sensitive layer has a maximum spectral sensitivity that is greater than 700 nm.
Claim 15
Dependent Claim 24 words
The element of claim 1 wherein the fourth or fifth light sensitive layer has a maximum spectral sensitivity that is greater than 720 nm.
Claim 16
Dependent Claim 24 words
The element of claim 1 wherein the fourth or fifth light sensitive layer has a maximum spectral sensitivity of from 590 to 640 nm.
Claim 17
Dependent Claim 24 words
The element of claim 1 wherein the fourth or fifth light sensitive layer has a maximum spectral sensitivity of from 400 to 460 nm.
Claim 18
Dependent Claim 22 words
The element of claim 1 wherein at least one of the fourth and fifth couplers is an azole, anilide, or phenolic coupler.
Claim 19
Dependent Claim 10 words
The element of claim 1 additionally comprising a reflective support.
Claim 20
Dependent Claim 10 words
The element of claim 1 additionally comprising a transparent support.
Claim 21
Dependent Claim 17 words
The element of claim 1 packaged with instructions to process using a color negative print developing process.
Claim 22
Dependent Claim 12 words
The element of claim 1 wherein the element is a direct-view element.
Claim 23
Dependent Claim 31 words
A process for forming an image in an element as described in claim 1 after the element has been imagewise exposed to light comprising contacting the element with a color-developing compound.
Claim 24
Dependent Claim 14 words
The process of claim 22 in which the developer is a p-phenylene diamine compound.
Claim 25
Dependent Claim 27 words
The element of claim 1 wherein the emulsions in the element are comprised of 3-dimensional silver chloride emulsions, which are predominantly greater than 95 M% silver chloride.
Claim 26
Dependent Claim 11 words
The element of claim 1 wherein the emulsions are predominantly monodisperse.
Claim 27
Dependent Claim 23 words
The element of claim 1 wherein the grain sizes of the emulsions are between 0.05 u and 0.95 u in cubic edge length.
Claim 28
Dependent Claim 17 words
The element of claim 1 wherein at least one of the emulsions of the element contains iridium.
Claim 29
Dependent Claim 13 words
The element of claim 1 wherein the emulsions are sulfur and gold sensitized.

References Cited (Backward Citations)

US4705745A Cited
US4816378A Cited
US4746599A Cited
EP0825488A1 Cited
EP0915374A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2004-01-30 2004-07-31 2005-01-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2008-01-30 2008-07-31 2009-01-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2012-01-30 2012-07-31 2013-01-30 $7700.00 Window Closed / Lapsed

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