US6133355A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Selective deposition modeling materials and method
Assignee: 3D Systems Inc
•
Filing: 1997-06-12
•
Granted: 2000-10-17
•
Expires: 2017-06-12
Abstract
Abstract A novel thermopolymer material adapted for use in thermal stereolithography. More particularly, a thermopolymer material comprising a mixture of: a low shrinkage polymer resin; a low viscosity material such as paraffin wax; at least one microcrystalline wax; a toughening polymer; a plasticizer. Alternative embodiments further include components to improve the materials ability to transfer heat and to improve strength. The subject material, together with the described process greatly reduce part building distortions while retaining desirable toughness, strength and jetting properties.
Inventors
- 👤 Richard N. Leyden
- 👤 Charles W. Hull
- 👤 Dinh Ton That
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 11:07
CPC Classifications
B; B29; B29C; B29C64/00; B29C64/10; B29C64/106; B29C64/112; B33; B33Y; B33Y10/00; B33Y70/00
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
149 words
A material for use in selective deposition modeling by jetting from an ink jet print head to build a three-dimensional object in layerwise fashion comprising a mixture of: a) between about 20 and 45% by weight of paraffin wax; b) between about 20 and 50% by weight of a hydrocarbon resin, wherein the hydrocarbon resin is a copolymer of α-methylstyrene and vinyl toluene; c) between about 10 and 30% by weight of microcrystalline wax selected from the group consisting of a microcrystalline ester wax, a soft microcrystalline wax, a hard microcrystalline wax and mixtures thereof; and d) between about 2 and 5% by weight of an ethylene-vinyl acetate copolymer, wherein each % by weight is based on the total weight of the mixture, and wherein the material has a viscosity between about 7 and about 30 centipoise at at least one temperature between about 125 and about 135° C.
Claim 2
Dependent Claim
149 words
A material for use in selective deposition modeling by jetting from an ink jet print head to build a three-dimensional object in layerwise fashion comprising a mixture of: a) between about 20 and 45% by weight of paraffin wax; b) between about 20 and 50% by weight of a hydrocarbon resin, wherein the hydrocarbon resin is a copolymer of α-methylstyrene and vinyl toluene; c) between about 10 and 30% by weight of microcrystalline wax selected from the group consisting of a microcrystalline ester wax, a soft microcrystalline wax, a hard microcrystalline wax and mixtures thereof; and d) between about 2 and 5% by weight of an ethylene-vinyl acetate copolymer, wherein each % by weight is based on the total weight of the mixture, and wherein the material has a viscosity between about 7 and about 30 centipoise at at least one temperature between about 125 and about 135° C.
Claim 3
Dependent Claim
32 words
The material of claim 1 for use in selective deposition modeling configured to have a viscosity of between about 18 and 25 centipoise at a temperature between about 125 and 130° C.
Claim 4
Dependent Claim
24 words
The material of claim 2 for use in selective deposition modeling configured to have a surface tension of between about 24 and 29 dyne/cm.
Claim 5
Dependent Claim
31 words
The material of claim 2 for use in selective deposition modeling configured to have a volumetric shrinkage of less than 11% when cooling from between about 125 and about 130° C.
Claim 6
Dependent Claim
44 words
The material of claim 2 for use in selective deposition modeling wherein said at least one microcrystalline wax comprises between 10 and 15% w microcrystalline ester wax, between 5 and 20% w soft microcrystalline wax, and between 5 and 10% w hard microcrystalline wax.
Claim 7
Dependent Claim
20 words
The material of claim 6 for use in selective deposition modeling further comprising up to 4% w of an antioxidant.
Claim 8
Dependent Claim
44 words
The material of claim 6 for use in selective deposition modeling wherein said at least one microcrystalline wax comprises about 12% w of a microcrystalline ester wax; about 5% w of a hard microcrystalline wax; and about 5% w of a soft microcrystalline wax.
Claim 9
Dependent Claim
21 words
The material of claim 6 for use in selective deposition modeling further comprising between about 1 and 5% w of dioctylterephthalate.
Claim 10
Dependent Claim
22 words
The material of claim 6 for use in selective deposition modeling further comprising between about 1 and 5% w of diisononyl phthalate.
Claim 11
Dependent Claim
30 words
The material of claim 1 or use in selective deposition modeling wherein the material has a shrinkage of about 11% or less when cooled from 130° C. to 25° C.
Claim 12
Dependent Claim
31 words
The material of claim 1 for use in selective deposition modeling wherein it is dispensed into an environment which is within about 10° C. of the solidifying temperature of the material.
Claim 13
Dependent Claim
33 words
The material of claim 1 for use in selective deposition modeling having a viscosity between about 18 and about 25 centipoise at at least one temperature between about 125 and about 130° C.
Claim 14
Dependent Claim
31 words
The material of claim 1 for use in selective deposition modeling wherein the material transforms from a liquid to a solid over a temperature range of more than about 10° C.
Claim 15
Dependent Claim
16 words
The material of claim 1 for use in selective deposition modeling additionally comprising a coloring agent.
Claim 16
Dependent Claim
21 words
The material of claim 14 for use in selective deposition modeling comprising up to about 2.0% w of the coloring agent.
Claim 17
Dependent Claim
30 words
The material of claim 1 wherein the ethylene-vinyl acetate copolymer has a viscosity of about 575 centipoise at 140° C. and a melting point of between 85 and 95° C.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2003-10-17 | 2004-04-17 | 2004-10-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2007-10-17 | 2008-04-17 | 2008-10-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2011-10-17 | 2012-04-17 | 2012-10-17 | $7700.00 | Window Closed / Lapsed |