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US6130166A Expired / Lapsed US ⏱️ 0.0 years remaining

Alternative plasma chemistry for enhanced photoresist removal

Assignee: United Microelectronics Corp
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Filing: 1999-02-01
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Granted: 2000-10-10
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Expires: 2019-02-01
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Abstract

Abstract A CF 4 /H 2 O 2 plasma is used to remove residues remaining after an ashing step. On a substrate, a layer of photoresist is formed over an underlying layer. The layer of photoresist is developed to form a photoresist pattern. The underlying layer is etched using the photoresist pattern. The substrate, including exposed areas of the underlying layer, are subjected to a plasma comprising H 2 O 2 vapor and a gaseous fluorocarbon to remove residual polymers.

Inventors

  • 👤 Edward Yeh

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 08:43
CPC Classifications
H; H10; H10P; H10P70/00; H10P70/20; H10P70/23; H10P70/234; G; G03; G03F; G03F7/00; G03F7/26; G03F7/42; G03F7/427; H10P50/00; H10P50/20; H10P50/28; H10P50/286; H10P50/287; H10W; H10W10/00; H10W10/01; H10W10/011; H10W10/014; H10W10/10; H10W10/17

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 77 words
A method for use when processing integrated circuitry comprising the following steps: (a) on a substrate, forming a layer of photoresist over an underlying layer; (b) developing the layer of photoresist to form a photoresist pattern; (c) etching the underlying layer using the photoresist pattern; and, (d) subjecting the substrate including exposed portions of the underlying layer to a plasma comprising hydrogen peroxide (H 2 O 2 ) vapor and a gaseous fluorocarbon to remove residual polymers.
Claim 2
Independent Claim 77 words
A method for use when processing integrated circuitry comprising the following steps: (a) on a substrate, forming a layer of photoresist over an underlying layer; (b) developing the layer of photoresist to form a photoresist pattern; (c) etching the underlying layer using the photoresist pattern; and, (d) subjecting the substrate including exposed portions of the underlying layer to a plasma comprising hydrogen peroxide (H 2 O 2 ) vapor and a gaseous fluorocarbon to remove residual polymers.
Claim 3
Dependent Claim 33 words
A method as in claim 1 wherein step (d) comprises the steps of: (d.1) introducing CF 4 into an ashing environment; and, (d.2) introducing H 2 O 2 vapor into the ashing environment.
Claim 4
Dependent Claim 17 words
A method as in claim 1, wherein in step (d) the gaseous fluorocarbon is CF 4 .
Claim 5
Dependent Claim 24 words
A method as in claim 1, wherein in step (d) the plasma comprises another oxygenated species in addition to H 2 O 2 vapor.
Claim 6
Dependent Claim 18 words
A method as in claim 4, wherein in step (d) the other oxygenated species is O 2 .
Claim 7
Dependent Claim 18 words
A method as in claim 4 wherein in step (d), the other oxygenated species is H 2 O.
Claim 8
Dependent Claim 29 words
A method as in claim 1, wherein in step (d) the plasma does not include significant amounts of an oxygenated species in addition to H 2 O 2 vapor.
Claim 9
Independent Claim 87 words
A method for forming an isolation structure on an integrated circuit using shallow trench isolation comprising the following steps: (a) forming a nitride mask to define a trench area on a substrate of the integrated circuit; (b) subjecting the substrate including the trench area to a plasma comprising hydrogen peroxide (H 2 O 2 ) vapor, and one of a gaseous fluorocarbon or a fluorinated hydrocarbon gas to clean impurities on the trench area; and, (c) etching the substrate to form a trench within the trench area.
Claim 10
Independent Claim 87 words
A method for forming an isolation structure on an integrated circuit using shallow trench isolation comprising the following steps: (a) forming a nitride mask to define a trench area on a substrate of the integrated circuit; (b) subjecting the substrate including the trench area to a plasma comprising hydrogen peroxide (H 2 O 2 ) vapor, and one of a gaseous fluorocarbon or a fluorinated hydrocarbon gas to clean impurities on the trench area; and, (c) etching the substrate to form a trench within the trench area.
Claim 11
Dependent Claim 17 words
A method as in claim 8, wherein in step (b) the gaseous fluorocarbon is CF 4 .
Claim 12
Dependent Claim 24 words
A method as in claim 8, wherein in step (b) the plasma comprises another oxygenated species in addition to H 2 O 2 vapor.
Claim 13
Dependent Claim 18 words
A method as in claim 10, wherein in step (b) the other oxygenated species is O 2 .
Claim 14
Dependent Claim 18 words
A method as in claim 10, wherein in step (b), the other oxygenated species is H 2 O.
Claim 15
Dependent Claim 41 words
A method as in claim 8 additionally comprising the following step: (d) subjecting the trench to a plasma comprising H 2 O 2 vapor, and one of a gaseous fluorocarbon or a fluorinated hydrocarbon gas to clean impurities within the trench.
Claim 16
Independent Claim 89 words
A method for forming a via contact hole in a semiconductor device comprising the following steps: (a) forming a metal layer on a wafer; (b) forming a dielectric layer on the metal layer; (c) forming a photoresist layer on the dielectric layer; (d) patterning the photoresist layer; (e) forming a via contact hole by an etching process which uses the photoresist as a pattern; and, (f) subjecting the substrate to a plasma comprising hydrogen peroxide (H 2 O 2 ) vapor and a gaseous fluorocarbon to remove residual polymers.
Claim 17
Independent Claim 89 words
A method for forming a via contact hole in a semiconductor device comprising the following steps: (a) forming a metal layer on a wafer; (b) forming a dielectric layer on the metal layer; (c) forming a photoresist layer on the dielectric layer; (d) patterning the photoresist layer; (e) forming a via contact hole by an etching process which uses the photoresist as a pattern; and, (f) subjecting the substrate to a plasma comprising hydrogen peroxide (H 2 O 2 ) vapor and a gaseous fluorocarbon to remove residual polymers.
Claim 18
Dependent Claim 33 words
A method as in claim 14 wherein step (f) comprises the steps of: (f.1) introducing CF 4 into an ashing environment; and, (f.2) introducing H 2 O 2 vapor into the ashing environment.
Claim 19
Dependent Claim 17 words
A method as in claim 14, wherein in step (f) the gaseous fluorocarbon is CF 4 .
Claim 20
Dependent Claim 24 words
A method as in claim 14, wherein in step (f) the plasma comprises another oxygenated species in addition to H 2 O 2 vapor.
Claim 21
Dependent Claim 25 words
A method as in claim 17, wherein in step (f), the other oxygenated species includes one of the following: O 2 , H 2 O.
Claim 22
Dependent Claim 29 words
A method as in claim 14, wherein in step (f) the plasma does not include significant amounts of an oxygenated species in addition to H 2 O 2 vapor.

References Cited (Backward Citations)

US5356478A Cited
US5647953A Cited
US5851302A Cited
US5925577A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
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