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US6107364A Expired / Lapsed US ⏱️ 0.0 years remaining

Methyl styrene as a high index of refraction monomer

Assignee: 3M Innovative Properties Co
•
Filing: 1997-05-09
•
Granted: 2000-08-22
•
Expires: 2017-05-09
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Abstract

Abstract Described are a polymerizable composition comprising methyl styrene monomer, polymers comprising monomeric units derived from methyl styrene monomers, and optical products comprising these polymers.

Inventors

  • 👤 Bettie C. Fong
  • 👤 David B. Olson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 17:28
CPC Classifications
C; C08; C08F; C08F212/00; C08F212/02; C08F212/04; C08F212/06; C08F212/12; C08L; C08L25/00; C08L25/02; C08L25/16; G; G02; G02B; G02B1/00; G02B1/04; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24628; Y10T428/24636; Y10T428/24645

Claims Analysis

Total Claims: 37
Claim 1
Independent Claim 25 words
A polymerizable composition comprising methyl styrene monomer of the general formula: ##STR17## one or more comonomers comprising at least one high index of refraction comonomer.
Claim 2
Dependent Claim 25 words
A polymerizable composition comprising methyl styrene monomer of the general formula: ##STR17## one or more comonomers comprising at least one high index of refraction comonomer.
Claim 3
Dependent Claim 21 words
The composition of claim 1, wherein the high index of refraction comonomer has an index of refraction of at least 1.50.
Claim 4
Dependent Claim 13 words
The composition of claim 1, wherein the comonomers comprise an unsaturated aromatic comonomer.
Claim 5
Dependent Claim 12 words
The composition of claim 1, wherein the comonomers comprise a (meth)acrylate monomer.
Claim 6
Dependent Claim 12 words
The composition of claim 1, wherein the comonomers comprise a brominated comonomer.
Claim 7
Dependent Claim 13 words
The composition of claim 1, wherein the comonomers comprise a brominated (meth)acrylate comonomer.
Claim 8
Dependent Claim 16 words
The composition of claim 1, wherein the comonomers comprise an alkyl-substituted brominated aromatic ester (meth)acrylate monomer.
Claim 9
Dependent Claim 46 words
The composition of claim 7, wherein the brominated aromatic (meth)acrylate comonomer comprises monomer of the general formula: ##STR18## wherein R can be hydrogen or methyl, R A can be a straight or branched alkyl, and x can be in the range from about 1 to 4.
Claim 10
Dependent Claim 27 words
The composition of claim 1, wherein the polymerizable composition comprises from about 5 to 15 parts by weight methyl styrene monomer, based on 100 parts polymerizable composition.
Claim 11
Dependent Claim 25 words
The composition of claim 1, comprising: from 5 to 40 parts by weight methyl styrene monomer; and from 60 to 95 parts by weight comonomer.
Claim 12
Dependent Claim 38 words
The composition of claim 1, comprising: from 5 to 25 parts by weight methyl styrene monomer; from 10 to 15 parts by weight non-halogenated (meth)acrylate monomer; and from 65 to 80 parts by weight brominated aromatic (meth)acrylate monomer.
Claim 13
Dependent Claim 25 words
A polymerizable composition comprising methyl styrene monomer of the general formula: ##STR19## wherein the polymerizable composition has an index of refraction of at least 1.55.
Claim 14
Dependent Claim 25 words
A polymerizable composition comprising methyl styrene monomer of the general formula: ##STR19## wherein the polymerizable composition has an index of refraction of at least 1.55.
Claim 15
Dependent Claim 15 words
The polymerizable composition of claim 12, wherein the index of refraction is at least 1.56.
Claim 16
Dependent Claim 20 words
An optical product comprising a polymeric material comprising monomeric units derived from methyl styrene monomer of the general formula: ##STR20##
Claim 17
Dependent Claim 20 words
An optical product comprising a polymeric material comprising monomeric units derived from methyl styrene monomer of the general formula: ##STR20##
Claim 18
Dependent Claim 22 words
The optical product of claim 14, wherein the polymeric material comprises monomeric units further derived from a high index of refraction comonomer.
Claim 19
Dependent Claim 22 words
The optical product of claim 15, wherein the high index of refraction monomer has an index of refraction of at least 1.50.
Claim 20
Dependent Claim 14 words
The optical product of claim 15, wherein the comonomer comprises an unsaturated aromatic comonomer.
Claim 21
Dependent Claim 13 words
The optical product of claim 15, wherein the comonomer comprises a (meth)acrylate monomer.
Claim 22
Dependent Claim 13 words
The optical product of claim 15, wherein the comonomer comprises a brominated comonomer.
Claim 23
Dependent Claim 14 words
The optical product of claim 15, wherein the comonomer comprises a brominated (meth)acrylate comonomer.
Claim 24
Dependent Claim 17 words
The optical product of claim 15, wherein the comonomers comprise an alkyl-substituted brominated aromatic ester (meth)acrylate monomer.
Claim 25
Dependent Claim 46 words
The optical product of claim 21, wherein the brominated aromatic (meth)acrylate comonomer comprises monomer of the general formula: wherein R can be hydrogen or methyl, R A can be a straight or branched alkyl, and x can be in the range from about 1 to 4.
Claim 26
Dependent Claim 28 words
The optical product of claim 15, wherein the polymerizable composition comprises from about 5 to 15 parts by weight methyl styrene monomer, based on 100 parts polymerizable composition.
Claim 27
Dependent Claim 26 words
The optical product of claim 14, comprising: from 5 to 40 parts by weight methyl styrene monomer; and from 60 to 95 parts by weight comonomer.
Claim 28
Dependent Claim 39 words
The optical product of claim 14, comprising: from 5 to 25 parts by weight methyl styrene monomer; from 10 to 15 parts by weight non-halogenated (meth)acrylate monomer; and from 65 to 80 parts by weight brominated aromatic (meth)acrylate monomer.
Claim 29
Dependent Claim 15 words
The optical product of claim 14, comprising a film derived from the methyl styrene monomer.
Claim 30
Dependent Claim 25 words
The optical product of claim 14, comprising a base; and an optical layer prepared from a polymerizable composition, the polymerizable composition comprising methyl styrene monomer.
Claim 31
Dependent Claim 47 words
The optical product of claim 27, wherein the base is prepared from materials selected from the group consisting of: cellulose acetate butyrate, cellulose acetate propionate, polyether sulfone, polymethyl methacrylate, polyurethane, polyester, polyvinyl chloride, syndiotactic polystyrene, polyethlene naphthalate, copolymers or blends based on naphthalene dicarboxylic acids, and glass.
Claim 32
Dependent Claim 12 words
The optical product of claim 28, wherein the base comprises a polarizer.
Claim 33
Dependent Claim 17 words
The optical product of claim 14, comprising a brightness enhancement film derived from the methyl styrene monomer.
Claim 34
Dependent Claim 13 words
A backlit flat panel display comprising the brightness enhancement film of claim 30.
Claim 35
Dependent Claim 13 words
A computer or television comprising the backlit flat panel display of claim 31.
Claim 36
Dependent Claim 16 words
A microstructure-bearing article comprising an optical layer derived from a polymerizable composition comprising methyl styrene monomer.
Claim 37
Dependent Claim 16 words
A microstructure-bearing article comprising an optical layer derived from a polymerizable composition comprising methyl styrene monomer.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2003-08-22 2004-02-21 2004-08-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2007-08-22 2008-02-21 2008-08-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2011-08-22 2012-02-21 2012-08-22 $7700.00 Window Closed / Lapsed

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