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US6063482A Expired / Lapsed US ⏱️ 0.0 years remaining

Biaxially oriented polypropylene film having improved tear propagation resistance

Assignee: Basell Polyolefine GmbH
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Filing: 1997-10-30
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Granted: 2000-05-16
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Expires: 2017-10-30
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Abstract

Abstract A biaxially oriented polypropylene film is described. The base ply of the film essentially consists of a polypropylene prepared by means of a metallocene catalyst. This polypropylene is distinguished by a mean isotactic block length of greater than 40, an n-heptane soluble fraction of less than 1% and a ratio of the weight average molecular weight Mw to the number average molecular weight Mn of less than 4.

Inventors

  • 👤 Herbert Peiffer
  • 👤 Detlef Busch
  • 👤 Gunter Schlogl
  • 👤 Thomas Dries
  • 👤 Andreas Winter

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 07:56
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/32; B32B27/06; B32B27/08; B32B27/18; C; C08; C08J; C08J5/00; C08J5/18; C08L; C08L23/00; C08L23/02; C08L23/10; B32B2307/00; B32B2307/50; B32B2307/514; B32B2307/518; B32B2309/00; B32B2309/08; B32B2309/10; B32B2309/105; B32B2439/00; B32B2553/00; C08J2323/00; C08J2323/02; C08J2323/10; C08J2323/12; C08L2314/00; C08L2314/06; Y; Y10; Y10S; Y10S428/00; Y10S428/91; Y10S526/00; Y10S526/943; Y10T; Y10T428/00; Y10T428/24; Y10T428/24942; Y10T428/2495; Y10T428/28; Y10T428/2813; Y10T428/2817; Y10T428/2826; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31913

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 125 words
A biaxially oriented polypropylene single ply film wherein the mean isotactic block length of the polypropylene molecule between two structural chain defects is, as a statistical average, greater than 40, the n-heptane-insoluble fraction of the polypropylene has a chain isotactic index of at least 95%, measured by means of 13 C-NMR spectroscopy, the ratio of the weight average M w to the number average M n of the molecular weight distribution is less than 4, the n-heptane-soluble fraction of the polypropylene is less than 1%, and the tear propagation resistance of the film in the longitudinal direction is greater than 15 N/(mm of film thickness) and the tear progagation resistance of the film in the transverse direction is greater than 15 N/(mm of film thickness).
Claim 2
Dependent Claim 125 words
A biaxially oriented polypropylene single ply film wherein the mean isotactic block length of the polypropylene molecule between two structural chain defects is, as a statistical average, greater than 40, the n-heptane-insoluble fraction of the polypropylene has a chain isotactic index of at least 95%, measured by means of 13 C-NMR spectroscopy, the ratio of the weight average M w to the number average M n of the molecular weight distribution is less than 4, the n-heptane-soluble fraction of the polypropylene is less than 1%, and the tear propagation resistance of the film in the longitudinal direction is greater than 15 N/(mm of film thickness) and the tear progagation resistance of the film in the transverse direction is greater than 15 N/(mm of film thickness).
Claim 3
Dependent Claim 35 words
The single ply film as claimed in claim 1, wherein the single ply contains a polypropylene whose n-heptane-insoluble fraction has a chain isotactic index, measured by means of 13 C-NMR spectroscopy, of at least 96%.
Claim 4
Dependent Claim 25 words
The single ply film as claimed in claim 1, wherein the single ply contains a polypropylene whose M w /M n is less than 3.0.
Claim 5
Dependent Claim 17 words
The single ply film as claimed in claim 1, wherein the single ply contains an antistatic agent.
Claim 6
Dependent Claim 17 words
The single ply film as claimed in claim 1, wherein the single ply contains a neutralizing agent.
Claim 7
Dependent Claim 16 words
The single ply film as claimed in claim 1, wherein the single ply contains a stabilizer.
Claim 8
Dependent Claim 16 words
The single ply film as claimed in claim 1, wherein the single ply contains a lubricant.
Claim 9
Dependent Claim 17 words
The single ply film as claimed in claim 1, wherein the single ply contains an antiblocking agent.
Claim 10
Dependent Claim 16 words
The single ply film as claimed in claim 1, in the form of a packaging film.
Claim 11
Dependent Claim 16 words
The single ply film as claimed in claim 1, in the form of a laminating film.
Claim 12
Dependent Claim 148 words
A biaxially oriented polypropylene film, which has at least one base ply which contains polypropylene, wherein the mean isotactic block length of the polypropylene molecule between two structural chain defects is, as a statistical average, greater than 40, the n-heptane-insoluble fraction of the polypropylene has a chain isotactic index of at least 95%, measured by means of 13 C-NMR spectroscopy, the ratio of the weight average M w to the number average M n of the molecular weight distribution is less than 4, the n-heptane-soluble fraction of the polypropylene is less than 1%, and the tear propagation resistance of the film in the longitudinal direction is greater than 15 N/(mm of film thickness) and the tear progagation resistance of the film in the transverse direction is greater than 15 N/(mm of film thickness), and at least one ply on each side of the base ply comprising α-olefinic polymers.
Claim 13
Dependent Claim 148 words
A biaxially oriented polypropylene film, which has at least one base ply which contains polypropylene, wherein the mean isotactic block length of the polypropylene molecule between two structural chain defects is, as a statistical average, greater than 40, the n-heptane-insoluble fraction of the polypropylene has a chain isotactic index of at least 95%, measured by means of 13 C-NMR spectroscopy, the ratio of the weight average M w to the number average M n of the molecular weight distribution is less than 4, the n-heptane-soluble fraction of the polypropylene is less than 1%, and the tear propagation resistance of the film in the longitudinal direction is greater than 15 N/(mm of film thickness) and the tear progagation resistance of the film in the transverse direction is greater than 15 N/(mm of film thickness), and at least one ply on each side of the base ply comprising α-olefinic polymers.
Claim 14
Dependent Claim 34 words
The polypropylene film as claimed in claim 11, wherein the base ply contains a polypropylene whose n-heptane-insoluble fraction has a chain isotactic index, measured by means of 13 C-NMR spectroscopy, of at least 96%.
Claim 15
Dependent Claim 24 words
The polypropylene film as claimed in claim 11, wherein the base ply contains a polypropylene whose M w /M n is less than 3.0.
Claim 16
Dependent Claim 18 words
The polypropylene film as claimed in claim 11, wherein the base ply contains a neutralizing agent and/or stabilizer.
Claim 17
Dependent Claim 16 words
The polypropylene film as claimed in claim 11, wherein the base ply contains an antistatic agent.
Claim 18
Dependent Claim 32 words
The polypropylene film as claimed in claim 11, wherein the thickness of the film is 4 to 100 μm, the base ply accounting for about 40 to 60% of the total thickness.
Claim 19
Dependent Claim 15 words
A polypropylene film as claimed in claim 11, in the form of a packaging film.
Claim 20
Dependent Claim 15 words
A polypropylene film as claimed in claim 11, in the form of a laminating film.
Claim 21
Dependent Claim 49 words
A process for the production of a polypropylene film as claimed in claim 11, wherein the orientation in the longitudinal direction is effected with a longitudinal stretching ratio of 3:1 to 9:1 and that in the transverse direction is effected with a transverse stretching ratio of 4:1 to 12:1.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2003-05-16 2003-11-15 2004-05-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2007-05-16 2007-11-15 2008-05-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2011-05-16 2011-11-15 2012-05-16 $7700.00 Window Closed / Lapsed

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