US6042998A
Expired / Lapsed
US
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Method and apparatus for extending spatial frequencies in photolithography images
Assignee: UNM Rainforest Innovations
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Filing: 1997-09-17
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Granted: 2000-03-28
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Expires: 2017-09-17
Abstract
Abstract The present invention extends the available spatial frequency content of an image through the use of a method and apparatus for combining nonlinear functions of intensity to form three dimensional patterns with spatial frequencies that are not present in either of the individual exposures and that are beyond 2/λ in all three spatial directions. The resulting pattern has spatial frequency content beyond the limits set by optical propagation of spatial frequencies limited to 2/λ (e.g. pitch reduction from ˜λ/2 to at least ˜λ/4). The extension of spatial frequencies preferably extends the use of currently existing photolithography capabilities, thereby resulting in a significant economic impact. Multiplying the spatial frequency of lithographically defined structures suitably allows for substantial improvements in, inter alia, crystal growth, quantum structure growth and fabrication, flux pinning sites for high-T c superconductors, form birefringent materials, reflective optical coatings, photonic bandgap, electronics, optical/magnetic storage media, arrays of field emitters, DRAM (Dynamic Random Access Memory) capacitors and in other applications requiring large areas of nm-scale features.
Inventors
- 👤 Steven R. J. Brueck
- 👤 Saleem H. Zaidi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 23:38
CPC Classifications
B; B82; B82Y; B82Y20/00; G; G02; G02B; G02B6/00; G02B6/10; G02B6/12; G02B6/122; G02B6/1225; G03; G03F; G03F7/00; G03F7/0035; G03F7/20; G03F7/2022; G03F7/70; G03F7/70216; G03F7/70325; G03F7/70408; G03F7/70425; G03F7/70466
Claims Analysis
Total Claims: 36
Claim 1
Independent Claim
196 words
A method for obtaining a pattern wherein the Fourier transform of said pattern contains high spatial frequencies by combining nonlinear functions of intensity of at least two exposures combined with at least one nonlinear processing step intermediate between the two exposures to form three dimensional patterns comprising the steps of: coating a substrate with a first photoresist layer; exposing said first photoresist layer with a first exposure; developing said first photoresist layer to form a first pattern in said first photoresist layer, said first pattern containing spatial frequencies greater than those in a two dimensional optical intensity image imposed onto said photoresist layer in said first exposure as a result of a nonlinear response of said first photoresist layer; coating said substrate with a second photoresist layer; exposing said second photoresist layer with a second exposure; developing said second photoresist layer to form a second pattern in said second photoresist layer, said second pattern containing spatial frequencies greater than those in a two dimensional optical intensity image imposed onto said photoresist layer in said second exposure as a result of a nonlinear response of said second photoresist layer; combining said patterns to provide a final pattern.
Claim 2
Independent Claim
196 words
A method for obtaining a pattern wherein the Fourier transform of said pattern contains high spatial frequencies by combining nonlinear functions of intensity of at least two exposures combined with at least one nonlinear processing step intermediate between the two exposures to form three dimensional patterns comprising the steps of: coating a substrate with a first photoresist layer; exposing said first photoresist layer with a first exposure; developing said first photoresist layer to form a first pattern in said first photoresist layer, said first pattern containing spatial frequencies greater than those in a two dimensional optical intensity image imposed onto said photoresist layer in said first exposure as a result of a nonlinear response of said first photoresist layer; coating said substrate with a second photoresist layer; exposing said second photoresist layer with a second exposure; developing said second photoresist layer to form a second pattern in said second photoresist layer, said second pattern containing spatial frequencies greater than those in a two dimensional optical intensity image imposed onto said photoresist layer in said second exposure as a result of a nonlinear response of said second photoresist layer; combining said patterns to provide a final pattern.
Claim 3
Dependent Claim
19 words
The method of claim 1 wherein said first exposure includes a plurality of exposures forming a plurality of images.
Claim 4
Dependent Claim
19 words
The method of claim 1 wherein said second exposure includes a plurality of exposures forming a plurality of images.
Claim 5
Dependent Claim
27 words
The method of claim 1, wherein a minimum of said spatial frequencies along at least one direction in said first or second pattern is smaller than 2/λ.
Claim 6
Dependent Claim
32 words
The method of claim 1, wherein said intermediate nonlinear processing step enables a frequency distribution of said pattern which is altered from frequency distributions of only said first and said second exposure.
Claim 7
Independent Claim
257 words
A method for obtaining a pattern wherein the Fourier transform of said pattern contains high spatial frequencies by combining nonlinear functions of intensity of at least two exposures combined with at least one nonlinear processing step intermediate between the two exposures to form three dimensional patterns comprising the steps of: coating a substrate with a first mask material and a first photoresist layer; exposing said first photoresist layer with a first exposure developing said photoresist to form a first pattern in said first photoresist layer, said first pattern containing spatial frequencies greater than those in a two dimensional optical intensity image imposed onto said photoresist layer in said first exposure as a result of a nonlinear response of said first photoresist layer; transferring said first pattern into said first mask material, said first mask material comprising at least one of SiO 2 , Si 3 N 4 , a metal, a polysilicon and a polymer; coating said substrate with a second photoresist; exposing said second photoresist with a second exposure developing said second photoresist layer to form a second pattern in said second photoresist layer, said second pattern containing spatial frequencies greater than those in a two dimensional optical intensity image imposed onto said photoresist layer in said second exposure as a result of a nonlinear response of said second photoresist layer; transferring said first pattern and said second pattern into said substrate using a combined mask including parts of said first mask layer and said second photoresist; removing said first mask material and said second photoresist.
Claim 8
Independent Claim
257 words
A method for obtaining a pattern wherein the Fourier transform of said pattern contains high spatial frequencies by combining nonlinear functions of intensity of at least two exposures combined with at least one nonlinear processing step intermediate between the two exposures to form three dimensional patterns comprising the steps of: coating a substrate with a first mask material and a first photoresist layer; exposing said first photoresist layer with a first exposure developing said photoresist to form a first pattern in said first photoresist layer, said first pattern containing spatial frequencies greater than those in a two dimensional optical intensity image imposed onto said photoresist layer in said first exposure as a result of a nonlinear response of said first photoresist layer; transferring said first pattern into said first mask material, said first mask material comprising at least one of SiO 2 , Si 3 N 4 , a metal, a polysilicon and a polymer; coating said substrate with a second photoresist; exposing said second photoresist with a second exposure developing said second photoresist layer to form a second pattern in said second photoresist layer, said second pattern containing spatial frequencies greater than those in a two dimensional optical intensity image imposed onto said photoresist layer in said second exposure as a result of a nonlinear response of said second photoresist layer; transferring said first pattern and said second pattern into said substrate using a combined mask including parts of said first mask layer and said second photoresist; removing said first mask material and said second photoresist.
Claim 9
Dependent Claim
20 words
The method of claim 6 wherein said transferring step includes at least one of etching, deposition and-lift off, and damascene.
Claim 10
Independent Claim
97 words
A method for increasing spatial frequency content of lithographic patterns comprising the steps of: depositing a material; depositing a photoresist on said material; exposing a periodic image in said photoresist, said periodic image having a pitch p min and a linewidth less than p min /2; developing said periodic image to form a periodic pattern in said photoresist; transferring said periodic pattern to said material; depositing a second photoresist layer on said material; offsetting said periodic pattern by p min /2; repeating said exposing, developing and transferring steps, thereby interpolating new said pattern midway between said pattern.
Claim 11
Independent Claim
97 words
A method for increasing spatial frequency content of lithographic patterns comprising the steps of: depositing a material; depositing a photoresist on said material; exposing a periodic image in said photoresist, said periodic image having a pitch p min and a linewidth less than p min /2; developing said periodic image to form a periodic pattern in said photoresist; transferring said periodic pattern to said material; depositing a second photoresist layer on said material; offsetting said periodic pattern by p min /2; repeating said exposing, developing and transferring steps, thereby interpolating new said pattern midway between said pattern.
Claim 12
Dependent Claim
16 words
The method of claim 8, wherein said step of depositing a material includes depositing doped polysilicon.
Claim 13
Dependent Claim
23 words
The method of claim 8, wherein said material includes an SiO 2 overlayer configured to act as a hardmask during said etching step.
Claim 14
Dependent Claim
33 words
The method of claim 8, wherein said step of depositing a photoresist includes depositing at least one of a negative photoresist, a positive photoresist and a positive photoresist with an image reversal step.
Claim 15
Dependent Claim
17 words
The method of claim 8, wherein said step of exposing a photoresist includes exposing using interference lithography.
Claim 16
Dependent Claim
23 words
The method of claim 8, wherein said step of exposing a photoresist includes exposing using interference lithography in combination with another lithographic technique.
Claim 17
Dependent Claim
23 words
The method of claim 8, wherein said step of exposing a photoresist includes exposing using interference lithography in combination with an optical stepper.
Claim 18
Dependent Claim
15 words
The method of claim 8, wherein said step of exposing a photoresist includes image reversal.
Claim 19
Dependent Claim
20 words
The method of claim 8, wherein said step of developing said periodic pattern includes etching said pattern into a hardmask.
Claim 20
Dependent Claim
22 words
The method of claim 8, wherein said exposing step includes exposing with at least one of multiple exposures and multiple-beam single exposures.
Claim 21
Dependent Claim
68 words
The method of claim 8, wherein said step of depositing a material includes depositing a material on at least one of a textured substrate, a quantum structure, a flux pinning site for high-T c superconductors, a birefringent material, a reflective optical coating, a photonic bandgap, an electronic device, an optical storage media, a magnetic storage media, an array of field emitters and a Dynamic Random Access Memory capacitor.
Claim 22
Independent Claim
142 words
A method for multiplying the spatial frequency content of a one-dimensional line/space pattern consisting of the steps of: providing a substrate; depositing a material on said substrate; depositing a photoresist on said material; exposing and developing a periodic pattern in said photoresist, said periodic pattern having a pitch p min and a linewidth less than p min /2; transferring said periodic pattern into said material by a process step; removing said first photoresist layer; depositing a second photoresist layer; exposing said second photoresist layer with said periodic pattern offset by p min /2; repeating the exposing, developing and transferring steps N times with offsets of p min /N, thereby interpolating N new said patterns equally spaced midway between said pattern, etching exposed said material down to a predetermined depth, thereby transferring said pattern through said material; transferring said pattern into said substrate.
Claim 23
Independent Claim
142 words
A method for multiplying the spatial frequency content of a one-dimensional line/space pattern consisting of the steps of: providing a substrate; depositing a material on said substrate; depositing a photoresist on said material; exposing and developing a periodic pattern in said photoresist, said periodic pattern having a pitch p min and a linewidth less than p min /2; transferring said periodic pattern into said material by a process step; removing said first photoresist layer; depositing a second photoresist layer; exposing said second photoresist layer with said periodic pattern offset by p min /2; repeating the exposing, developing and transferring steps N times with offsets of p min /N, thereby interpolating N new said patterns equally spaced midway between said pattern, etching exposed said material down to a predetermined depth, thereby transferring said pattern through said material; transferring said pattern into said substrate.
Claim 24
Dependent Claim
17 words
The method of claim 19, wherein said step of depositing a material includes depositing in-situ doped polysilicon.
Claim 25
Dependent Claim
23 words
The method of claim 19, wherein said material includes an SiO 2 overlayer configured to act as a hardmask during said etching step.
Claim 26
Dependent Claim
33 words
The method of claim 19, wherein said step of depositing a photoresist includes depositing at least one of a negative photoresist, a positive photoresist and a positive photoresist with an image reversal step.
Claim 27
Dependent Claim
17 words
The method of claim 19, wherein said step of exposing a photoresist includes exposing using interference lithography.
Claim 28
Dependent Claim
23 words
The method of claim 19, wherein said step of exposing a photoresist includes exposing using interference lithography in combination with a lithographic technique.
Claim 29
Dependent Claim
23 words
The method of claim 19, wherein said step of exposing a photoresist includes exposing using interference lithography in combination with an optical stepper.
Claim 30
Dependent Claim
15 words
The method of claim 19, wherein said step of exposing a photoresist includes image reversal.
Claim 31
Dependent Claim
20 words
The method of claim 19, wherein said step of developing said periodic pattern includes etching said pattern into a hardmask.
Claim 32
Dependent Claim
17 words
The method of claim 19, further comprising at least one of multiple exposures and multiple-beam single exposures.
Claim 33
Dependent Claim
19 words
The method of claim 19, wherein said pattern size avoids overlapping of pattern features upon doubling of said frequency.
Claim 34
Dependent Claim
15 words
The method of claim 19, further comprising registering said periodic pattern to a contact patterning.
Claim 35
Dependent Claim
18 words
The method of claim 19 further comprising the step of allowing about 100 nm between adjacent said patterns.
Claim 36
Dependent Claim
17 words
The method of claim 19, wherein said step of depositing a material includes depositing an NO layer.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 2003-03-28 | 2003-09-27 | 2004-03-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2007-03-28 | 2007-09-27 | 2008-03-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2011-03-28 | 2011-09-27 | 2012-03-28 | $7700.00 | Window Closed / Lapsed |