US5932055A — Direct metal fabrication (DMF) using a carbon pre…

Claim 1

Independent Claim 184 words

A method of direct metal fabrication (DMF) of metal parts, comprising: using a carbon precursor to wet a metal powder alloy (X) whose particles are mixed with a eutectic reducing element (A) and bind the particles into a green form part with a specified shape, said particles each having a plurality of grains that are bound together along grain boundaries; partially reducing the carbon precursor such that a thin carbon (C) film remains whose C═C bonds maintain the part's specified shape and acts as a catalyst causing the eutectic reducing element to become diffusely mobile; diffusing the eutectic reducing element along the particles' grain boundaries such that the reducing element interacts with the carbon film at the interface between the particles to form organo-metallic bonds C═A that are much stronger than the film's C═C bonds; and initiating supersolidus liquid phase sintering (SLPS) to form a liquid film along the particles' grain boundaries so that the grains slide relative to each other and densify in response to surface tension and capillary pressure to form a final part whose organo-metallic C═A bonds maintain the specified shape.

Claim 2

Independent Claim 184 words

A method of direct metal fabrication (DMF) of metal parts, comprising: using a carbon precursor to wet a metal powder alloy (X) whose particles are mixed with a eutectic reducing element (A) and bind the particles into a green form part with a specified shape, said particles each having a plurality of grains that are bound together along grain boundaries; partially reducing the carbon precursor such that a thin carbon (C) film remains whose C═C bonds maintain the part's specified shape and acts as a catalyst causing the eutectic reducing element to become diffusely mobile; diffusing the eutectic reducing element along the particles' grain boundaries such that the reducing element interacts with the carbon film at the interface between the particles to form organo-metallic bonds C═A that are much stronger than the film's C═C bonds; and initiating supersolidus liquid phase sintering (SLPS) to form a liquid film along the particles' grain boundaries so that the grains slide relative to each other and densify in response to surface tension and capillary pressure to form a final part whose organo-metallic C═A bonds maintain the specified shape.

Claim 3

Dependent Claim 73 words

The method of claim 1, wherein the concentration of the eutectic reducing element is sufficient to a) completely diffuse through the grain boundaries of the metal powder alloy, b) react with the carbon to form the organo-metallic bonds, and c) assist SLPS, and the concentration of carbon is sufficient to a) survive the reduction, b) form the thin carbon film and c) react with the eutectic reducing element to form the organo-metallic bonds.

Claim 4

Dependent Claim 27 words

The method of claim 2, wherein the eutectic reducing element is small enough to become diffusely mobile along the grain boundaries and is highly reactive with carbon.

Claim 5

Dependent Claim 12 words

The method of claim 3, wherein the eutectic reducing element is boron.

Claim 6

Dependent Claim 56 words

The method of claim 2, wherein the eutectic reducing element is introduced in a metal powder alloy Y that comprises: (a) the same elemental components which comprise the metal powder alloy X, and (b) the eutectic reducing element in a concentration greater than any concentration of the eutectic element present in the metal powder alloy X.

Claim 7

Dependent Claim 37 words

The method of claim 5, wherein the mixture is comprised of 75-85% by volume of alloy X, 5-15% by volume of alloy Y with 0.15-0.5% by weight of element A with the remaining being the carbon precursor.

Claim 8

Dependent Claim 22 words

The method of claim 2, wherein the carbon precursor is melted layer-by-layer using selective laser sintering to form the green form part.

Claim 9

Dependent Claim 28 words

The method of claim 2, wherein the powder mixture is imprinted onto a substrate carrier using a magnetographic printing process and laminated to form the green form part.

Claim 10

Dependent Claim 20 words

The method of claim 2, wherein the powder is mixed in a pre-cast mold to form the green form part.

Claim 11

Dependent Claim 35 words

The method of claim 1, wherein the green form part is placed in a furnace and subjected to a thermal cycle that partially reduces the carbon precursor, diffuses the eutectic reducing element, and initiates SLPS.

Claim 12

Dependent Claim 95 words

The method of claim 10, wherein in the thermal cycle the temperature of the furnace is a) raised from its ambient value to a first temperature range in which the precursor is partially reduced and the carbon film is deposited on the surface of the part; b) raised to a second temperature range to initiate grain boundary diffusion of the eutectic reducing element until the reducing element reaches its equilibrium state; c) raised to a third temperature range to initiate SLPS; and d) cooled to its ambient temperature to complete densification to the final part.

Claim 13

Dependent Claim 23 words

The method of claim 11, wherein the first, second, and third temperature ranges are approximately (200-500° C.), (500-1200° C.), and (1200-1300° C.), respectively.

Claim 14

Dependent Claim 28 words

The method of claim 11, wherein the green form part is reduced in an environment that is incapable of eliminating all of the carbon from the carbon precursor.

Claim 15

Dependent Claim 37 words

The method of claim 2, wherein the concentrations of carbon and the eutectic reducing element in the final part are small enough that the final part exhibits the material quality of the parent metal powder alloy X.

Claim 16

Independent Claim 319 words

A method of direct metal fabrication (DMF) of metal parts, comprising: providing a mixture of a polymer (P) having a concentration of carbon (C) and metal powder alloys (X) and (Y) having substantially the same elemental compositions except that alloy Y includes a eutectic reducing element A at a concentration higher than any concentration of said eutectic reducing element A present in alloy X, said X and Y alloys' particles each having a plurality of grains that are bounded together along grain boundaries; using the polymer to wet and bind the X and Y alloy particles into a green form part with a specified shape; and in a single thermal cycle, heating the green form part to partially reduce the polymer so that a thin carbon film remains whose C═C bonds maintain the part's specified shape and acts as a catalyst causing the eutectic reducing element to become diffusely mobile; increasing the temperature to accelerate the diffusion of the eutectic reducing element along the grain boundaries of the alloy Y particles, through the carbon film, and along the grain boundaries of the adjacent alloy X particles until equilibrium of element A in the mixture is achieved so that the mixture is a fully homogenized metal powder alloy Z that is held together by the organo-metallic bonds C═A formed when said element A interacts with the carbon film; increasing the temperature above a solidus temperature for alloy Z to initiate supersolidus liquid phase sintering (SLPS) where a liquid film forms along the particles' grain boundaries so that the grains slide relative to each other and densify in response to surface tension and capillary pressure to form a final part whose organo-metallic C═A bonds maintain the specified shape, said carbon and eutectic reducing elements constituting such a small portion of said final part that it exhibits the properties of the parent alloy X; and cooling the final part to complete densification.

Claim 17

Independent Claim 319 words

A method of direct metal fabrication (DMF) of metal parts, comprising: providing a mixture of a polymer (P) having a concentration of carbon (C) and metal powder alloys (X) and (Y) having substantially the same elemental compositions except that alloy Y includes a eutectic reducing element A at a concentration higher than any concentration of said eutectic reducing element A present in alloy X, said X and Y alloys' particles each having a plurality of grains that are bounded together along grain boundaries; using the polymer to wet and bind the X and Y alloy particles into a green form part with a specified shape; and in a single thermal cycle, heating the green form part to partially reduce the polymer so that a thin carbon film remains whose C═C bonds maintain the part's specified shape and acts as a catalyst causing the eutectic reducing element to become diffusely mobile; increasing the temperature to accelerate the diffusion of the eutectic reducing element along the grain boundaries of the alloy Y particles, through the carbon film, and along the grain boundaries of the adjacent alloy X particles until equilibrium of element A in the mixture is achieved so that the mixture is a fully homogenized metal powder alloy Z that is held together by the organo-metallic bonds C═A formed when said element A interacts with the carbon film; increasing the temperature above a solidus temperature for alloy Z to initiate supersolidus liquid phase sintering (SLPS) where a liquid film forms along the particles' grain boundaries so that the grains slide relative to each other and densify in response to surface tension and capillary pressure to form a final part whose organo-metallic C═A bonds maintain the specified shape, said carbon and eutectic reducing elements constituting such a small portion of said final part that it exhibits the properties of the parent alloy X; and cooling the final part to complete densification.

Claim 18

Dependent Claim 85 words

The method of claim 15, wherein the concentration of the eutectic reducing element is sufficient to a) completely diffuse through the grain boundaries of the metal powder alloys X and Y, b) react with the carbon at the interface between alloy particles to form a sufficient number of organo-metallic bonds, and c) assist SLPS, and the concentration of carbon is sufficient to a) survive the reduction, b) form the thin carbon film and c) react with the eutectic reducing element to form the organo-metallic bonds.

Claim 19

Dependent Claim 36 words

The method of claim 16, wherein the mixture is comprised of 75-85% by volume of alloy X, 5-15% by volume of alloy Y with 0.15-0.5% by weight of element A with the remaining being the polymer.

Claim 20

Dependent Claim 21 words

The method of claim 15, wherein the polymer is melted layer-by-layer using selective laser sintering to form the green form part.

Claim 21

Dependent Claim 27 words

The method of claim 15, wherein the powder mixture is imprinted onto a carrier using a magnetographic printing process and laminated to form the green form part.

Claim 22

Dependent Claim 20 words

The method of claim 15, wherein the powder is mixed in a pre-cast mold to form the green form part.

Claim 23

Independent Claim 190 words

A method of direct metal fabrication (DMF) of metal parts, comprising: a) mixing powders of a parent metal, a eutectic reducing element A, and a polymer to form a mixture; b) spreading a layer of said mixture on a platform; c) directing a beam of energy onto selected areas of said layer to cause localized melting of said polymer, said polymer resolidifying to bind said metal powders in said selected areas; d) repeating steps b and c to build up a green form part; and e) placing said green form part in a furnace where it is subjected to a thermal cycle that f) partially reduces the polymer leaving a thin carbon film whose C═C bonds maintain the part's specified shape and act as a catalyst causing the eutectic reducing element to become diffusely mobile, g) accelerates the diffusion of the eutectic reducing element along the grain boundaries of the adjacent parent metal particles to form organo-metallic bonds C═A, h) initiates supersolidus liquid phase sintering (SLPS) to densify the powder into a final part whose organo-metallic C═A bonds maintain the specified shape, and i)cools the final part to complete densification.

Claim 24

Independent Claim 190 words

A method of direct metal fabrication (DMF) of metal parts, comprising: a) mixing powders of a parent metal, a eutectic reducing element A, and a polymer to form a mixture; b) spreading a layer of said mixture on a platform; c) directing a beam of energy onto selected areas of said layer to cause localized melting of said polymer, said polymer resolidifying to bind said metal powders in said selected areas; d) repeating steps b and c to build up a green form part; and e) placing said green form part in a furnace where it is subjected to a thermal cycle that f) partially reduces the polymer leaving a thin carbon film whose C═C bonds maintain the part's specified shape and act as a catalyst causing the eutectic reducing element to become diffusely mobile, g) accelerates the diffusion of the eutectic reducing element along the grain boundaries of the adjacent parent metal particles to form organo-metallic bonds C═A, h) initiates supersolidus liquid phase sintering (SLPS) to densify the powder into a final part whose organo-metallic C═A bonds maintain the specified shape, and i)cools the final part to complete densification.

Claim 25

Dependent Claim 73 words

The method of claim 21, wherein the concentration of the eutectic reducing element is sufficient to a) completely diffuse through the grain boundaries of the metal powder alloy, b) react with the carbon to form the organo-metallic bonds, and c) assist SLPS and the concentration of carbon is sufficient to a) survive the reduction, b) form the thin carbon film and c) react with the eutectic reducing element to form the organo-metallic bonds.

Claim 26

Dependent Claim 54 words

The method of claim 22, wherein the eutectic reducing element is introduced in a metal powder alloy (Y) that comprises: (a) the same elemental components which comprise the parent metal powder, and (b) the eutectic reducing element in a concentration greater than any concentration of said eutectic element present in the parent metal powder.

Claim 27

Dependent Claim 37 words

The method of claim 23, wherein the mixture is comprised of 75-85% by volume of the parent metal, 5-15% by volume of alloy Y with 0.15-0.5% by weight of element A with the remaining being the polymer.

Claim 28

Independent Claim 196 words

A method of direct metal fabrication of metal parts, comprising: a) mixing powders of a parent metal, a eutectic reducing element A, and a polymer to form a mixture; b) feeding the mixture to a magnetographic printer that sequentially prints latent images formed from said mixture onto respective sheets of a thermally activated substrate carrier as it moves through the printer; c) cutting the next sheet off said substrate carrier; d) registering and laminating each successive sheet on top of the previous sheet to buildup a green form part layer-by-layer; and e) placing said green form part in a furnace where it is subjected to a thermal cycle that f) partially reduces the polymer leaving a thin carbon film whose C═C bonds maintain the part's specified shape and act as a catalyst causing the eutectic reducing element to become diffusely mobile, g) accelerates the diffusion of the eutectic reducing element along the grain boundaries of the adjacent parent metal particles to form organo-metallic bonds C═A, h) initiates supersolidus liquid phase sintering (SLPS) to densify the powder into a final part whose organo-metallic C═A bonds maintain the specified shape, and i)cools the final part to complete densification.

Claim 29

Independent Claim 196 words

A method of direct metal fabrication of metal parts, comprising: a) mixing powders of a parent metal, a eutectic reducing element A, and a polymer to form a mixture; b) feeding the mixture to a magnetographic printer that sequentially prints latent images formed from said mixture onto respective sheets of a thermally activated substrate carrier as it moves through the printer; c) cutting the next sheet off said substrate carrier; d) registering and laminating each successive sheet on top of the previous sheet to buildup a green form part layer-by-layer; and e) placing said green form part in a furnace where it is subjected to a thermal cycle that f) partially reduces the polymer leaving a thin carbon film whose C═C bonds maintain the part's specified shape and act as a catalyst causing the eutectic reducing element to become diffusely mobile, g) accelerates the diffusion of the eutectic reducing element along the grain boundaries of the adjacent parent metal particles to form organo-metallic bonds C═A, h) initiates supersolidus liquid phase sintering (SLPS) to densify the powder into a final part whose organo-metallic C═A bonds maintain the specified shape, and i)cools the final part to complete densification.

Claim 30

Dependent Claim 76 words

The method of claim 25, wherein the concentration of the eutectic reducing element is sufficient to a) completely diffuse through the grain boundaries of the metal powder alloy, b) react with the carbon to form a sufficient number of organo-metallic bonds, and c) assist SLPS and the concentration of carbon is sufficient to a) survive the reduction, b) form the thin carbon film and c) react with the eutectic reducing element to form the organo-metallic bonds.

Claim 31

Dependent Claim 54 words

The method of claim 26, wherein the eutectic reducing element is introduced in a metal powder alloy (Y) that comprises: (a) the same elemental components which comprise the parent metal powder, and (b) the eutectic reducing element in a concentration greater than any concentration of said eutectic element present in the parent metal powder.

Claim 32

Dependent Claim 37 words

The method of claim 27, wherein the mixture is comprised of 75-85% by volume of the parent metal, 5-15% by volume of alloy Y with 0.15-0.5% by weight of element A with the remaining being the polymer.

Claim 33

Dependent Claim 27 words

The method of claim 25, wherein the substrate carrier comprises a polymer material that contributes carbon to the formation of the carbon film and the organo-metallic bonds.

Claim 34

Dependent Claim 144 words

The method of claim 25, wherein the magnetographic printer comprises: a rotating drum; a static writing head array that transfers an electronic latent image from a CAD file onto the rotating drum in the form of a magnetic latent image; a powder feeder that feeds the mixture to the rotating drum so that it is transferred to the magnetic latent image; a hot roller that thermally activates the substrate carrier and draws in past the rotating drum so that the mixture in the form of the latent image is transferred onto the next sheet of the substrate carrier; an erasing bar that magnetical erases the magnetic latent image from the drum after the mixture has been transferred to the substrate carrier; and a cold roller that thermally deactivates the substrate carrier so that it can be cut and laminated into the green form part.

Claim 35

Independent Claim 168 words

A method of direct metal fabrication (DMF) of metal parts, comprising: a) providing a master mold for a green form part; b) mixing a metal powder alloy comprising alloy X particles and a eutectic reducing element with a polymer resin that wets and binds the particles in said mold to form the green form part; c) placing said mold in a furnace where it is subjected to a thermal cycle that f) partially reduces the polymer resin leaving a thin carbon film whose C═C bonds maintain the part's specified shape and acts as a catalyst causing the eutectic reducing element to become diffusely mobile, g) accelerates the diffusion of the eutectic reducing element along the grain boundaries of the adjacent alloy X particles to form organo-metallic bonds C═A, h) initiates supersolidus liquid phase sintering (SLPS) to densify the powder into a final part whose organo-metallic C═A bonds maintain the specified shape, and i)cools the final part to complete densification; and j) removing the final part from the mold.

Claim 36

Independent Claim 168 words

A method of direct metal fabrication (DMF) of metal parts, comprising: a) providing a master mold for a green form part; b) mixing a metal powder alloy comprising alloy X particles and a eutectic reducing element with a polymer resin that wets and binds the particles in said mold to form the green form part; c) placing said mold in a furnace where it is subjected to a thermal cycle that f) partially reduces the polymer resin leaving a thin carbon film whose C═C bonds maintain the part's specified shape and acts as a catalyst causing the eutectic reducing element to become diffusely mobile, g) accelerates the diffusion of the eutectic reducing element along the grain boundaries of the adjacent alloy X particles to form organo-metallic bonds C═A, h) initiates supersolidus liquid phase sintering (SLPS) to densify the powder into a final part whose organo-metallic C═A bonds maintain the specified shape, and i)cools the final part to complete densification; and j) removing the final part from the mold.

Claim 37

Dependent Claim 18 words

The method of claim 31, wherein said master mold is formed using a rapid prototype manufacturing (RM) process.

Claim 38

Dependent Claim 18 words

The method of claim 31, wherein said final part has the material quality of the metal powder alloy.

Claim 39

Dependent Claim 31 words

The method of claim 31, wherein the green form part is reduced in an environment in said furnace that is incapable of eliminating all of the carbon in said polymer resin.

Claim 40

Dependent Claim 76 words

The method of claim 31, wherein the concentration of the eutectic reducing element is sufficient to a) completely diffuse through the grain boundaries of the metal powder alloy, b) react with the carbon to form a sufficient number of organo-metallic bonds, and c) assist SLPS and the concentration of carbon is sufficient to a) survive the reduction, b) form the thin carbon film and c) react with the eutectic reducing element to form the organo-metallic bonds.

Claim 41

Dependent Claim 50 words

The method of claim 35, wherein the eutectic reducing element is introduced in a metal powder alloy (Y) which comprises: (a) the same elemental components which comprise alloy X, and (b) the eutectic reducing element in a concentration greater than any concentration of said eutectic element present in alloy X.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	2002-08-02	2003-02-01	2003-08-03	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	2006-08-02	2007-02-01	2007-08-03	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	2010-08-02	2011-02-01	2011-08-03	$7700.00	Window Closed / Lapsed

Direct metal fabrication (DMF) using a carbon precursor to bind the "green form" part and catalyze a eutectic reducing element in a supersolidus liquid phase sintering (SLPS) process

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