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US5863486A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of providing leveling property to photocurable resin composition layers in production process of three-dimensional objects by photohardening

Assignee: TAKEMOTO YUSHI A CORP OF JAPAN KK
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Filing: 1997-05-08
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Granted: 1999-01-26
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Expires: 2017-05-08
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Abstract

Abstract In a process for producing a three-dimensional photohardened object by forming a layer of photocurable resin composition containing a photocurable liquid, a filler and a photoinitiator, photohardening at least a portion of this layer by exposing it to actinic radiation, and thereafter repeating the process of forming thereabove a new layer of photocurable resin composition and photohardening at least a portion of this layer by exposing it to actinic radiation, the property of the photocurable resin composition to become level can be improved by adding phosphoric acid ester of a specified structure at a specified rate.

Inventors

  • 👤 Tatsuhiko Ozaki
  • 👤 Toshiharu Suzuki
  • 👤 Hirokazu Matsueda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 21:05
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/0048; B; B29; B29C; B29C64/00; B29C64/10; B29C64/106; B29C64/124; B29C64/129; B29C64/135; B33; B33Y; B33Y70/00; B33Y70/10; G03F7/0037; B29C35/00; B29C35/02; B29C35/08; B29C35/0805; B29C2035/0833; B29C2035/0838; G03F7/0047

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 186 words
In a process for producing a three-dimensional photohardened object by forming a layer of photocurable resin composition containing a photocurable liquid, a filler and a photoinitiator, photohardening at least a portion of said layer by applying actinic radiation thereto, and thereafter repeating the process of forming thereabove a new layer of photocurable resin composition and photohardening at least a portion of said new layer by application of said actinic radiation to thereby produce a three-dimensional photohardened object, the improvement wherein said process includes the step of improving leveling property of said layer of said photocurable resin composition by adding 0.1-5 weight parts of phosphoric acid ester shown by Formula 1 given below to said photocurable resin composition for 100 weight parts of said filler contained therein, said Formula 1 being given as follows: ##STR2## where R is alkyl group with 1-15 carbon atoms, A is a residual group obtained by removing hydroxyl groups from a diol selected from the diol group consisting of polyetherdiol, polyesterdiol and polyetheresterdiol, M is H or a monovalent base, and m and n are each 1 or 2 such that m+n=3.
Claim 2
Dependent Claim 186 words
In a process for producing a three-dimensional photohardened object by forming a layer of photocurable resin composition containing a photocurable liquid, a filler and a photoinitiator, photohardening at least a portion of said layer by applying actinic radiation thereto, and thereafter repeating the process of forming thereabove a new layer of photocurable resin composition and photohardening at least a portion of said new layer by application of said actinic radiation to thereby produce a three-dimensional photohardened object, the improvement wherein said process includes the step of improving leveling property of said layer of said photocurable resin composition by adding 0.1-5 weight parts of phosphoric acid ester shown by Formula 1 given below to said photocurable resin composition for 100 weight parts of said filler contained therein, said Formula 1 being given as follows: ##STR2## where R is alkyl group with 1-15 carbon atoms, A is a residual group obtained by removing hydroxyl groups from a diol selected from the diol group consisting of polyetherdiol, polyesterdiol and polyetheresterdiol, M is H or a monovalent base, and m and n are each 1 or 2 such that m+n=3.
Claim 3
Dependent Claim 29 words
The improvement of claim 1 wherein A in said Formula 1 represents a residual group obtained by removing hydroxyl groups from polyetherdiol with repetition number of oxyalkylene units 5-100.
Claim 4
Dependent Claim 27 words
The improvement of claim 2 wherein said oxyalkylene units consist of oxypropylene units or oxyethylene units and oxypropylene units at molar ratio of 100/0-50/50 in molar %.
Claim 5
Dependent Claim 28 words
The improvement of claim 1 wherein said phosphoric acid ester shown by said Formula 1 is alkoxypolyether acidic phosphoric acid ester having alkoxy group with 1-6 carbon atoms.
Claim 6
Dependent Claim 28 words
The improvement of claim 2 wherein said phosphoric acid ester shown by said Formula 1 is alkoxypolyether acidic phosphoric acid ester having alkoxy group with 1-6 carbon atoms.
Claim 7
Dependent Claim 36 words
The improvement of claim 1 wherein said phosphoric acid ester shown by said Formula 1 is a salt obtained by neutralizing alkoxypolyether acidic phosphoric acid ester having alkoxy group with 1-6 carbon atoms with heterocyclic monoamine.
Claim 8
Dependent Claim 36 words
The improvement of claim 2 wherein said phosphoric acid ester shown by said Formula 1 is a salt obtained by neutralizing alkoxypolyether acidic phosphoric acid ester having alkoxy group with 1-6 carbon atoms with heterocyclic monoamine.
Claim 9
Dependent Claim 16 words
The improvement of claim 1 wherein said filler includes inorganic fine solid particles and inorganic whiskers.
Claim 10
Dependent Claim 16 words
The improvement of claim 2 wherein said filler includes inorganic fine solid particles and inorganic whiskers.
Claim 11
Dependent Claim 16 words
The improvement of claim 4 wherein said filler includes inorganic fine solid particles and inorganic whiskers.
Claim 12
Dependent Claim 16 words
The improvement of claim 5 wherein said filler includes inorganic fine solid particles and inorganic whiskers.
Claim 13
Dependent Claim 16 words
The improvement of claim 6 wherein said filler includes inorganic fine solid particles and inorganic whiskers.
Claim 14
Dependent Claim 16 words
The improvement of claim 7 wherein said filler includes inorganic fine solid particles and inorganic whiskers.
Claim 15
Dependent Claim 13 words
The improvement of claim 1 wherein said photocurable liquid comprises unsaturated urethane resin.
Claim 16
Dependent Claim 13 words
The improvement of claim 2 wherein said photocurable liquid comprises unsaturated urethane resin.
Claim 17
Dependent Claim 13 words
The improvement of claim 4 wherein said photocurable liquid comprises unsaturated urethane resin.
Claim 18
Dependent Claim 13 words
The improvement of claim 5 wherein said photocurable liquid comprises unsaturated urethane resin.
Claim 19
Dependent Claim 13 words
The improvement of claim 6 wherein said photocurable liquid comprises unsaturated urethane resin.
Claim 20
Dependent Claim 13 words
The improvement of claim 7 wherein said photocurable liquid comprises unsaturated urethane resin.

References Cited (Backward Citations)

JPS62101408A Cited
EP0250121A2 Cited
US4942066A Cited
US5002855A Cited
JPH0661849A Cited
JPH0661848A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2002-01-25 2002-07-27 2003-01-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2006-01-25 2006-07-27 2007-01-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2010-01-25 2010-07-27 2011-01-26 $7700.00 Window Closed / Lapsed

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