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Process for forming silicon carbide films and microcomponents

Assignee: University of California
•
Filing: 1995-07-27
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Granted: 1999-01-19
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Expires: 2015-07-27
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Abstract

Abstract Silicon carbide films and microcomponents are grown on silicon substrates at surface temperatures between 900 K and 1700 K via C 60 precursors in a hydrogen-free environment. Selective crystalline silicon carbide growth can be achieved on patterned silicon-silicon oxide samples. Patterned SiC films are produced by making use of the high reaction probability of C 60 with silicon at surface temperatures greater than 900 K and the negligible reaction probability for C 60 on silicon dioxide at surface temperatures less than 1250 K.

Inventors

  • 👤 Alex V. Hamza
  • 👤 Mehdi Balooch
  • 👤 Mehran Moalem

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 01:53
CPC Classifications
C; C30; C30B; C30B23/00; C30B23/02; C30B25/00; C30B25/02; C30B29/00; C30B29/10; C30B29/36; Y; Y10; Y10S; Y10S438/00; Y10S438/931

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 38 words
A process for forming silicon carbide films and microcomponents on a silicon substrate, comprising: forming a silicon carbide layer on a silicon substrate surface by heating the silicon surface in the presence of C 60 and silicon vapor.
Claim 2
Dependent Claim 38 words
A process for forming silicon carbide films and microcomponents on a silicon substrate, comprising: forming a silicon carbide layer on a silicon substrate surface by heating the silicon surface in the presence of C 60 and silicon vapor.
Claim 3
Dependent Claim 26 words
A process as recited in claim 1, wherein forming the silicon carbide layer is carried out at a temperature between about 900 K and 1700 K.
Claim 4
Dependent Claim 18 words
A process as recited in claim 1, wherein forming the silicon carbide layer is carried out under vacuum.
Claim 5
Dependent Claim 23 words
A process as recited in claim 1, wherein forming the silicon carbide layer is carried out in the presence of C 60 vapor.
Claim 6
Dependent Claim 26 words
A process as recited in claim 1, wherein forming the silicon carbide layer is carried out in the presence of C 60 in a solid form.
Claim 7
Dependent Claim 20 words
A process as recited in claim 1, wherein the silicon carbide layer is greater than about one micron in thickness.
Claim 8
Dependent Claim 16 words
A process as recited in claim 1, wherein heating the silicon surface is carried out radiatively.
Claim 9
Dependent Claim 16 words
A process as recited in claim 1, wherein heating the silicon surface is carried out resistively.
Claim 10
Dependent Claim 15 words
A process as recited in claim 1, wherein the silicon carbide layer is stoichiometric (SiC).
Claim 11
Dependent Claim 38 words
A process as recited in claim 1, further comprising: forming a C 60 -covered silicon surface by exposing the silicon substrate surface to C 60 before forming the silicon carbide layer on the C 60 -covered silicon surface.
Claim 12
Dependent Claim 26 words
A process as recited in claim 10, wherein forming the C 60 -covered silicon surface is carried out at a temperature less than about 900 K.
Claim 13
Dependent Claim 17 words
A process as recited in claim 10, wherein the silicon carbide layer and silicon substrate are epitaxial.
Claim 14
Dependent Claim 25 words
A process as recited in claim 1, wherein the silicon substrate is selected from the group consisting of Si (100) wafers and Si (111) wafers.
Claim 15
Dependent Claim 56 words
A process for selectively forming silicon carbide films and microcomponents on a silicon substrate, comprising: forming a silicon carbide layer on a patterned silicon and silicon oxide substrate surface by heating the silicon-silicon oxide surface in the presence of C 60 ; removing the silicon dioxide from the substrate to form a patterned silicon carbide layer.
Claim 16
Dependent Claim 56 words
A process for selectively forming silicon carbide films and microcomponents on a silicon substrate, comprising: forming a silicon carbide layer on a patterned silicon and silicon oxide substrate surface by heating the silicon-silicon oxide surface in the presence of C 60 ; removing the silicon dioxide from the substrate to form a patterned silicon carbide layer.
Claim 17
Dependent Claim 26 words
A process as recited in claim 14, wherein forming the silicon carbide layer is carried out at a temperature between about 900 K and 1250 K.
Claim 18
Dependent Claim 38 words
A process as recited in claim 14, further comprising: forming a C 60 -covered silicon surface by exposing the silicon-silicon oxide surface to C 60 before forming the silicon carbide layer on the C 60 -covered silicon surface.
Claim 19
Dependent Claim 26 words
A process as recited in claim 16, wherein forming the C 60 -covered silicon surface is carried out at a temperature less than about 900 K.
Claim 20
Dependent Claim 47 words
A process for forming carbide films and microcomponents on a metal substrate, comprising: forming a carbide layer on a substrate surface by heating the surface in the presence of C 60 , wherein the substrate is selected from the group consisting of germanium, tantalum, titanium, and tungsten.
Claim 21
Dependent Claim 47 words
A process for forming carbide films and microcomponents on a metal substrate, comprising: forming a carbide layer on a substrate surface by heating the surface in the presence of C 60 , wherein the substrate is selected from the group consisting of germanium, tantalum, titanium, and tungsten.
Claim 22
Dependent Claim 35 words
A process as recited in claim 18, further comprising: forming a C 60 -covered substrate surface by exposing the substrate surface to C 60 before forming the carbide layer on the C 60 -covered surface.

References Cited (Backward Citations)

US5053255A Cited
US5209916A Cited
US5558903A Cited
US5415126A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2002-01-18 2002-07-20 2003-01-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2006-01-18 2006-07-20 2007-01-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2010-01-18 2010-07-20 2011-01-19 $7700.00 Window Closed / Lapsed

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