US5855836A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for selective deposition modeling
Assignee: 3D Systems Inc
•
Filing: 1997-06-12
•
Granted: 1999-01-05
•
Expires: 2017-06-12
Abstract
Abstract A novel thermopolymer material adapted for use in thermal stereolithography. More particularly, a thermopolymer material comprising a mixture of: a low shrinkage polymer resin; a low viscosity material such as paraffin wax; at least one microcrystalline wax; a toughening polymer, a plasticizer. Alternative embodiments further include components to improve the materials ability to transfer heat and to improve strength. The subject material, together with the described process greatly reduce part building distortions while retaining desirable toughness, strength and jetting properties.
Inventors
- 👤 Richard N. Leyden
- 👤 Charles W. Hull
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 17:55
CPC Classifications
B; B29; B29C; B29C64/00; B29C64/10; B29C64/106; B29C64/112; B33; B33Y; B33Y10/00; B33Y70/00
Claims Analysis
Total Claims: 40
Claim 1
Independent Claim
184 words
A selective deposition modeling method of forming at least a portion of a three-dimensional object on a layer-by-layer basis, comprising the steps of: a) generating computer data corresponding to layers of said object; b) providing a building material which is a fluid at at least one temperature between 80° C. and about 140° C., comprising: (i) about 20-80% w of a reactive material; (ii) about 10-30% w of a low shrinkage polymer resin; (iii) about 5-20% w of at least one microcrystalline wax; (iv) about 2-10% w of a toughening polymer; and (v) about 1-3% w of a plasticizer; c) elevating the temperature of said material to a temperature above 80° C. to about 140° C.; d) selectively dispensing said material at said elevated temperature according to said computer data to form a layer of said object; e) providing an environment that lowers the temperature of said dispensed material; f) repeating steps d) and e) to form subsequent layers until at least said portion of the object is formed; and g) reacting the reactive material included in at least one layer of the object.
Claim 2
Dependent Claim
184 words
A selective deposition modeling method of forming at least a portion of a three-dimensional object on a layer-by-layer basis, comprising the steps of: a) generating computer data corresponding to layers of said object; b) providing a building material which is a fluid at at least one temperature between 80° C. and about 140° C., comprising: (i) about 20-80% w of a reactive material; (ii) about 10-30% w of a low shrinkage polymer resin; (iii) about 5-20% w of at least one microcrystalline wax; (iv) about 2-10% w of a toughening polymer; and (v) about 1-3% w of a plasticizer; c) elevating the temperature of said material to a temperature above 80° C. to about 140° C.; d) selectively dispensing said material at said elevated temperature according to said computer data to form a layer of said object; e) providing an environment that lowers the temperature of said dispensed material; f) repeating steps d) and e) to form subsequent layers until at least said portion of the object is formed; and g) reacting the reactive material included in at least one layer of the object.
Claim 3
Dependent Claim
12 words
The method of claim 1 wherein said reactive material is a photopolymer.
Claim 4
Dependent Claim
20 words
The method of claim 1 wherein the temperature of said material is elevated to a temperature about 90° C.-130° C.
Claim 5
Dependent Claim
28 words
The method of claim 1 wherein the temperature of said material is elevated until it has a viscosity in the range of about 18 cps to 25 cps.
Claim 6
Dependent Claim
20 words
The method of claim 1 wherein said material is configured to solidify over a range of at least 10° C.
Claim 7
Dependent Claim
136 words
The method of claim 1 wherein said material comprises: a) about 40-50% w of a photopolymer; b) about 20-30% w of a hydrocarbon resin which is a copolymer of -methylstyrene and vinyl toluene; c) about 15-20% w of a combination of between 5 to 10% w microcrystalline ester wax, between 5 to 10% w soft microcrystalline wax, and between 2 to 5% w hard microcrystalline wax; d) about 5-10% w of a low viscosity polymer with a melting point between 90° C.; e) about 1-5% w of an ethylene-vinyl acetate copolymer with a viscosity of about 575 cps at about 140° C. and a melting point of about 85° C. to 95° C.; f) about 1-5% w of tetrakis methane with a melting point about 110°-125° C.; and g) about 1-5% w of Diisononyl phthalate (DINP).
Claim 8
Dependent Claim
234 words
A selective deposition modeling method of forming at least a portion of a three dimensional object on a layer-by-layer basis comprising the steps of: a) generating computer data corresponding to the layers of said object; b) providing a building material which is solid at ambient temperature and a fluid at at least one temperature between about 80° C. and about 140° C. comprising: i) a low shrinkage thermoplastic resin, ii) at least a first microcrystalline wax, said microcrystalline wax being present in an amount such that the building material solidifies over a broad temperature range, and iii) a low viscosity polymer, said low viscosity polymer being present in an amount such that the viscosity of the building material when heated to a dispensable fluid state is suitable for delivery through a dispenser in a selective deposition modeling system; c) elevating the temperature of said building material to a temperature in the range of about 80° C. and about 140° C. to cause said building material to become fluid; d) selectively dispensing said building material in accordance with said computer data to form a cross-section of said three dimensional object when said material is elevated to a temperature in said range; e) providing an environment that lowers the temperature of said dispensed building material; and f) repeating steps d) and e) to form subsequent layers until at least said portion of the object is formed.
Claim 9
Dependent Claim
234 words
A selective deposition modeling method of forming at least a portion of a three dimensional object on a layer-by-layer basis comprising the steps of: a) generating computer data corresponding to the layers of said object; b) providing a building material which is solid at ambient temperature and a fluid at at least one temperature between about 80° C. and about 140° C. comprising: i) a low shrinkage thermoplastic resin, ii) at least a first microcrystalline wax, said microcrystalline wax being present in an amount such that the building material solidifies over a broad temperature range, and iii) a low viscosity polymer, said low viscosity polymer being present in an amount such that the viscosity of the building material when heated to a dispensable fluid state is suitable for delivery through a dispenser in a selective deposition modeling system; c) elevating the temperature of said building material to a temperature in the range of about 80° C. and about 140° C. to cause said building material to become fluid; d) selectively dispensing said building material in accordance with said computer data to form a cross-section of said three dimensional object when said material is elevated to a temperature in said range; e) providing an environment that lowers the temperature of said dispensed building material; and f) repeating steps d) and e) to form subsequent layers until at least said portion of the object is formed.
Claim 10
Dependent Claim
22 words
The method of claim 7 wherein the building material shrinks about 11% on cooling from about 130° C. to about 25° C.
Claim 11
Dependent Claim
24 words
The method of claim 8 wherein the building material transforms from a liquid to a solid over a temperature range of about 10° C.
Claim 12
Dependent Claim
28 words
The method of claim 9 wherein the building material has a viscosity from about 18 to 25 cps at a temperature from about 125° to about 130° C.
Claim 13
Dependent Claim
194 words
A selective deposition modeling method of forming at least a portion of a three dimensional object on a layer-by-layer basis comprising the steps of: a) generating computer data corresponding to the layers of said object; b) providing a building material which is solid at ambient temperature and a fluid at at least one temperature between about 80° C. and about 140° C. comprising: i) about 10-30% w of at least one microcrystalline wax, ii) about 20-60% w of a low shrinkage material, iii) about 10-40% w of a low viscosity material, said low viscosity material not being included in i) or ii) above; and iv) about 2-25% w of a toughening polymer c) elevating the temperature of said building material to a temperature in the range of about 80° C. and about 140° C.; d) selectively dispensing a layer of said building material in accordance with said computer data to form a layer of said three dimensional object; e) providing an environment that lowers the temperature of said dispensed building material; and D repeating steps d) and e) to form subsequent layers until at least said portion of said three dimensional object is formed.
Claim 14
Dependent Claim
194 words
A selective deposition modeling method of forming at least a portion of a three dimensional object on a layer-by-layer basis comprising the steps of: a) generating computer data corresponding to the layers of said object; b) providing a building material which is solid at ambient temperature and a fluid at at least one temperature between about 80° C. and about 140° C. comprising: i) about 10-30% w of at least one microcrystalline wax, ii) about 20-60% w of a low shrinkage material, iii) about 10-40% w of a low viscosity material, said low viscosity material not being included in i) or ii) above; and iv) about 2-25% w of a toughening polymer c) elevating the temperature of said building material to a temperature in the range of about 80° C. and about 140° C.; d) selectively dispensing a layer of said building material in accordance with said computer data to form a layer of said three dimensional object; e) providing an environment that lowers the temperature of said dispensed building material; and D repeating steps d) and e) to form subsequent layers until at least said portion of said three dimensional object is formed.
Claim 15
Dependent Claim
17 words
The method of claim 11 wherein the building material further comprises about 1-5% w of a plasticizer.
Claim 16
Dependent Claim
16 words
The method of claim 11 wherein the selective deposition modeling method is a thermal stereolithography method.
Claim 17
Dependent Claim
15 words
The method of claim 13 wherein the material is dispensed from an ink jet device.
Claim 18
Dependent Claim
33 words
The method of claim 11 wherein said building material is configured to have a viscosity between about 7 to 28 cps at at least one temperature between about 125° C. and 135° C.
Claim 19
Independent Claim
38 words
The method of claimed 11 wherein the temperature of said material is elevated into said range of temperatures to a temperature such that it has a viscosity for dispensing of between about 7 cps to about 28 cps.
Claim 20
Dependent Claim
26 words
The method of claim 11 wherein said material is dispensed into an environment which is within about 10° C. of a solidus temperature of the material.
Claim 21
Dependent Claim
16 words
The method of claim 1 wherein the selective deposition modeling method is a thermal stereolithography method.
Claim 22
Dependent Claim
14 words
The method of claim 18 wherein the material is dispensed using an ink jet.
Claim 23
Dependent Claim
26 words
The method of claim 1 wherein said material is dispensed into an environment which is within about 10° C. of a solidus temperature of the material.
Claim 24
Dependent Claim
16 words
The method of claim 7 wherein the selective deposition modeling method is a thermal stereolithography method.
Claim 25
Dependent Claim
15 words
The method of claim 21 wherein the material is dispensed from an ink jet device.
Claim 26
Dependent Claim
27 words
The method of claim 7 wherein the building material is dispensed into an environment which is within about 10° C. of a solidus temperature of the material.
Claim 27
Dependent Claim
27 words
The method of claim 7 wherein the building material has a viscosity of about 7-28 cps at a temperature of about 125° C. to about 135° C.
Claim 28
Dependent Claim
25 words
The method of claim 8 wherein the building material transforms from a liquid to a solid over a temperature range of at least 10° C.
Claim 29
Dependent Claim
10 words
The method of claim 7 additionally comprising a coloring agent.
Claim 30
Dependent Claim
10 words
The method of claim 11 additionally comprising a coloring agent.
Claim 31
Dependent Claim
15 words
The method of claim 20 comprising up to about 2.0% w of the coloring agent.
Claim 32
Dependent Claim
27 words
The method of claim 7 additionally comprising the formation of a support structure from the building material, the support structure being removed after formation of the object.
Claim 33
Dependent Claim
27 words
The method of claim 11 additionally comprising the formation of a support structure from the building material, the support structure being removed after formation of the object.
Claim 34
Dependent Claim
27 words
The method of claim 1 wherein said building material is configured to have a viscosity of less than 25 cps at a temperature of about 90° C.
Claim 35
Dependent Claim
28 words
The method of claim 12 wherein said building material is configured to have a viscosity between about 18 and 25 cps at a temperature of about 130° C.
Claim 36
Dependent Claim
27 words
The method of claim 12 wherein said building material is configured to have a viscosity of less than 25 cps at a temperature of about 130° C.
Claim 37
Dependent Claim
23 words
The method of claim 32 wherein the temperature of said material is elevated to a temperature of about 125° C. and 135° C.
Claim 38
Dependent Claim
31 words
The method of claim 12 wherein the temperature of said material is elevated until it has a viscosity for dispensing in the range of about 18 cps to about 25 cps.
Claim 39
Dependent Claim
20 words
The method of claim 32 wherein said material is configured to solidify over a range of at least 10° C.
Claim 40
Dependent Claim
115 words
The method of claim 32 wherein said material comprises; a) about 20% w of a paraffin wax; b) about 50% w of a hydrocarbon resin which is a copolymer of α-methylstyrene and vinyl toluene; c) a combination of between 10 to 15% w medium hard microcrystalline ester wax, between 5 to 20% w soft microcrystalline wax and between 5 to 10% w hard microcrystalline wax; d) about 1-5% w of an ethylene-vinyl acetate copolymer with a viscosity of about 140° C. and a melting point of about 85° to 95° C.; e) about 1-5% w of tetrakis methane with a melting point of about 110°-125° C.; and f) about 1-5% w of Diisonony phthalate (DINP).
References Cited (Backward Citations)
US2775758A
Cited
US4041476A
Cited
US3947853A
Cited
JPS5110813A
Cited
GB1556451A
Cited
US4247508A
Cited
US4247508B1
Cited
US4490728A
Cited
US4537631A
Cited
US4484948A
Cited
US4390369A
Cited
US4659383A
Cited
US4386961A
Cited
US4665492A
Cited
US4575330A
Cited
US4575330B1
Cited
US4631557B1
Cited
US4593292A
Cited
US4631557A
Cited
US4667206A
Cited
FR2583333A1
Cited
FR2583334A1
Cited
US4749347A
Cited
US4714934A
Cited
US4992806A
Cited
EP0250121A2
Cited
US4961154A
Cited
US4752498A
Cited
US4951067A
Cited
US4751528B1
Cited
WO1989002575A1
Cited
US4751528A
Cited
US4801477A
Cited
US5031120A
Cited
EP0322257A2
Cited
US5021802A
Cited
US5041161A
Cited
US4999143A
Cited
US5141680A
Cited
US5043741A
Cited
WO1990001727A1
Cited
US4942060A
Cited
US5140937A
Cited
US5059266A
Cited
US5075689A
Cited
US5216616A
Cited
US5134569A
Cited
US5121329A
Cited
US5340433A
Cited
EP0426363A2
Cited
US5136515A
Cited
WO1991008902A1
Cited
WO1991010711A1
Cited
JPH03236940A
Cited
US5171360A
Cited
US5126529A
Cited
US5303141A
Cited
US5506607A
Cited
US5260009A
Cited
EP0581445A1
Cited
US5312224A
Cited
US5362427A
Cited
US5572431A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2002-01-04 | 2002-07-06 | 2003-01-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2006-01-04 | 2006-07-06 | 2007-01-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2010-01-04 | 2010-07-06 | 2011-01-05 | $7700.00 | Window Closed / Lapsed |