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US5854102A Expired / Lapsed US ⏱️ 0.0 years remaining

Vertical diode structures with low series resistance

Assignee: Micron Technology Inc
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Filing: 1997-09-05
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Granted: 1998-12-29
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Expires: 2017-09-05
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Abstract

Abstract A vertical diode is provided having a diode opening extending through an insulation layer and contacting an active region on a silicon wafer. A titanium silicide layer covers the interior surface of the diode opening and contacts the active region. The diode opening is initially filled with an amorphous silicon plug that is doped during deposition and subsequently recrystallized to form large grain polysilicon. The silicon plug has a top portion that is heavily doped with a first type dopant and a bottom portion that is lightly doped with a second type dopant. The top portion is bounded by the bottom portion so as not to contact the titanium silicide layer. For one embodiment of the vertical diode, a programmable resistor contacts the top portion of the silicon plug and a metal line contacts the programmable resistor.

Inventors

  • 👤 Fernando Gonzalez
  • 👤 Tyler A. Lowrey
  • 👤 Trung Tri Doan
  • 👤 Raymond A. Turi
  • 👤 Graham R. Wolstenholme

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 10:42
CPC Classifications
H; H10; H10D; H10D8/00; H10D8/01; H10D8/045; H10D84/00; H10D84/201; H10D84/204; H10D84/221; Y; Y10; Y10S; Y10S257/00; Y10S257/91; Y10S438/00; Y10S438/979

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 209 words
A method for forming a diode on a silicon wafer, the silicon wafer having an exposed surface and being doped with a first conductivity type dopant, the method comprising the steps of: (a) highly doping a portion of the exposed surface of the silicon wafer with a second conductivity type dopant to form an active region; (b) disposing a first refractory metal silicide layer over said active region; (c) forming a layer of insulation material over said first refractory metal silicide layer; (d) etching a diode opening through said layer of insulation material to expose a portion of said first refractory metal silicide layer, said diode opening being defined by an interior surface; (e) filling said diode opening with an amorphous silicon to form a silicon plug, said silicon plug comprising a bottom portion contacting said active region and a top portion separated from said active region by said bottom portion; (f) lightly doping said amorphous silicon with said second conductivity type of dopant; (g) heating said amorphous silicon to convert said amorphous silicon to large grain polysilicon; (h) highly doping said top portion of said silicon plug with said first conductivity type of dopant; and (i) securing a metal contact onto said top portion of said silicon plug.
Claim 2
Independent Claim 209 words
A method for forming a diode on a silicon wafer, the silicon wafer having an exposed surface and being doped with a first conductivity type dopant, the method comprising the steps of: (a) highly doping a portion of the exposed surface of the silicon wafer with a second conductivity type dopant to form an active region; (b) disposing a first refractory metal silicide layer over said active region; (c) forming a layer of insulation material over said first refractory metal silicide layer; (d) etching a diode opening through said layer of insulation material to expose a portion of said first refractory metal silicide layer, said diode opening being defined by an interior surface; (e) filling said diode opening with an amorphous silicon to form a silicon plug, said silicon plug comprising a bottom portion contacting said active region and a top portion separated from said active region by said bottom portion; (f) lightly doping said amorphous silicon with said second conductivity type of dopant; (g) heating said amorphous silicon to convert said amorphous silicon to large grain polysilicon; (h) highly doping said top portion of said silicon plug with said first conductivity type of dopant; and (i) securing a metal contact onto said top portion of said silicon plug.
Claim 3
Dependent Claim 97 words
A method for forming a diode as recited in claim 1, wherein said step of disposing a first refractory metal silicide layer comprises: (a) depositing a refractory metal layer over said active region; (b) heating said refractory metal layer in a nitrogen rich environment so that a portion of the refractory metal layer reacts with the silicon wafer to form said refractory metal silicide layer and a portion of said refractory metal layer reacts with the nitrogen to form a nitride; and (c) etching said nitride to remove said nitride and leave said refractory metal silicide layer.
Claim 4
Dependent Claim 49 words
A method for forming a diode as recited in claim 1, wherein said filling step further comprises: (a) depositing a layer of said amorphous silicon over said layer of insulation material and within said diode opening; and (b) removing said layer of amorphous silicon overlying said layer of insulation.
Claim 5
Dependent Claim 20 words
A method for forming a diode as recited in claim 3, wherein said removing step is a chemical-mechanical polishing step.
Claim 6
Dependent Claim 31 words
A method for forming a diode as recited in claim 1, wherein said heating step is performed at a temperature in a range between about 450° C. to about 550° C.
Claim 7
Dependent Claim 45 words
A method for forming a diode as recited in claim 1, wherein said heating step is performed at a temperature and over a time sufficient to form polysilicon having an average diameter grain size in a range between about 0.3 microns to about 0.8 microns.
Claim 8
Dependent Claim 63 words
A method for forming a diode as recited in claim 1, wherein said step of highly doping said top portion of said silicon plug comprises: (a) implanting ions of said first type of dopant within said top portion of said silicon plug; and (b) annealing said top portion of said silicon plug having said ions of said first type of dopant implanted therein.
Claim 9
Dependent Claim 19 words
A method for forming a diode as recited in claim 7, wherein said annealing step is an RTP step.
Claim 10
Dependent Claim 41 words
A method for forming a diode as recited in claim 1, wherein said securing step comprises: (a) positioning a programmable resistor in contact with said top portion of said silicon plug; and (b) contacting said metal contact to said programmable resistor.
Claim 11
Dependent Claim 49 words
A method for forming a diode as recited in claim 9, wherein the step of positioning a programmable resistor comprises: (a) depositing a layer of chalcaginide material in contact with said top portion of said silicon plug; and (b) forming a layer of titanium nitride over said chalcaginide material.
Claim 12
Dependent Claim 32 words
A method for forming a diode as recited in claim 1, wherein said etching step farther comprises disposing a second refractory metal silicide layer on said interior surface of said diode opening.
Claim 13
Dependent Claim 84 words
A method for forming a diode as recited in claim 11, wherein said step of disposing a second refractory metal silicide layer comprises: (a) covering said interior surface of said diode opening with a polysilicon layer; (b) applying a refractory metal layer over said polysilicon layer; and (c) exposing said refractory metal layer to a temperature sufficient to chemically react said polysilicon layer with said refractory metal layer to form said second refractory metal silicide layer on said interior surface of said diode opening.
Claim 14
Dependent Claim 42 words
A method for forming a diode as recited in claim 11, wherein said filling step comprises said top portion of said silicon plug being partially bounded by said bottom portion so as to be separated from said second refractory metal silicide layer.
Claim 15
Dependent Claim 85 words
A method for forming a diode as recited in claim 13, wherein said securing step comprises: (a) positioning a insulative silicon layer on said insulation layer and over said diode opening; (b) etching a passageway through said insulative silicon layer and down to said top portion of said silicon plug; (c) positioning a programmable resistor over said insulative silicon layer and within said passageway so as to contact said top portion of said silicon plug; and (d) contacting said metal contact to said programmable resistor.
Claim 16
Independent Claim 430 words
A method for forming a diode on a silicon wafer, the silicon wafer having an exposed surface and being doped with a first conductivity type dopant, the method comprising the steps of: (a) highly doping a portion of the exposed surface of the silicon wafer with a second conductivity type dopant to form an active region; (b) disposing a first refractory metal silicide layer over said active region; (c) forming a layer of insulation material over said first refractory metal silicide layer; (d) etching a diode opening through said layer of insulation material to expose a portion of said first refractory metal silicide layer, said diode opening being defined by an interior surface; (e) covering said layer of insulation material and said interior surface of said diode opening with a polysilicon layer; (f) applying a refractory metal layer over said polysilicon layer; (g) exposing said refractory metal layer to a temperature sufficient to chemically react said polysilicon layer with said refractory metal layer to form a second refractory metal silicide layer positioned over said layer of insulation material and on said interior surface of said diode opening; (h) depositing a layer of said amorphous silicon over said refractory metal silicide layer so as to fill said diode opening; (i) removing said layer of amorphous silicon and said second refractory metal silicide layer overlying said layer of insulation to form a silicon plug within said diode opening, said silicon plug comprising a bottom portion contacting said second refractory metal silicide layer lining said diode opening and a top portion partially bounded by said bottom portion so as to be separated from said second refractory metal silicide layer; (j) lightly doping said amorphous silicon with said second conductivity type of dopant; (k) heating said amorphous silicon to convert said amorphous silicon to large grain polysilicon; (l) implanting a high concentration of ions of said first conductivity type of dopant within said top portion of said silicon plug; (m) annealing said top portion of said silicon plug having said ions of said first type of dopant implanted therein; (n) positioning an insulative silicon layer on said layer of insulation and over said diode opening; (o) etching a passageway through said insulative silicon layer and down to said top portion of said silicon plug; (p) placing a layer of chalcaginide material over said insulative silicon layer and within said passageway so as to contact said top portion of said silicon plug; (q) locating a layer of titanium nitride over said chalcaginide material; and (r) securing a metal contact onto said layer of titanium nitride.
Claim 17
Independent Claim 430 words
A method for forming a diode on a silicon wafer, the silicon wafer having an exposed surface and being doped with a first conductivity type dopant, the method comprising the steps of: (a) highly doping a portion of the exposed surface of the silicon wafer with a second conductivity type dopant to form an active region; (b) disposing a first refractory metal silicide layer over said active region; (c) forming a layer of insulation material over said first refractory metal silicide layer; (d) etching a diode opening through said layer of insulation material to expose a portion of said first refractory metal silicide layer, said diode opening being defined by an interior surface; (e) covering said layer of insulation material and said interior surface of said diode opening with a polysilicon layer; (f) applying a refractory metal layer over said polysilicon layer; (g) exposing said refractory metal layer to a temperature sufficient to chemically react said polysilicon layer with said refractory metal layer to form a second refractory metal silicide layer positioned over said layer of insulation material and on said interior surface of said diode opening; (h) depositing a layer of said amorphous silicon over said refractory metal silicide layer so as to fill said diode opening; (i) removing said layer of amorphous silicon and said second refractory metal silicide layer overlying said layer of insulation to form a silicon plug within said diode opening, said silicon plug comprising a bottom portion contacting said second refractory metal silicide layer lining said diode opening and a top portion partially bounded by said bottom portion so as to be separated from said second refractory metal silicide layer; (j) lightly doping said amorphous silicon with said second conductivity type of dopant; (k) heating said amorphous silicon to convert said amorphous silicon to large grain polysilicon; (l) implanting a high concentration of ions of said first conductivity type of dopant within said top portion of said silicon plug; (m) annealing said top portion of said silicon plug having said ions of said first type of dopant implanted therein; (n) positioning an insulative silicon layer on said layer of insulation and over said diode opening; (o) etching a passageway through said insulative silicon layer and down to said top portion of said silicon plug; (p) placing a layer of chalcaginide material over said insulative silicon layer and within said passageway so as to contact said top portion of said silicon plug; (q) locating a layer of titanium nitride over said chalcaginide material; and (r) securing a metal contact onto said layer of titanium nitride.
Claim 18
Dependent Claim 20 words
A method for forming a diode as recited in claim 15, wherein said removing step is a chemical-mechanical polishing step.
Claim 19
Dependent Claim 31 words
A method for forming a diode as recited in claim 15, wherein said heating step is performed at a temperature in a range between about 450° C. to about 550° C.
Claim 20
Dependent Claim 45 words
A method for forming a diode as recited in claim 15, wherein said heating step is performed at a temperature and over a time sufficient to form polysilicon having an average diameter grain size in a range between about 0.3 microns to about 0.8 microns.
Claim 21
Dependent Claim 19 words
A method for forming a diode as recited in claim 15, wherein said annealing step is an RTP step.

References Cited (Backward Citations)

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JPS6322195A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2001-12-28 2002-06-29 2002-12-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2005-12-28 2006-06-29 2006-12-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2009-12-28 2010-06-29 2010-12-29 $7700.00 Window Closed / Lapsed

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