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Apparatus and method for forming three-dimensional objects in stereolithography utilizing a laser exposure system having a diode pumped frequency quadrupled solid state laser

Assignee: 3D Systems Inc
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Filing: 1997-01-31
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Granted: 1998-11-24
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Expires: 2017-01-31
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Abstract

Abstract Embodiments of the instant invention are directed to laser exposure systems that employ a pulsed solid state laser to provide a reactive response wavelength and a pulse repetition rate specifically optimized for application to solidification of a liquid photopolymer in a stereolithographic process. The solid state laser employs two second harmonic crystals for generating an emission wavelength at about 320-345 nm and a pulse repetition rate, wherein the pulse repetition rate is selected such that a resulting pulse separation at the target surface is less than a width of the beam when the beam is being scanned at a desired velocity and an average exposure deposited by the beam is equal to a desired amount.

Inventors

  • 👤 Jouni P. Partanen
  • 👤 William F. Hug

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 03:16
CPC Classifications
B; B29; B29C; B29C64/00; B29C64/10; B29C64/106; B29C64/124; B29C64/129; B29C64/135; B33; B33Y; B33Y10/00; B33Y30/00

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 185 words
A method of forming a 3D object from a solidifiable medium, comprising the steps of: forming a coating of solidifiable medium adjacent to a previously formed lamina in preparation for forming a subsequent lamina of said object; selectively exposing a target surface of said solidifiable medium to a beam of pulses of electromagnetic radiation, having a desired pulse repetition rate, to form a subsequent lamina of the object and to adhere said subsequent lamina to said previously formed lamina; and repeating the forming and exposing steps to form the three-dimensional object from a plurality of adhered laminae; wherein the pulse repetition rate is selected to be equal to or greater than that given in ##EQU2## wherein V s is a scanning speed of the beam, W o is a half width of the beam at 1/e 2 of a peak irradiance distribution of the beam, P L is a power of the beam, E c is a critical exposure of the medium, C d is a desired cure depth, and D p is a penetration depth (1/e absorption depth) of the beam in the medium.
Claim 2
Independent Claim 185 words
A method of forming a 3D object from a solidifiable medium, comprising the steps of: forming a coating of solidifiable medium adjacent to a previously formed lamina in preparation for forming a subsequent lamina of said object; selectively exposing a target surface of said solidifiable medium to a beam of pulses of electromagnetic radiation, having a desired pulse repetition rate, to form a subsequent lamina of the object and to adhere said subsequent lamina to said previously formed lamina; and repeating the forming and exposing steps to form the three-dimensional object from a plurality of adhered laminae; wherein the pulse repetition rate is selected to be equal to or greater than that given in ##EQU2## wherein V s is a scanning speed of the beam, W o is a half width of the beam at 1/e 2 of a peak irradiance distribution of the beam, P L is a power of the beam, E c is a critical exposure of the medium, C d is a desired cure depth, and D p is a penetration depth (1/e absorption depth) of the beam in the medium.
Claim 3
Independent Claim 151 words
A method of forming a 3D object from a solidifiable medium, comprising the steps of: forming a coating of solidifiable medium adjacent to a previously formed lamina in preparation for forming a subsequent lamina of said object; selectively exposing a target surface of said solidifiable medium to a beam of pulses of electromagnetic radiation, having a desired pulse repetition rate, to form a subsequent lamina of the object and to adhere said subsequent lamina to said previously formed lamina; and repeating the forming and exposing steps to form the three-dimensional object from a plurality of adhered laminae; wherein the pulse repetition rate is selected to result in a pulse separation at said target surface to be less than or equal to an effective width of said beam when said beam is being scanned at a desired velocity and an average exposure deposited by said beam is equal to a desired amount.
Claim 4
Independent Claim 151 words
A method of forming a 3D object from a solidifiable medium, comprising the steps of: forming a coating of solidifiable medium adjacent to a previously formed lamina in preparation for forming a subsequent lamina of said object; selectively exposing a target surface of said solidifiable medium to a beam of pulses of electromagnetic radiation, having a desired pulse repetition rate, to form a subsequent lamina of the object and to adhere said subsequent lamina to said previously formed lamina; and repeating the forming and exposing steps to form the three-dimensional object from a plurality of adhered laminae; wherein the pulse repetition rate is selected to result in a pulse separation at said target surface to be less than or equal to an effective width of said beam when said beam is being scanned at a desired velocity and an average exposure deposited by said beam is equal to a desired amount.
Claim 5
Dependent Claim 37 words
A method as claimed in claim 2 wherein the electromagnetic radiation has a wavelength within the range of wavelengths which have reactive responses which are within about 50% of the peak reactive response of the solidifiable medium.
Claim 6
Dependent Claim 18 words
A method as claimed in claim 3 wherein the electromagnetic radiation is produced by a solid state laser.
Claim 7
Dependent Claim 19 words
The method of claim 3 wherein the wavelength of said electromagnetic radiation is in the range of 320-345 nM.
Claim 8
Dependent Claim 19 words
The method of claim 3 wherein the wavelength of said electromagnetic radiation is in the range of 328-337 nM.
Claim 9
Dependent Claim 28 words
The method of claim 4 wherein a stimulated emission cross-section for the fundamental wavelength yielding the wavelength of electromagnetic radiation is greater than 1×10 -19 cm 2 .
Claim 10
Dependent Claim 30 words
The method of claim 3 wherein the electromagnetic radiation is obtained from a frequency quadrupled Q switched 1342 nM Nd:YVO 4 laser providing an output wavelength of approproximately 335 nM.
Claim 11
Dependent Claim 29 words
The method of claim 3 wherein the electromagnetic radiation is obtained from a frequency quadrupled Q switched 1328 nM Nd:S--FAP laser providing an output wavelength of approproximately 332 nM.
Claim 12
Dependent Claim 13 words
The method of claim 3 wherein the pulse rate is greater 10 Khz.
Claim 13
Dependent Claim 13 words
The method of claim 3 wherein the pulse rate is greater 20 Khz.
Claim 14
Dependent Claim 13 words
The method of claim 3 wherein the pulse rate is greater 30 Khz.
Claim 15
Independent Claim 125 words
A method of forming a 3D object from a solidifiable medium, comprising the steps of: forming a coating of solidifiable medium adjacent to a previously formed lamina in preparation for forming a subsequent lamina of said object; selectively exposing a target surface of said solidifiable medium to a beam of electromagnetic radiation produced by a solid state laser to form a subsequent lamina of the object and to adhere said subsequent lamina to said previously formed lamina; and repeating the forming and exposing steps to form the three-dimensional object from a plurality of adhered laminae; wherein the electromagnetic radiation has a wavelength within the range of wavelengths which have reactive responses which are within about 50% of the peak reactive response of the solidifiable medium.
Claim 16
Independent Claim 125 words
A method of forming a 3D object from a solidifiable medium, comprising the steps of: forming a coating of solidifiable medium adjacent to a previously formed lamina in preparation for forming a subsequent lamina of said object; selectively exposing a target surface of said solidifiable medium to a beam of electromagnetic radiation produced by a solid state laser to form a subsequent lamina of the object and to adhere said subsequent lamina to said previously formed lamina; and repeating the forming and exposing steps to form the three-dimensional object from a plurality of adhered laminae; wherein the electromagnetic radiation has a wavelength within the range of wavelengths which have reactive responses which are within about 50% of the peak reactive response of the solidifiable medium.
Claim 17
Dependent Claim 29 words
The method of claim 2, wherein said effective width of said beam is equal to a width of cure associated with a single pulse of said beam of pulses.
Claim 18
Independent Claim 196 words
A method of forming a three-dimensional object from a solidifiable medium, comprising the steps of: forming a coating of solidifiable medium adjacent to a previously formed lamina in preparation for forming a subsequent lamina of said object; selectively exposing a target surface of said solidifiable medium to a beam of pulses of electromagnetic radiation, having a desired pulse repetition rate, to form a subsequent lamina of the object and to adhere said subsequent lamina to said previously formed lamina, wherein exposure of said solidifiable medium to a pulse of said beam results in a subcritical region of partially polymerized solidifiable medium adjacent to a solidified portion of said solidifiable medium; and repeating the forming and exposing steps to form the three-dimensional object from a plurality of adhered laminae; wherein the pulse repetition rate is selected to result in a pulse separation at said target surface to be greater than an effective width of said beam and wherein said subcritical regions of sufficiently overlap to exceed a critical exposure for said subcritical regions when said beam is being scanned at a desired velocity and an average exposure deposited by said beam is equal to a desired amount.
Claim 19
Independent Claim 196 words
A method of forming a three-dimensional object from a solidifiable medium, comprising the steps of: forming a coating of solidifiable medium adjacent to a previously formed lamina in preparation for forming a subsequent lamina of said object; selectively exposing a target surface of said solidifiable medium to a beam of pulses of electromagnetic radiation, having a desired pulse repetition rate, to form a subsequent lamina of the object and to adhere said subsequent lamina to said previously formed lamina, wherein exposure of said solidifiable medium to a pulse of said beam results in a subcritical region of partially polymerized solidifiable medium adjacent to a solidified portion of said solidifiable medium; and repeating the forming and exposing steps to form the three-dimensional object from a plurality of adhered laminae; wherein the pulse repetition rate is selected to result in a pulse separation at said target surface to be greater than an effective width of said beam and wherein said subcritical regions of sufficiently overlap to exceed a critical exposure for said subcritical regions when said beam is being scanned at a desired velocity and an average exposure deposited by said beam is equal to a desired amount.
Claim 20
Dependent Claim 24 words
The method of claim 15, wherein said solidified portion of said solidifiable medium is surrounded by said subcritical region of partially polymerized solidifiable medium.

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