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US5837581A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for forming a capacitor using a hemispherical-grain structure

Assignee: Taiwan Semiconductor Manufacturing Co TSMC Ltd
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Filing: 1997-04-04
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Granted: 1998-11-17
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Expires: 2017-04-04
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Abstract

Abstract An improved method for forming a dynamic random access memory (DRAM) capacitor with increased capacitance includes depositing a first oxide layer over a substrate, and patterning a first photoresist layer on the first oxide layer, thereby defining a node contact area. A node trench is etched in the first oxide layer using the first photoresist as a mask. Afterwards, a polysilicon layer is deposited on the first oxide layer, and a second photoresist layer is patterned on this polysilicon layer, defining an electrode area. A hemispherical-grain (HSG) polysilicon layer is deposited on the polysilicon layer and the first oxide layer. The HSG polysilicon layer is then etched back to form a HSG spacer on the sidewalls of the polysilicon layer, and to form a large number of micro-grooves in the upper portion of the polysilicon layer corresponding to the HSG topography of the HSG polysilicon layer. A nitride layer is then conformally deposited to line the micro-grooves. A second oxide layer is then deposited on the nitride layer, filling the nitride-lined micro-grooves with oxide. The second oxide layer is then anisotropically etched back, leaving a nitride/oxide fill in the micro-grooves. The polysilicon layer is then anisotropically etched using the nitride/oxide fill as an etching mask, thereby forming a large number of closely packed narrow trenches in the polysilicon layer. The second oxide layer and the silicon nitride layer are then removed.

Inventors

  • 👤 Chih-Hsiung Cheng

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 14:54
CPC Classifications
H; H10; H10B; H10B12/00; H10B12/30; H10B12/31; H10B12/318; H10B12/01; H10B12/02; H10B12/03; H10B12/033; Y; Y10; Y10S; Y10S438/00; Y10S438/964

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 377 words
A method for forming a capacitor in an integrated circuit, said method comprising: forming a first oxide layer over a substrate; forming a first photoresist layer over said first oxide layer, said photoresist layer defining a node contact area; removing a portion of said first oxide layer using said first photoresist layer as a mask, thereby forming a node trench in said first oxide layer, said node trench exposing a portion of said substrate; forming a polysilicon layer on said first oxide layer, said polysilicon layer filling said node trench in said first oxide layer; forming a second photoresist layer on said polysilicon layer, said second photoresist layer defining an electrode area; removing portions of said polysilicon layer left uncovered by said second photoresist layer, wherein portions of said first oxide layer uncovered by said second photoresist layer are exposed; forming a hemispherical-grain (HSG) polysilicon layer on said polysilicon layer and said exposed portions of said first oxide layer; etching back said HSG polysilicon layer until portions of said first oxide layer are exposed, wherein a plurality of grooves is formed in an upper portion of said polysilicon layer, said plurality of grooves corresponding to grooves between grains of said HSG polysilicon layer; forming a conformal silicon nitride layer on said first oxide layer and said polysilicon layer, wherein said silicon nitride layer lines said plurality of grooves; forming a second oxide layer on said silicon nitride layer, wherein said plurality of nitride-lined grooves is filled with oxide of said second oxide layer; anisotropically etching back said second oxide layer until portions of said silicon nitride layer aligned between said plurality of grooves are exposed, wherein residual oxide from said second oxide layer remains in said plurality of nitride-lined grooves; removing said exposed portions of said silicon nitride layer, wherein portions of said polysilicon layer are exposed; anisotropically etching said exposed portions of said polysilicon layer using said residual oxide in said plurality of nitride-lined grooves as a mask, wherein a plurality of trenches is formed in the polysilicon layer aligned between said plurality of nitride-lined grooves; removing said residual oxide; removing remaining portions of said silicon nitride layer; forming a conformal dielectric layer on said polysilicon layer; and forming a conductive layer on said dielectric layer.
Claim 2
Independent Claim 377 words
A method for forming a capacitor in an integrated circuit, said method comprising: forming a first oxide layer over a substrate; forming a first photoresist layer over said first oxide layer, said photoresist layer defining a node contact area; removing a portion of said first oxide layer using said first photoresist layer as a mask, thereby forming a node trench in said first oxide layer, said node trench exposing a portion of said substrate; forming a polysilicon layer on said first oxide layer, said polysilicon layer filling said node trench in said first oxide layer; forming a second photoresist layer on said polysilicon layer, said second photoresist layer defining an electrode area; removing portions of said polysilicon layer left uncovered by said second photoresist layer, wherein portions of said first oxide layer uncovered by said second photoresist layer are exposed; forming a hemispherical-grain (HSG) polysilicon layer on said polysilicon layer and said exposed portions of said first oxide layer; etching back said HSG polysilicon layer until portions of said first oxide layer are exposed, wherein a plurality of grooves is formed in an upper portion of said polysilicon layer, said plurality of grooves corresponding to grooves between grains of said HSG polysilicon layer; forming a conformal silicon nitride layer on said first oxide layer and said polysilicon layer, wherein said silicon nitride layer lines said plurality of grooves; forming a second oxide layer on said silicon nitride layer, wherein said plurality of nitride-lined grooves is filled with oxide of said second oxide layer; anisotropically etching back said second oxide layer until portions of said silicon nitride layer aligned between said plurality of grooves are exposed, wherein residual oxide from said second oxide layer remains in said plurality of nitride-lined grooves; removing said exposed portions of said silicon nitride layer, wherein portions of said polysilicon layer are exposed; anisotropically etching said exposed portions of said polysilicon layer using said residual oxide in said plurality of nitride-lined grooves as a mask, wherein a plurality of trenches is formed in the polysilicon layer aligned between said plurality of nitride-lined grooves; removing said residual oxide; removing remaining portions of said silicon nitride layer; forming a conformal dielectric layer on said polysilicon layer; and forming a conductive layer on said dielectric layer.
Claim 3
Dependent Claim 32 words
The method according to claim 1, wherein said substrate comprises a metal-oxide-semiconductor transistor formed in and on the substrate, said metal-oxide-semiconductor transistor being a part of a dynamic random access memory cell.
Claim 4
Dependent Claim 29 words
The method according to claim 1, wherein said HSG polysilicon layer is formed using a chemical vapor deposition process with a temperature in a range of about 530°˜600° C.
Claim 5
Dependent Claim 21 words
The method according to claim 1, wherein said silicon nitride layer has a thickness in a range of about 100˜900 angstroms.
Claim 6
Dependent Claim 24 words
The method according to claim 1, wherein each trench of said plurality of trenches has a width in a range of about 100˜1000 angstroms.
Claim 7
Dependent Claim 38 words
The method according to claim 1, wherein adjacent trenches of said plurality of trenches define a plurality of vertically extending fins, each vertically extending fin of said plurality of vertically extending fins having a width of 500 angstroms.
Claim 8
Dependent Claim 15 words
The method according to claim 1, wherein said conformal dielectric layer comprises an oxide-nitride-oxide layer.
Claim 9
Dependent Claim 27 words
The method according to claim 1, wherein a HSG spacer is formed on a sidewall of said polysilicon layer when said HSG polysilicon layer is etched back.
Claim 10
Dependent Claim 19 words
The method according to claim 8, wherein said nitride and second oxide layers are formed on said HSG spacer.
Claim 11
Dependent Claim 25 words
The method according to claim 9, wherein an oxide spacer is formed around said HSG spacer when said second oxide layer is anisotropically etched back.
Claim 12
Independent Claim 411 words
A method for forming a capacitor in an integrated circuit, said method comprising: forming a first oxide layer over a substrate; forming a first photoresist layer over said first oxide layer, said photoresist layer defining a node contact area; removing a portion of said first oxide layer using said first photoresist layer as a mask, thereby forming a node trench in said first oxide layer, said node trench exposing a portion of said substrate; forming a polysilicon layer on said first oxide layer, said polysilicon layer filling said node trench in said first oxide layer; forming a second photoresist layer on said polysilicon layer, said second photoresist layer defining an electrode area; removing portions of said polysilicon layer left uncovered by said second photoresist layer, wherein portions of said first oxide layer uncovered by said second photoresist layer are exposed; forming a hemispherical-grain (HSG) polysilicon layer on said polysilicon layer and said exposed portions of said first oxide layer; etching back said HSG polysilicon layer until portions of said first oxide layer are exposed, wherein a HSG spacer is formed on a sidewall of said polysilicon layer and wherein a plurality of grooves is formed in an upper portion of said polysilicon layer, said plurality of grooves corresponding to grooves between grains of said HSG polysilicon layer; forming a conformal silicon nitride layer on said first oxide layer, said HSG spacer and said polysilicon layer, wherein said silicon nitride layer lines said plurality of grooves in said polysilicon layer; forming a second oxide layer on said silicon nitride layer, wherein said plurality of nitride-lined grooves is filled with oxide of said second oxide layer; anisotropically etching back said second oxide layer until a portion of said silicon nitride layer surrounding said HSG spacer is exposed, wherein residual oxide from said second oxide layer remains in said plurality of nitride-lined grooves and portions of said silicon nitride layer aligned between said nitride-lined grooves are exposed; removing said exposed portions of said silicon nitride layer, wherein portions of said polysilicon layer are exposed; anisotropically etching said exposed portions of said polysilicon layer using said residual oxide in said plurality of nitride-lined grooves as a mask, wherein a plurality of trenches is formed in the polysilicon layer aligned between said plurality of nitride-lined grooves; removing said residual oxide; removing remaining portions of said silicon nitride layer; forming a conformal dielectric layer on said polysilicon layer; and forming a conductive layer on said dielectric layer.
Claim 13
Independent Claim 411 words
A method for forming a capacitor in an integrated circuit, said method comprising: forming a first oxide layer over a substrate; forming a first photoresist layer over said first oxide layer, said photoresist layer defining a node contact area; removing a portion of said first oxide layer using said first photoresist layer as a mask, thereby forming a node trench in said first oxide layer, said node trench exposing a portion of said substrate; forming a polysilicon layer on said first oxide layer, said polysilicon layer filling said node trench in said first oxide layer; forming a second photoresist layer on said polysilicon layer, said second photoresist layer defining an electrode area; removing portions of said polysilicon layer left uncovered by said second photoresist layer, wherein portions of said first oxide layer uncovered by said second photoresist layer are exposed; forming a hemispherical-grain (HSG) polysilicon layer on said polysilicon layer and said exposed portions of said first oxide layer; etching back said HSG polysilicon layer until portions of said first oxide layer are exposed, wherein a HSG spacer is formed on a sidewall of said polysilicon layer and wherein a plurality of grooves is formed in an upper portion of said polysilicon layer, said plurality of grooves corresponding to grooves between grains of said HSG polysilicon layer; forming a conformal silicon nitride layer on said first oxide layer, said HSG spacer and said polysilicon layer, wherein said silicon nitride layer lines said plurality of grooves in said polysilicon layer; forming a second oxide layer on said silicon nitride layer, wherein said plurality of nitride-lined grooves is filled with oxide of said second oxide layer; anisotropically etching back said second oxide layer until a portion of said silicon nitride layer surrounding said HSG spacer is exposed, wherein residual oxide from said second oxide layer remains in said plurality of nitride-lined grooves and portions of said silicon nitride layer aligned between said nitride-lined grooves are exposed; removing said exposed portions of said silicon nitride layer, wherein portions of said polysilicon layer are exposed; anisotropically etching said exposed portions of said polysilicon layer using said residual oxide in said plurality of nitride-lined grooves as a mask, wherein a plurality of trenches is formed in the polysilicon layer aligned between said plurality of nitride-lined grooves; removing said residual oxide; removing remaining portions of said silicon nitride layer; forming a conformal dielectric layer on said polysilicon layer; and forming a conductive layer on said dielectric layer.
Claim 14
Dependent Claim 32 words
The method according to claim 11, wherein said substrate comprises a metal-oxide-semiconductor transistor formed in and on the substrate, said metal-oxide-semiconductor transistor being a part of a dynamic random access memory cell.
Claim 15
Dependent Claim 29 words
The method according to claim 11, wherein said HSG polysilicon layer is formed using a chemical vapor deposition process with a temperature in a range of about 530°˜600° C.
Claim 16
Dependent Claim 21 words
The method according to claim 11, wherein said silicon nitride layer has a thickness in a range of about 100˜900 angstroms.
Claim 17
Dependent Claim 24 words
The method according to claim 11, wherein each trench of said plurality of trenches has a width in a range of about 100˜1000 angstroms.
Claim 18
Dependent Claim 39 words
The method according to claim 11, wherein adjacent trenches of said plurality of trenches define a plurality of vertically extending fins, each vertically extending fin of said plurality of vertically extending fins having a width of about 500 angstroms.
Claim 19
Dependent Claim 15 words
The method according to claim 11, wherein said conformal dielectric layer comprises an oxide-nitride-oxide layer.

References Cited (Backward Citations)

US5387531A Cited
US5342800A Cited
US5302540A Cited
US5278091A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2001-11-16 2002-05-18 2002-11-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2005-11-16 2006-05-18 2006-11-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2009-11-16 2010-05-18 2010-11-17 $7700.00 Window Closed / Lapsed

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