Patent US5789460A successfully refreshed from Google Patents.
US5789460A
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Radiation curable compositions
Assignee: DuPont Toray Specialty Materials KK
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Filing: 1996-01-24
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Granted: 1998-08-04
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Expires: 2016-01-24
Abstract
Abstract Curable compositions comprising a substance that produces a base when exposed to radiation and a polymer molecule that contains silicon-hydrogen bonds which react with hydroxyl groups under the action of the base to form silicon-oxygen bonds (Si--O) and hydrogen molecules. These compositions cure when exposed to radiation. A pattern can be formed by placing a mask between a coating of the composition and the radiation source during this exposure episode and thereafter dissolving the uncured composition. The compositions have little weight loss during their cure, they can be cured by low intensity radiation, and they yield heat-resistant cured products.
Inventors
- 👤 Brian Robert Harkness
- 👤 Mamoru Tachikawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 21:02
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/075; G03F7/0757; C; C08; C08K; C08K5/00; C08K5/16; C08K5/205; C08L; C08L83/00; C08L83/04; C09; C09D; C09D183/00; C09D183/04; G03F7/0045; C08G; C08G77/00; C08G77/04; C08G77/12; C08G77/14; C08G77/16; C08G77/18; C08G77/20; C08G77/22; C08G77/24; C08G77/26; C08G77/70
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
169 words
A curable composition comprising (i) a substance that produces a base when exposed to radiation; (ii) a hydroxyl-functional crosslinker selected from the group consisting of water, silane compounds that have at least 2 silanol groups per molecule, silicone polymer molecules that contain on average at least 2 silanol groups in each polymer molecule, and organic compounds that contain on average at least 2 hydroxyl groups per molecule; and (iii) a polymer molecule that contains silicon-hydrogen bonds which react with the hydroxyl groups of component (ii) under the action of the base to form silicon-oxygen bonds and hydrogen molecules, wherein the substance that produces the base is present at from 0.01 to 50 weight % based on the total weight of the composition and is selected from the group consisting of benzyl carbamates, benzoin carbamates, O-carbamoylhydroxyamines, O-carbamoyloximes, aromatic sulfonamides, alpha-lactams, N-(2-allylethenyl)amides, arylazide compounds, N-arylformamides, and 4-(ortho-nitrophenyl)dihydropyridines, and wherein each polymer molecule contains on average at least 2 silicon atoms that have 1 silicon-hydrogen bond and at least 2 silicon-oxygen bonds.
Claim 2
Dependent Claim
169 words
A curable composition comprising (i) a substance that produces a base when exposed to radiation; (ii) a hydroxyl-functional crosslinker selected from the group consisting of water, silane compounds that have at least 2 silanol groups per molecule, silicone polymer molecules that contain on average at least 2 silanol groups in each polymer molecule, and organic compounds that contain on average at least 2 hydroxyl groups per molecule; and (iii) a polymer molecule that contains silicon-hydrogen bonds which react with the hydroxyl groups of component (ii) under the action of the base to form silicon-oxygen bonds and hydrogen molecules, wherein the substance that produces the base is present at from 0.01 to 50 weight % based on the total weight of the composition and is selected from the group consisting of benzyl carbamates, benzoin carbamates, O-carbamoylhydroxyamines, O-carbamoyloximes, aromatic sulfonamides, alpha-lactams, N-(2-allylethenyl)amides, arylazide compounds, N-arylformamides, and 4-(ortho-nitrophenyl)dihydropyridines, and wherein each polymer molecule contains on average at least 2 silicon atoms that have 1 silicon-hydrogen bond and at least 2 silicon-oxygen bonds.
Claim 3
Dependent Claim
23 words
The composition of claim 1 wherein the polymer molecule is selected from the group consisting of silicone polymer molecules and silicone-modified organic resins.
Claim 4
Dependent Claim
221 words
The composition of claim 1 wherein the substance that produces the base is selected from the group consisting of (A) benzyl carbamates with the structure BzCH 2 OC(═O)NR 3 R 4 wherein Bz represents a benzyl group and in which a nitro group is substituted at position 2 or at positions 2 and 6 of the benzyl group, a methoxy group is optionally substituted at position 4 or 5 of the benzyl group, R 3 is H, C 1 to C 10 alkyl, aralkyl, or aryl, and R 4 is C 1 to C 10 alkyl, aralkyl, or aryl; (B) benzoin carbamates ArC(═O)CHArOC(═O)NR 5 R 6 in which Ar is phenyl, R 5 is a hydrogen atom and R 6 is C 5 to C 10 alkyl; (C) O-carbamoylhydroxyamines R 7 R 8 NOC(═O)NR 9 R 10 in which R 7 and R 8 are bonded with each other to give a phthaloyl group, R 9 is a hydrogen atom, and R 10 is C 5 to C 10 alkyl; and (D) 4-(ortho-nitrophenyl)dihydropyridines in which a methyl or ethyl group is bonded at position 1 of the dihydropyridine and a methoxycarbonyl group is bonded at positions 3 and 5 of the dihydropyridine; and wherein the substance that produces the base is present at 0.1 to 25 weight % of the composition.
Claim 5
Dependent Claim
36 words
The curable composition of claim 2 wherein the organic resin of the silicon modified organic resin is selected from the group consisting of alkyd resins, polyester resins, acrylic resins, epoxy resins, phenolic resins and polyimide resins.
Claim 6
Dependent Claim
186 words
The curable composition of claim 1 wherein the polymer molecule is a silicone polymer molecule of the following general formula (R.sub.3 SiO.sub.1/2).sub.a (R.sub.2 SiO.sub.2/2).sub.b (RSiO.sub.3/2).sub.c (SiO.sub.4/2).sub.d wherein each R is a monovalent radical independently selected from the group consisting of a hydrogen atom, a trifluoropropyl group, a trimethylsilyl group, a methoxy group, and C 1 to C 8 hydrocarbon groups, with the proviso that in each polymer molecule R is the hydrogen atom on average in at least 2 of the R 2 SiO 2/2 and RSiO 3/2 considered collectively; the divalent oxygen atom bonded to silicon in R 3 SiO 1/2 is bonded to another silicon atom; at least 1 of the divalent oxygen atoms bonded to silicon in R 2 SiO 2/2 , RSiO 3/2 , and SiO 4/2 is bonded to another silicon and the remaining oxygen are bonded to another silicon, hydrogen, C 1 to C 6 alkyl, C 1 to C 6 alkenyl or C 6 to C 8 aryl; wherein the silicone polymer has an average degree of polymerization of at least 5; and wherein 0.7>a/(a+b+c+d)≧0; 1≧b/(a+b+c+d)≧0; 1≧c/(a+b+c+d)≧0; and 0.65≧d/(a+b+c+d)≧0.
Claim 7
Dependent Claim
37 words
A method for curing a curable composition comprising exposing the curable composition of claim 1 to radiation at a temperature from 0° C. to 200° C. in an atmosphere having a relative humidity of at least 10%.
Claim 8
Dependent Claim
23 words
The method of claim 6 wherein the radiation is selected from the group consisting of UV-containing light, electron beams, x-rays, and ion beams.
Claim 9
Dependent Claim
18 words
The method of claim 6 additionally comprising a post-treatment at a temperature from 0° C. to 200° C.
Claim 10
Dependent Claim
26 words
A method for curing a curable composition comprising exposing the curable composition of claim 1 to radiation at a temperature from 0° C. to 200° C.
Claim 11
Dependent Claim
23 words
The method of claim 9 wherein the radiation is selected from the group consisting of UV-containing light, electron beams, x-rays, and ion beams.
Claim 12
Dependent Claim
18 words
The method of claim 9 additionally comprising a post-treatment at a temperature from 0° C. to 200° C.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 2001-08-03 | 2002-02-02 | 2002-08-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2005-08-03 | 2006-02-02 | 2006-08-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2009-08-03 | 2010-02-02 | 2010-08-04 | $7700.00 | Window Closed / Lapsed |