US5789073A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Fiber reinforced composite materials
Assignee: Toray Industries Inc
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Filing: 1993-01-15
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Granted: 1998-08-04
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Expires: 2013-01-15
Abstract
Abstract Tough laminated composite material which comprise (A) long reinforcing fibers, (B) a matrix resin mixed with the long reinforcing fibers and (C1) a resin, preferably in the form of fine resin particles, forming a phase separate from said matrix resin which is localized in inter-layer zones, wherein 90% or more of said resin (C1) is localized in inter-layer zones and/or wherein the border length factor in the inter-layer zones is 2.5 or more and prepregs used to form the composite materials.
Inventors
- 👤 Nobuyuki Odagiri
- 👤 Shigeru Suzue
- 👤 Akimitsu Matsusaki
- 👤 Hajime Kishi
- 👤 Takeji Nakae
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 12:03
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/24; C08J5/241; C08J5/243; F; F17; F17C; F17C2209/00; F17C2209/21; F17C2209/2154; Y; Y10; Y10S; Y10S428/00; Y10S428/902; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249924; Y10T428/24994; Y10T428/25; Y10T428/254; Y10T428/26; Y10T428/31504; Y10T428/31551; Y10T428/31562; Y10T428/31721; Y10T428/31725; Y10T428/31786; Y10T442/00; Y10T442/30; Y10T442/3472; Y10T442/3528; Y10T442/3545
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
77 words
A fiber reinforced thermosetting resin matrix prepreg containing reinforcing fibers having an outer resin layer apart from the reinforcing fibers at one or both surfaces of the prepreg, said outer resin layer comprising particles of thermoplastic resin of particle diameters in the range of from 0.1 to 150 microns, wherein 90% or more of the thermoplastic resin particles are located within a depth which is 30% of a thickness of the prepreg determined from the prepreg surface.
Claim 2
Dependent Claim
77 words
A fiber reinforced thermosetting resin matrix prepreg containing reinforcing fibers having an outer resin layer apart from the reinforcing fibers at one or both surfaces of the prepreg, said outer resin layer comprising particles of thermoplastic resin of particle diameters in the range of from 0.1 to 150 microns, wherein 90% or more of the thermoplastic resin particles are located within a depth which is 30% of a thickness of the prepreg determined from the prepreg surface.
Claim 3
Dependent Claim
21 words
The prepreg of claim 1, wherein the thermoplastic resin particles have diameters in the range of from 0.5 to 60 microns.
Claim 4
Dependent Claim
33 words
The prepreg of claim 1, wherein 90% or more of the thermoplastic resin particles are located within a depth which is 10% of a thickness of the prepreg determined from the prepreg surface.
Claim 5
Dependent Claim
41 words
The prepreg of claim 1, wherein the thermoplastic resin is selected from the group consisting of polyacrylate, poly(vinyl acetate), polystyrol, polyimide, polyacetal, poly(phenylene oxide), poly(phenylene sulfide), polyallylate, polyamideimide, polyamide, polysulfone, polyethersulfone, polyaramid, polyetherimide, polycarbonate, polyester, polybenzamidazole, polypropylene, polyethylene, and cellulose derivatives.
Claim 6
Dependent Claim
26 words
A laminated fiber reinforced thermosetting resin composite which has been made by laminating several prepregs at least one of which is the prepreg of claim 1.
Claim 7
Dependent Claim
67 words
A laminated fiber reinforced thermosetting resin composite comprising at least one resin layer separating fiber layers in the laminated composite, said resin layer comprising particles of thermoplastic resin in a matrix resin, wherein 90% or more of the thermoplastic resin particles are localized in inter-layer zones which have thicknesses which are 30% of thickness of a total combined thickness of each fiber layer and each resin layer.
Claim 8
Dependent Claim
67 words
A laminated fiber reinforced thermosetting resin composite comprising at least one resin layer separating fiber layers in the laminated composite, said resin layer comprising particles of thermoplastic resin in a matrix resin, wherein 90% or more of the thermoplastic resin particles are localized in inter-layer zones which have thicknesses which are 30% of thickness of a total combined thickness of each fiber layer and each resin layer.
Claim 9
Dependent Claim
38 words
The composite of claim 6, wherein the amount of thermoplastic resin in the resin layer separating fiber layers is within the range of 1 to 30 parts by weight to 100 parts by weight of the matrix resin.
Claim 10
Independent Claim
92 words
A method of making a fiber reinforced thermosetting resin prepreg, comprising the steps of providing a fiber layer containing reinforcing fibers and applying to the fiber layer thermoplastic resin particles of diameters in the range of from 0.1 to 150 microns in a thin resin layer apart from the fiber layer at one surface of the prepreg, so as to make a prepreg in which 90% or more of the thermoplastic resin particles are located within a depth which is 30% of a thickness of the prepreg determined from the prepreg surface.
Claim 11
Independent Claim
92 words
A method of making a fiber reinforced thermosetting resin prepreg, comprising the steps of providing a fiber layer containing reinforcing fibers and applying to the fiber layer thermoplastic resin particles of diameters in the range of from 0.1 to 150 microns in a thin resin layer apart from the fiber layer at one surface of the prepreg, so as to make a prepreg in which 90% or more of the thermoplastic resin particles are located within a depth which is 30% of a thickness of the prepreg determined from the prepreg surface.
Claim 12
Dependent Claim
21 words
The method of claim 8, wherein the thermoplastic resin particles have diameters in the range of from 0.5 to 60 microns.
Claim 13
Dependent Claim
63 words
A fiber reinforced thermosetting resin matrix prepreg containing reinforcing fibers having an outer resin layer apart from the reinforcing fibers at one or both surfaces of the prepreg, said outer resin layer comprising particles of thermoplastic resin of particle diameters in the range of from 0.1 to 150 microns, there being substantially no thermoplastic resin particles within the fiber layer of the prepreg.
Claim 14
Dependent Claim
63 words
A fiber reinforced thermosetting resin matrix prepreg containing reinforcing fibers having an outer resin layer apart from the reinforcing fibers at one or both surfaces of the prepreg, said outer resin layer comprising particles of thermoplastic resin of particle diameters in the range of from 0.1 to 150 microns, there being substantially no thermoplastic resin particles within the fiber layer of the prepreg.
Claim 15
Independent Claim
72 words
A method of making a fiber reinforced thermosetting resin prepreg, comprising the steps of providing a fiber layer containing reinforcing fibers and applying to the fiber layer thermoplastic resin-particles of diameters in the range of from 0.1 to 150 microns in a thin resin layer apart from the fiber layer at one surface of the prepreg so that there are substantially no thermoplastic resin particles within the fiber layer of the prepreg.
Claim 16
Independent Claim
72 words
A method of making a fiber reinforced thermosetting resin prepreg, comprising the steps of providing a fiber layer containing reinforcing fibers and applying to the fiber layer thermoplastic resin-particles of diameters in the range of from 0.1 to 150 microns in a thin resin layer apart from the fiber layer at one surface of the prepreg so that there are substantially no thermoplastic resin particles within the fiber layer of the prepreg.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2001-08-03 | 2002-02-02 | 2002-08-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2005-08-03 | 2006-02-02 | 2006-08-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2009-08-03 | 2010-02-02 | 2010-08-04 | $7700.00 | Window Closed / Lapsed |