Crystal growth modifiers for perylene pigments

Claim 2

A pigment composition comprising a co-precipitated blend comprising (a) 60 to 95 percent by weight of a perylene pigment having the formula ##STR9## wherein R 1 and R 2 are independently C 1 -C 6 alkyl, C 5 -C 7 cycloalkyl, C 7 -C 16 aralkyl, or C 6 -C 10 aryl; and (b) 5 to 40 percent by weight of a polycyclic aromatic compound containing at least five aromatic rings wherein at least one such aromatic ring is substituted with one or more keto groups.

Claim 3

A pigment composition according to claim 1 wherein the polycyclic aromatic compound is (i) an anthanthrone having the formula ##STR10## wherein X 1 and X 2 are independently hydrogen, halogen, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 7 -C 16 aralkyl, or C 6 -C 10 aryl, (ii) a quinacridone having the formula ##STR11## wherein Y 1 and Y 2 are independently hydrogen, halogen, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 7 -C 16 aralkyl, or C 6 -C 10 aryl, or (iii) a flavanthrone having the formula ##STR12## wherein Z 1 and Z 2 are independently hydrogen, halogen, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 7 -C 16 aralkyl, or C 6 -C 10 aryl.

Claim 4

A pigment composition according to claim 1 wherein the co-precipitated blend comprises 75 to 90 percent by weight of perylene pigment (a) and 10 to 25 percent by weight of polycyclic aromatic compound (b).

Claim 5

A pigment composition according to claim 1 wherein the polycyclic aromatic compound is an anthanthrone having the formula ##STR13## wherein X 1 and X 2 are independently hydrogen or halogen.

Claim 6

A pigment composition according to claim 1 wherein the polycyclic aromatic compound is 4,8-dibromoanthanthrone.

Claim 7

A pigment composition according to claim 1 wherein the polycyclic aromatic compound is a 2,9-disubstituted quinacridone having the formula ##STR14## wherein Y 1 and Y 2 are independently hydrogen or halogen.

Claim 8

A pigment composition according to claim 1 wherein the polycyclic aromatic compound is 2,9-dichloroquinacridone.

Claim 9

A pigment composition according to claim 1 wherein the polycyclic aromatic compound is unsubstituted flavanthrone having the formula ##STR15##

Claim 10

A process for preparing a pigment composition according to claim 1 comprising (1) acid pasting or acid swelling a mixture comprising (a) 60 to 95 percent by weight, relative to the total weight of components (a) and (b), of a perylene pigment of formula ##STR16## wherein R 1 and R 2 are independently C 1 -C 6 alkyl, C 5 -C 7 cycloalkyl, C 7 -C 16 aralkyl, or C 6 -C 10 aryl; and (b) 5 to 40 percent by weight, relative to the total weight of components (a) and (b), of a polycyclic aromatic compound containing at least five aromatic rings wherein at least one such aromatic ring is substituted with one or more keto groups; with 5 to 25 parts by weight, relative to the total weight of components (a) and (b), of a strong acid; (2) drowning the mixture from step (1) by adding said mixture to 0.5 to 100 parts by weight, per part of said mixture, of a liquid in which the pigment is substantially insoluble, thereby precipitating the pigment composition; (3) isolating the pigment composition; (4) optionally, conditioning the pigment composition.

Claim 11

A process according to claim 9 wherein the polycyclic aromatic compound is (i) an anthanthrone having the formula ##STR17## wherein X 1 and X 2 are independently hydrogen, halogen, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 7 -C 16 aralkyl, or C 6 -C 10 aryl, (ii) a quinacridone having the formula ##STR18## wherein Y 1 and Y 2 are independently hydrogen, halogen, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 7 -C 16 aralkyl, or C 6 -C 10 aryl, or (iii) a flavanthrone having the formula ##STR19## wherein Z 1 and Z 2 are independently hydrogen, halogen, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 7 -C 16 aralkyl, or C 6 -C 10 aryl.

Claim 12

A process according to claim 9 wherein the mixture used in step (1) comprises 75 to 90 percent by weight, relative to the total weight of components (a) and (b), of perylene pigment (a) and 10 to 25 percent by weight, relative to the total weight of components (a) and (b), of polycyclic aromatic compound (b).

Claim 13

A process according to claim 9 wherein the strong acid used in step (1) is concentrated sulfuric acid, oleum, or a mixture thereof.

Claim 14

A process according to claim 9 wherein 9 to 15 parts by weight, relative to the total weight of components (a) and (b), of a strong acid is used in step (1).

Claim 15

A process according to claim 9 wherein the liquid used in drowning step (2) is water.