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Compositions and processes for the oxidative dyeing of keratin fibres with para-phenylenediamine derivatives and a cationic substantive polymer

Assignee: L'Oréal SA
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Filing: 1996-07-26
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Granted: 1998-04-07
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Expires: 2016-07-26
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Abstract

Abstract The invention relates to an oxidation dye composition for keratin fibers, in particular for human keratin fibers such as hair, of the type comprising, in a medium which is suitable for dyeing, at least one oxidation dye precursor and optionally one or more couplers, and which is characterized in that it contains (i) as oxidation dye precursor, at least one para-phenylenediamine substituted in the 2-position on the benzene ring with a C1-C4 hydroxyalkyl or hydroxyalkoxy radical, and/or at least one of the addition salts thereof with an acid, and (ii) at least one cationic or amphoteric substantive polymer. The invention also relates to the use of this composition for dyeing keratin fibers, especially hair.

Inventors

  • 👤 Jean Cotteret
  • 👤 Marie-Pascale Audousset

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 17:13
CPC Classifications
A; A61; A61Q; A61Q5/00; A61Q5/10; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/411; A61K8/72; A61K8/84; A61K2800/00; A61K2800/40; A61K2800/54; A61K2800/542; A61K2800/5426

Claims Analysis

Total Claims: 39
Claim 1
Independent Claim 105 words
An oxidation dye composition for keratin fibres, comprising, in a medium appropriate for dyeing, at least one oxidation dye precursor, and optionally, at least one coupler, and at least one cationic substantive polymer which is a dimethyldiallylammonium chloride homopolymer; said at least one oxidation dye precursor being selected from para-phenylenediamines of formula (I): ##STR6## in which m is an integer equal to zero or 1, and n is an integer ranging from 1 to 4, or an acid addition salt thereof, the oxidation dye precursor, and coupler if required, being present in amounts effective to react with an oxidation agent to dye said keratin fibres.
Claim 2
Dependent Claim 105 words
An oxidation dye composition for keratin fibres, comprising, in a medium appropriate for dyeing, at least one oxidation dye precursor, and optionally, at least one coupler, and at least one cationic substantive polymer which is a dimethyldiallylammonium chloride homopolymer; said at least one oxidation dye precursor being selected from para-phenylenediamines of formula (I): ##STR6## in which m is an integer equal to zero or 1, and n is an integer ranging from 1 to 4, or an acid addition salt thereof, the oxidation dye precursor, and coupler if required, being present in amounts effective to react with an oxidation agent to dye said keratin fibres.
Claim 3
Dependent Claim 28 words
A composition according to claim 1, wherein the para-phenylenediamine of formula (I) is 2-(β-hydroxyethyl)-para-phenylenediamine or an acid addition salt thereof, or 2-(β-hydroxyethyloxy)-para-phenylenediamine or an acid addition salt thereof.
Claim 4
Dependent Claim 29 words
A composition according to claim 1, wherein said acid addition salt of the para-phenylenediamine of formula (I) is selected from the hydrochlorides, the sulphates, the hydrobromides and the tartrates.
Claim 5
Dependent Claim 36 words
A composition according to claim 1, wherein said para-phenylenediamine of formula (I), or the salt thereof, is present in a concentration ranging from 0.05 to 10% by weight, relative to the total weight of the composition.
Claim 6
Dependent Claim 36 words
A composition according to claim 4, wherein said para-phenylenediamine of formula (I), or the salt thereof, is present in a concentration ranging from 0.1 to 5% by weight, relative to the total weight of the composition.
Claim 7
Dependent Claim 33 words
A composition according to claim 1, wherein the cationic or amphoteric substantive polymer is present in a concentration ranging from 0.02 to 10% by weight, relative to the total weight of the composition.
Claim 8
Dependent Claim 33 words
A composition according to claim 6, wherein the cationic or amphoteric substantive polymer is present in a concentration ranging from 0.05 to 5% by weight, relative to the total weight of the composition.
Claim 9
Dependent Claim 14 words
A composition according to claim 1, wherein said composition contains at least one coupler.
Claim 10
Dependent Claim 26 words
A composition according to claim 1, wherein said composition contains at least one additional ingredient, the ingredient being a direct dye or an oxidation dye precursor.
Claim 11
Dependent Claim 27 words
A composition according to claim 1, which is ready to use and which additionally contains an oxidizing agent and has a pH ranging from 3 to 11.
Claim 12
Dependent Claim 50 words
A process for dyeing keratin fibres, comprising the steps of: (i) applying to said fibres the dye composition according to claim 1; and (ii) applying an oxidizing agent to said fibres simultaneously with or subsequently to said dye composition, to develop a colour in an acidic, neutral or alkaline medium.
Claim 13
Dependent Claim 24 words
A process according to claim 11, wherein said oxidizing agent is added to said dye composition at the time of applying in step (i).
Claim 14
Dependent Claim 41 words
A process according to claim 11, wherein said oxidizing agent is contained in a composition (A), and said dye composition is separately contained in a composition (B), and wherein said separate compositions (A) and (B) are applied to said fibres simultaneously.
Claim 15
Dependent Claim 32 words
A process according to claim 11, wherein said oxidizing agent is separately contained in a second composition and is separately applied to said fibres subsequently to said application of said dye composition.
Claim 16
Dependent Claim 13 words
A process according to claim 11, wherein said fibres are human keratin fibres.
Claim 17
Dependent Claim 107 words
A process for dying keratin fibres, comprising the steps of: (i) applying to said fibres a dye composition, which comprises, in a medium appropriate for dyeing, at least one para-phenylenediamine of formula (I): ##STR7## in which m is an integer equal to zero or 1, and n is an integer ranging from 1 to 4, or an acid addition salt thereof; and (ii) applying an oxidizing composition, which comprises an oxidizing agent and at least one cationic substantive polymer which is a dimethyldiallylammonium chloride homopolymer, to said fibres simultaneously with or subsequently to said dye composition, to develop a colour in an alkaline, neutral or acidic medium.
Claim 18
Dependent Claim 107 words
A process for dying keratin fibres, comprising the steps of: (i) applying to said fibres a dye composition, which comprises, in a medium appropriate for dyeing, at least one para-phenylenediamine of formula (I): ##STR7## in which m is an integer equal to zero or 1, and n is an integer ranging from 1 to 4, or an acid addition salt thereof; and (ii) applying an oxidizing composition, which comprises an oxidizing agent and at least one cationic substantive polymer which is a dimethyldiallylammonium chloride homopolymer, to said fibres simultaneously with or subsequently to said dye composition, to develop a colour in an alkaline, neutral or acidic medium.
Claim 19
Dependent Claim 16 words
A process according to claim 16, wherein said dye composition further comprises at least one coupler.
Claim 20
Dependent Claim 18 words
A process according to claim 16, wherein said dye composition further comprises a cationic or amphoteric substantive polymer.
Claim 21
Dependent Claim 24 words
A process according to claim 16, wherein said oxidizing composition is added to said dye composition at the time of applying in step (i).
Claim 22
Dependent Claim 33 words
A process according to claim 16, wherein said oxidizing composition is separately contained, from said dye composition, and wherein the separately contained oxidizing composition and the separately contained dye composition are applied simultaneously.
Claim 23
Dependent Claim 21 words
A process according to claim 16, wherein said oxidizing composition is separately applied to said fibres subsequent to said dye composition.
Claim 24
Dependent Claim 13 words
A process according to claim 16, wherein said fibres are human keratin fibres.
Claim 25
Dependent Claim 46 words
A kit for dyeing keratin fibres comprising at least two compartments, at least one of said compartments containing a dye composition according to claim 1, and at least one other of said compartments containing a composition comprising an oxidizing agent in a medium appropriate for dyeing.
Claim 26
Dependent Claim 14 words
A kit according to claim 23, wherein said keratin fibres are human keratin fibres.
Claim 27
Dependent Claim 94 words
A kit for dyeing keratin fibres comprising at least two compartments, at least one of said compartments containing a dye composition which comprises, in a medium appropriate for dyeing, at least one para-phenylenediamine of formula (I): ##STR8## in which m is an integer equal to zero or 1, and n is an integer ranging from 1 to 4, or an acid addition salt thereof, and at least one other of said compartments containing an oxidizing composition which comprises an oxidizing agent and at least one cationic substantive polymer which is a dimethyldiallylammonium chloride homopolymer.
Claim 28
Dependent Claim 94 words
A kit for dyeing keratin fibres comprising at least two compartments, at least one of said compartments containing a dye composition which comprises, in a medium appropriate for dyeing, at least one para-phenylenediamine of formula (I): ##STR8## in which m is an integer equal to zero or 1, and n is an integer ranging from 1 to 4, or an acid addition salt thereof, and at least one other of said compartments containing an oxidizing composition which comprises an oxidizing agent and at least one cationic substantive polymer which is a dimethyldiallylammonium chloride homopolymer.
Claim 29
Dependent Claim 22 words
A kit according to claim 25, wherein said at least one compartment containing said dye composition further contains at least one coupler.
Claim 30
Dependent Claim 14 words
A kit according to claim 25, wherein said keratin fibres are human keratin fibres.
Claim 31
Dependent Claim 109 words
A process for dyeing keratin fibres comprising the steps of: (i) applying to said fibres a dye composition according to claim 1, said dye composition being obtained from a kit for dyeing keratin fibres comprising at least two compartments, at least one of said compartments containing a dye composition according to claim 1, and at least one other of said compartments containing a composition comprising an oxidizing agent in a medium appropriate for dyeing; and (ii) applying, to develop a colour in said medium, said oxidizing agent and said appropriate dyeing medium to said fibres simultaneously with or subsequently to the application of said dyeing composition to said fibres.
Claim 32
Dependent Claim 14 words
A process according to claim 28, wherein said keratin fibres are human keratin fibres.
Claim 33
Dependent Claim 145 words
A process for dyeing keratin fibres comprising the steps of: (i) applying to said fibres a dye composition which comprises, in a medium appropriate for dyeing, at least one para-phenylenediamine of formula (I): ##STR9## in which m is an integer equal to zero of 1, and n is an integer ranging from 1 to 4, or an acid addition salt thereof, said dye composition being obtained from a kit for dyeing keratin fibres comprising at least two compartments, at least one of said compartments containing said dye composition, and at least one other of said compartments containing an oxidizing composition which comprises an oxidizing agent and at least one cationic substantive polymer which is a dimethyldiallylammonium chloride homopolymer; and (ii) applying, to develop a colour, said oxidizing composition to said fibres simultaneously with or subsequently to the application of said dyeing composition to said fibres.
Claim 34
Dependent Claim 145 words
A process for dyeing keratin fibres comprising the steps of: (i) applying to said fibres a dye composition which comprises, in a medium appropriate for dyeing, at least one para-phenylenediamine of formula (I): ##STR9## in which m is an integer equal to zero of 1, and n is an integer ranging from 1 to 4, or an acid addition salt thereof, said dye composition being obtained from a kit for dyeing keratin fibres comprising at least two compartments, at least one of said compartments containing said dye composition, and at least one other of said compartments containing an oxidizing composition which comprises an oxidizing agent and at least one cationic substantive polymer which is a dimethyldiallylammonium chloride homopolymer; and (ii) applying, to develop a colour, said oxidizing composition to said fibres simultaneously with or subsequently to the application of said dyeing composition to said fibres.
Claim 35
Dependent Claim 22 words
A process according to claim 30, wherein said at least one compartment containing said dye composition further contains at least one coupler.
Claim 36
Dependent Claim 14 words
A process according to claim 30, wherein said keratin fibres are human keratin fibres.
Claim 37
Dependent Claim 14 words
A composition according to claim 1, wherein said keratin fibres are human keratin fibres.
Claim 38
Dependent Claim 13 words
A composition according to claim 33, wherein said human keratin fibres are hair.
Claim 39
Dependent Claim 19 words
A composition according to claim 1, which is in the form of a liquid, a cream or a gel.

References Cited (Backward Citations)

US4566875A Cited
EP0007537A1 Cited
US4840639A Cited
US5143518A Cited
GB2239265A Cited
EP0400330B1 Cited
EP0557203A1 Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2001-04-06 2001-10-06 2002-04-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2005-04-06 2005-10-06 2006-04-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2009-04-06 2009-10-06 2010-04-07 $7700.00 Window Closed / Lapsed

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