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US5700739A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of multi-step reactive ion etch for patterning adjoining semiconductor metallization layers

Assignee: Taiwan Semiconductor Manufacturing Co TSMC Ltd
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Filing: 1995-08-03
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Granted: 1997-12-23
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Expires: 2015-08-03
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Abstract

Abstract A method for forming patterned conductor metallization layers adjoining patterned barrier metallization layers upon semiconductor substrates. A semiconductor substrate is provided which has formed upon its surface a patterned second masking layer upon a blanket first masking layer. The patterned second masking layer is formed from a photoresist material and the blanket first masking layer is formed from a silicon oxide material, a silicon nitride material or a silicon oxynitride material. Beneath the blanket first masking layer resides a blanket multi-layer metallization stack which includes a blanket conductor metallization layer adjoining a blanket barrier metallization layer. The blanket first masking layer and the upper lying blanket metallization layer of the blanket conductor metallization layer and the blanket barrier metallization layer are successively patterned through a Reactive Ion Etch (RIE) process using as the etch mask the patterned second masking layer. The patterned second masking layer is then removed. The remaining lower lying metallization layer is then patterned through a Reactive Ion Etch (RIE) process using a patterned first masking layer and the patterned upper metallization layer as the etch mask.

Inventors

  • 👤 An-Min Chiang
  • 👤 Wei-kun Yeh

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 03:16
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/71; H10D; H10D64/00; H10D64/01; H10D64/011

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 272 words
A method for forming a patterned conductor metallization layer adjoining a patterned barrier metallization layer over a semiconductor substrate comprising: providing a semiconductor substrate: forming over the semiconductor substrate a blanket conductor metallization layer adjoining a blanket barrier metallization layer, the blanket barrier metallization layer being formed from a barrier material selected from the group of barrier materials consisting of metal silicide barrier materials and metal nitride barrier materials, where one of the blanket conductor metallization layer and the blanket barrier metallization layer is an upper metallization layer formed further removed from the semiconductor substrate and the other of the blanket conductor metallization and the blanket barrier metallization layer is a lower metallization layer formed closer to the semiconductor substrate; forming a blanket first masking layer upon the surface of the upper metallization layer, the blanket first masking layer being formed from a material selected from the group of materials consisting of silicon oxide materials, silicon nitride materials and silicon oxynitride materials; forming a patterned second masking layer upon the surface of the blanket first masking layer; etching sequentially through a first etch method portions of the blanket first masking layer and the upper metallization layer sequentially exposed through the patterned second masking layer to yield a patterned first masking layer and a patterned upper metallization layer; and etching through a second etch method portions of the lower metallization layer exposed through the pattern of the patterned first masking layer and the patterned upper metallization layer to form a patterned lower metallization layer, where the patterned second masking layer is removed after the first etch method and before the second etch method.
Claim 2
Independent Claim 272 words
A method for forming a patterned conductor metallization layer adjoining a patterned barrier metallization layer over a semiconductor substrate comprising: providing a semiconductor substrate: forming over the semiconductor substrate a blanket conductor metallization layer adjoining a blanket barrier metallization layer, the blanket barrier metallization layer being formed from a barrier material selected from the group of barrier materials consisting of metal silicide barrier materials and metal nitride barrier materials, where one of the blanket conductor metallization layer and the blanket barrier metallization layer is an upper metallization layer formed further removed from the semiconductor substrate and the other of the blanket conductor metallization and the blanket barrier metallization layer is a lower metallization layer formed closer to the semiconductor substrate; forming a blanket first masking layer upon the surface of the upper metallization layer, the blanket first masking layer being formed from a material selected from the group of materials consisting of silicon oxide materials, silicon nitride materials and silicon oxynitride materials; forming a patterned second masking layer upon the surface of the blanket first masking layer; etching sequentially through a first etch method portions of the blanket first masking layer and the upper metallization layer sequentially exposed through the patterned second masking layer to yield a patterned first masking layer and a patterned upper metallization layer; and etching through a second etch method portions of the lower metallization layer exposed through the pattern of the patterned first masking layer and the patterned upper metallization layer to form a patterned lower metallization layer, where the patterned second masking layer is removed after the first etch method and before the second etch method.
Claim 3
Dependent Claim 29 words
The method of claim 1 wherein the patterned second masking layer is formed upon the blanket first masking layer at a thickness of about 15000 to about 20000 angstroms.
Claim 4
Dependent Claim 17 words
The method of claim 2 wherein the patterned second masking layer is formed from an organic photoresist.
Claim 5
Dependent Claim 28 words
The method of claim 1 wherein the blanket first masking layer is formed upon the upper metallization layer at a thickness of about 1000 to about 3000 angstroms.
Claim 6
Dependent Claim 27 words
The method of claim 1 wherein the blanket conductor metallization layer is formed over the semiconductor substrate at a thickness of about 5000 to about 8000 angstroms.
Claim 7
Dependent Claim 23 words
The method of claim 5 wherein the blanket conductor metallization layer is formed from an aluminum alloy containing at least 90 percent aluminum.
Claim 8
Dependent Claim 15 words
The method of claim 6 wherein the blanket conductor metallization layer is formed from copper.
Claim 9
Dependent Claim 27 words
The method of claim 1 wherein the blanket barrier metallization layer is formed upon the semiconductor substrate at a thickness of about 1000 to about 3000 angstroms.
Claim 10
Independent Claim 275 words
A method for forming a patterned conductor metallization layer adjoining a patterned barrier metallization layer over a semiconductor substrate comprising: providing a semiconductor substrate; forming over the semiconductor substrate a blanket conductor metallization layer adjoining a blanket barrier metallization layer, the blanket barrier metallization layer being formed from a barrier material selected from the group of barrier materials consisting of metal silicide barrier materials and metal nitride barrier materials, where one of the blanket conductor metallization layer and the blanket barrier metallization layer is an upper metallization layer formed further removed from the semiconductor substrate and the other of the blanket conductor metallization and the blanket barrier metallization layer is a lower metallization layer formed closer to the semiconductor substrate; forming a blanket first masking layer upon the surface of the upper metallization layer, the blanket first masking layer being formed from a material selected from the group of materials consisting of silicon oxide materials, silicon nitride materials and silicon oxynitride materials; forming a patterned second masking layer upon the surface of the blanket first masking layer; etching sequentially in-situ through a first etch method portions of the blanket first masking layer and the upper metallization layer sequentially exposed through the patterned second masking layer to yield a patterned first masking layer and a patterned upper metallization layer; and etching in-situ through a second etch method portions of the lower metallization layer exposed through the pattern of the patterned first masking layer and the patterned upper metallization layer to form a patterned lower metallization layer, where the patterned second masking layer is removed in-situ after the first etch method and before the second etch method.
Claim 11
Independent Claim 275 words
A method for forming a patterned conductor metallization layer adjoining a patterned barrier metallization layer over a semiconductor substrate comprising: providing a semiconductor substrate; forming over the semiconductor substrate a blanket conductor metallization layer adjoining a blanket barrier metallization layer, the blanket barrier metallization layer being formed from a barrier material selected from the group of barrier materials consisting of metal silicide barrier materials and metal nitride barrier materials, where one of the blanket conductor metallization layer and the blanket barrier metallization layer is an upper metallization layer formed further removed from the semiconductor substrate and the other of the blanket conductor metallization and the blanket barrier metallization layer is a lower metallization layer formed closer to the semiconductor substrate; forming a blanket first masking layer upon the surface of the upper metallization layer, the blanket first masking layer being formed from a material selected from the group of materials consisting of silicon oxide materials, silicon nitride materials and silicon oxynitride materials; forming a patterned second masking layer upon the surface of the blanket first masking layer; etching sequentially in-situ through a first etch method portions of the blanket first masking layer and the upper metallization layer sequentially exposed through the patterned second masking layer to yield a patterned first masking layer and a patterned upper metallization layer; and etching in-situ through a second etch method portions of the lower metallization layer exposed through the pattern of the patterned first masking layer and the patterned upper metallization layer to form a patterned lower metallization layer, where the patterned second masking layer is removed in-situ after the first etch method and before the second etch method.
Claim 12
Dependent Claim 35 words
The method of claim 9 wherein the patterned second masking layer is formed from a an organic photoresist formed upon the blanket first masking layer at a thickness of about 15000 to about 20000 angstroms.
Claim 13
Dependent Claim 24 words
The method of claim 10 wherein the patterned second masking layer is removed in-situ through a Reactive Ion Etch (RIE) plasma process employing ozone.
Claim 14
Dependent Claim 28 words
The method of claim 9 wherein the blanket first masking layer is formed upon the upper metallization layer at a thickness of about 1000 to about 3000 angstroms.
Claim 15
Dependent Claim 33 words
The method of claim 12 wherein the blanket first masking layer is etched in-situ to form the patterned first masking layer through exposure to a Reactive Ion Etch (RIE) plasma containing fluorine species.
Claim 16
Dependent Claim 46 words
The method of claim 9 wherein the blanket conductor metallization layer is formed over the semiconductor substrate at a thickness of about 5000 to about 8000 angstroms and the blanket conductor metallization layer is formed from an aluminum alloy which contains at least 90 percent aluminum.
Claim 17
Dependent Claim 33 words
The method of claim 14 wherein the blanket conductor metallization layer is etched in-situ to form the patterned conductor metallization layer through exposure to a Reactive Ion Etch (RIE) plasma containing chlorine species.
Claim 18
Dependent Claim 27 words
The method of claim 9 wherein the blanket barrier metallization layer is formed upon the semiconductor substrate at a thickness of about 1000 to about 3000 angstroms.

References Cited (Backward Citations)

US4410622A Cited
US4954423A Cited
US5436199A Cited
US5369053A Cited
US5346586A Cited
US5518963A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2000-12-22 2001-06-23 2001-12-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-12-22 2005-06-23 2005-12-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2008-12-22 2009-06-23 2009-12-23 $7700.00 Window Closed / Lapsed

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