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US5693693A Expired / Lapsed US ⏱️ 0.0 years remaining

Bar code printing and scanning using wax based invisible fluorescent inks

Assignee: Syngenta Ltd
•
Filing: 1994-12-01
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Granted: 1997-12-02
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Expires: 2014-12-01
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Abstract

Abstract Wax based invisible inks have been discovered that emit light at various wavelengths in the visible region when they are excited by UV light. This allows lower layer clear text information to be written on an object with a regular, visible ink and an upper layer bar code to be written over the lower layer text information with an ink that is invisible to the naked eye. This allows the lower layer text information and upper layer bar code to contain more information than conventional bar codes. These inks allow printing and decoding invisible bar codes over printed information with visible inks. The detection by fluorescence of these invisible inks provides a high signal to noise ratio and no interference with the visible printed information.

Inventors

  • 👤 Judith D. Auslander
  • 👤 William Berson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 23:21
CPC Classifications
G; G06; G06K; G06K19/00; G06K19/06; G06K19/06009; G06K19/06037; C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/35; C08K5/357; C09; C09D; C09D11/00; C09D11/50; G06K1/00; G06K1/12; G06K1/121; G06K7/00; G06K7/10; G06K7/12; Y; Y10; Y10S; Y10S260/00; Y10S260/38

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 43 words
An ink composition comprising: a) 0.5 to 10% of 2-aryl-4H3, 1 or 2-(2-arylsulfonylaminophenyl-4H-3, 1-G benzoxazinone, 4); b) 65 to 85% of urethane compound of a synthetic petroleum wax; c) 4 to 15% carnauba wax; and d) 10 to 20% ethyl vinyl acetate polymer.
Claim 2
Dependent Claim 43 words
An ink composition comprising: a) 0.5 to 10% of 2-aryl-4H3, 1 or 2-(2-arylsulfonylaminophenyl-4H-3, 1-G benzoxazinone, 4); b) 65 to 85% of urethane compound of a synthetic petroleum wax; c) 4 to 15% carnauba wax; and d) 10 to 20% ethyl vinyl acetate polymer.
Claim 3
Dependent Claim 97 words
An ink composition comprising: a) 0.5 to 10% complexes of rare earth metal ions M 3+ , of the general formula: BM(L.sub.2) where; B is a cation such as Na + , Li + , NH 4 + ; M is a metal ion from the lanthanide group; and L is a chromphore ligand dispersed in; b) the complexes are dissolved in 65 to 85% of a wax selected from polyethylene wax, natural parafin wax and urethane derivative of oxidized synthetic wax; c) 4 to 15% carnauba wax; and d) 10 to 20% ethyl vinyl acetate polymer.
Claim 4
Dependent Claim 97 words
An ink composition comprising: a) 0.5 to 10% complexes of rare earth metal ions M 3+ , of the general formula: BM(L.sub.2) where; B is a cation such as Na + , Li + , NH 4 + ; M is a metal ion from the lanthanide group; and L is a chromphore ligand dispersed in; b) the complexes are dissolved in 65 to 85% of a wax selected from polyethylene wax, natural parafin wax and urethane derivative of oxidized synthetic wax; c) 4 to 15% carnauba wax; and d) 10 to 20% ethyl vinyl acetate polymer.
Claim 5
Dependent Claim 43 words
The complex claimed in claim 2, wherein the lanthanide is selected from the group of Pr 3+ , Nd 3+ , Sm 3+ , Eu 3+ , Tb 3+ , Dy 3+ , Yb 3+ , Er 3+ , and Tm 3+ .
Claim 6
Dependent Claim 56 words
The composition claimed in claim 2, wherein the chromophore ligand is selected from the group of β diketones of the general formula: ##STR4## where R 1 and R 2 belong to the groups of the alkyl radical C 1 -C 18 radical of halogenated C 1 -C 18 , (fluorinated or chlorinated) radical, phenyl, and thienyl.
Claim 7
Dependent Claim 46 words
The ink claimed in claim 2, wherein the chromphore ligand can be represented by the formula: ##STR5## where: R 3 is an alkyl group C 1 -C 18 or an halogenated alkyl with the same length. R4, R5, R6 and R7 are identical groups or different.

References Cited (Backward Citations)

FR1471367A Cited
US4572803A Cited
GB2090194A Cited
US4918047A Cited
JPS63191870A Cited
EP0340898A2 Cited
US5431697A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2000-12-01 2001-06-02 2001-12-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-12-01 2005-06-02 2005-12-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2008-12-01 2009-06-02 2009-12-02 $7700.00 Window Closed / Lapsed

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