Polarizer films comprising wholly aromatic liquid crystalline polymers and dichroic dyes

Claim 2

A polarizing film having a polarizing efficiency of at least 70% and comprising a blend of a film-forming, wholly aromatic thermotropic liquid crystal polymer and a dichroic dye, with said liquid crystal polymer being a polyester which comprises repeat units corresponding to the formula: - P.sup.1 !.sub.m - P.sup.2 !.sub.n - P.sup.3 !.sub.q - wherein P 1 , P 2 , and P 3 represent monomeric moieties with P 1 being an aromatic hydroxy carboxylic acid, P 2 being an aromatic dicarboxylic acid, and P 3 being a phenol, with m, n and q representing mole percent of the respective monomers ranging from 5-70 mole percent individually.

Claim 3

The polarizing film of claim 1, wherein said repeat unit further comprises monomeric moieties - P 4 ! r - and P 5 ! s -, wherein P 4 represents a second aromatic hydroxy carboxylic acid different from P 1 , P 5 represents a second phenolic moiety different from P 3 , and r and s represent mole percent of the respective monomers ranging from 5-20 mole percent individually.

Claim 4

The polarizing film of claim 1, wherein P 1 is selected from the group consisting of 4-hydroxybenzoic acid, 2-hydroxy-6-naphthoic acid, and 4-carboxy-4'-hydroxy-1,1'-biphneyl.

Claim 5

The polarizing film of claim 1, wherein P 2 is selected from the group consisting of terephthalic acid, isophthalic acid, phthalic acid, 2-phenylterephthalic acid, 1,2-naphthalenedicarboxylic acid, 1,4-naphthalenedicarboxylic acid, 2,6-naphthalene dicarboxylic acid and 4,4'-biphenyldicarboxylic acid.

Claim 6

The polarizing film of claim 1, wherein P 3 is selected from the group consisting of resorcinol, hydroquinone, methyl hydroquinone, phenyl hydroquinone, catechol, 4,4'-dihydroxybiphenyl and acetaminophen.

Claim 7

The polarizing film of claim 2, wherein said P 5 is a diphenol selected from resorcinol, hydroquinone, catechol, 4,4'-dihydroxybiphenyl, bisphenol-A and acetaminophen.

Claim 8

The polarizing film of claim 3, wherein P 1 is 4-hydroxybenzoic acid.

Claim 9

The polarizing film of claim 3, wherein P 1 is 2-hydroxy-6-naphthoic acid.

Claim 10

The polarizing film of claim 4, wherein P 2 is terephthalic acid.

Claim 11

The polarizing film of claim 5, wherein P 3 is resorcinol.

Claim 12

The polarizing film of claim 5, wherein P 3 is 4,4'-dihydroxybiphenyl.

Claim 13

The polarizing film of claim 2, wherein said P 4 is 4-hydroxybenzoic acid.

Claim 14

The polarizing film of claim 6, wherein said P 5 is resorcinol.

Claim 15

The polarizing film of claim 1, wherein said dye is selected from the group consisting of straight chain dye, branched dye, direct dye, disperse dye, solvent dye and acidic dye.

Claim 16

The polarizing film of claim 1, wherein said dye is selected from the group consisting of azo dyes, anthraquinone dyes, Disperse Red, Blue 214, Red 60 and Yellow 56, Black 17, 19 and 154, Brown 44, 106, 195, 210, 242 and 247, Blue 1, 15, 22, 78, 90, 98, 151, 168, 202, 236, 249, and 270, Violet 9, 12, 51, and 98, Green 1 and 85, Yellow 8, 12, 44, 86, and 87, Orange 26, 39, 106 and 107, and Methylene violet Bernthsen.

Claim 17

The polarizing film of claim 15, wherein said dye is an anthraquinone dye.

Claim 18

The polarizing film of claim 1, wherein said blend is prepared by melt blending said polymer and said dye.

Claim 19

A polarizing film having a polarizing efficiency of at least 70% and comprising a blend of (a) a film-forming wholly aromatic thermotropic liquid crystal polyester which comprises 4-hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid, terephthalic acid, 4,4'-dihydroxybiphenyl and resorcinol in a molar ratio 30:30:20:10:10 respectively, and (b) a dichroic dye.

Claim 20

A polarizing film having a polarizing efficiency of at least 70% and comprising a blend of (a) a film-forming wholly aromatic thermotropic liquid crystal polyester which comprises 4-hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid, terephthalic acid, 4,4'-dihydroxybiphenyl and resorcinol in a molar ratio 30:30:20:10:10 respectively, and (b) a dichroic dye.

Claim 21

A process of preparing a polarizer film-forming composition, which process comprises: (a) preparing a suitable film-forming, wholly aromatic thermotropic liquid crystal polymer and (b) blending said liquid crystal polymer with one or more suitable dichroic dyes by a suitable process to form the polarizer film-forming composition, with said liquid crystal polymer being a polyester or a polyesteramide, wherein said polyester comprises repeat units corresponding to the formula: - P.sup.1 !.sub.m - P.sup.2 !.sub.n - P.sup.3 !.sub.q - wherein P 1 , P 2 , and P 3 represent monomeric moieties with P 1 being an aromatic hydroxy carboxylic acid, P 2 being an aromatic dicarboxylic acid, and P 3 being a phenol; and further wherein said polyesteramide comprises repeat units corresponding to the formula: - P.sup.4 !.sub.m - P.sup.5 !.sub.n - P.sup.6 !.sub.q - wherein P 4 , P 5 , and P 6 represent monomeric moieties with P 4 being an aromatic amino carboxylic acid, P 5 being an aromatic dicarboxylic acid, and P 6 being a phenol; with m, n and q representing mole percent of the respective monomers ranging from 5-70 mole percent individually.

Claim 22

A process of preparing a polarizer film-forming composition, which process comprises: (a) preparing a suitable film-forming, wholly aromatic thermotropic liquid crystal polymer and (b) blending said liquid crystal polymer with one or more suitable dichroic dyes by a suitable process to form the polarizer film-forming composition, with said liquid crystal polymer being a polyester or a polyesteramide, wherein said polyester comprises repeat units corresponding to the formula: - P.sup.1 !.sub.m - P.sup.2 !.sub.n - P.sup.3 !.sub.q - wherein P 1 , P 2 , and P 3 represent monomeric moieties with P 1 being an aromatic hydroxy carboxylic acid, P 2 being an aromatic dicarboxylic acid, and P 3 being a phenol; and further wherein said polyesteramide comprises repeat units corresponding to the formula: - P.sup.4 !.sub.m - P.sup.5 !.sub.n - P.sup.6 !.sub.q - wherein P 4 , P 5 , and P 6 represent monomeric moieties with P 4 being an aromatic amino carboxylic acid, P 5 being an aromatic dicarboxylic acid, and P 6 being a phenol; with m, n and q representing mole percent of the respective monomers ranging from 5-70 mole percent individually.

Claim 23

The process of claim 19, wherein said repeat units further comprise a second aromatic hydroxy carboxylic acid monomeric moiety different from P 1 , and a second phenolic monomeric moiety different from P 3 .

Claim 24

A polarizing film having a polarizing efficiency of at least 70% and comprising a blend of a film-forming, wholly aromatic thermotropic liquid crystal polymer and a dichroic dye, with said liquid crystal polymer being a polyesteramide which comprises repeat units corresponding to the formula: - P.sup.1 !.sub.m - P.sup.2 !.sub.n - P.sup.3 !.sub.q - wherein P 1 , P 2 , and P 3 represent monomeric moieties with P 1 being an aromatic amino carboxylic acid, P 2 being an aromatic dicarboxylic acid, and P 3 being a phenol with m, n and q representing mole percent of the respective monomers ranging from 5-70 mole percent individually.

Claim 25

A polarizing film having a polarizing efficiency of at least 70% and comprising a blend of a film-forming, wholly aromatic thermotropic liquid crystal polymer and a dichroic dye, with said liquid crystal polymer being a polyesteramide which comprises repeat units corresponding to the formula: - P.sup.1 !.sub.m - P.sup.2 !.sub.n - P.sup.3 !.sub.q - wherein P 1 , P 2 , and P 3 represent monomeric moieties with P 1 being an aromatic amino carboxylic acid, P 2 being an aromatic dicarboxylic acid, and P 3 being a phenol with m, n and q representing mole percent of the respective monomers ranging from 5-70 mole percent individually.

Claim 26

The polarizer film of claim 21, wherein P 1 is 4-aminobenzoic acid.