Patent US5659173A successfully refreshed from Google Patents.
← Back to Patent Explorer
US5659173A Expired / Lapsed US ⏱️ 0.0 years remaining

Converting acoustic energy into useful other energy forms

Assignee: University of California
•
Filing: 1994-02-23
•
Granted: 1997-08-19
•
Expires: 2014-02-23
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Sonoluminescence is an off-equilibrium phenomenon in which the energy of a resonant sound wave in a liquid is highly concentrated so as to generate flashes of light. The conversion of sound to light represents an energy amplification of eleven orders of magnitude. The flashes which occur once per cycle of the audible or ultrasonic sound fields can be comprised of over one million photons and last for less 100 picoseconds. The emission displays a clocklike synchronicity; the jitter in time between consecutive flashes is less than fifty picoseconds. The emission is blue to the eye and has a broadband spectrum increasing from 700 nanometers to 200 nanometers. The peak power is about 100 milliWatts. The initial stage of the energy focusing is effected by the nonlinear oscillations of a gas bubble trapped in the liquid. For sufficiently high drive pressures an imploding shock wave is launched into the gas by the collapsing bubble. The reflection of the shock from its focal point results in high temperatures and pressures. The sonoluminescence light emission can be sustained by sensing a characteristic of the emission and feeding back changes into the driving mechanism. The liquid is in a sealed container and the seeding of the gas bubble is effected by locally heating the liquid after sealing the container. Different energy forms than light can be obtained from the converted acoustic energy. When the gas contains deuterium and tritium there is the feasibility of the other energy form being fusion, namely including the generation of neutrons.

Inventors

  • 👤 Seth J. Putterman
  • 👤 Bradley Paul Barber
  • 👤 Robert Anthony Hiller
  • 👤 Ritva Maire Johanna Lofstedt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 19:26
CPC Classifications
G; G21; G21B; G21B3/00; Y; Y02; Y02E; Y02E30/00; Y02E30/10

Claims Analysis

Total Claims: 101
Claim 1
Independent Claim 116 words
A method of converting acoustic energy into a different energy form comprising: creating a gaseous bubble in a liquid in a container, locating the bubble in a liquid under the action of acoustic energy applied to the liquid, compressing and decompressing the bubble under the action of resonating pressure applied to the liquid by the acoustic energy, increasing the resonating pressure to generate from the bubble an emission of the different energy form, and sensing selectively at least one of a characteristic of the different energy form, bubble or acoustic energy and feeding back changes in the characteristic to regulate the generation of acoustic energy thereby to sustain the emission generation of the different energy form.
Claim 2
Independent Claim 116 words
A method of converting acoustic energy into a different energy form comprising: creating a gaseous bubble in a liquid in a container, locating the bubble in a liquid under the action of acoustic energy applied to the liquid, compressing and decompressing the bubble under the action of resonating pressure applied to the liquid by the acoustic energy, increasing the resonating pressure to generate from the bubble an emission of the different energy form, and sensing selectively at least one of a characteristic of the different energy form, bubble or acoustic energy and feeding back changes in the characteristic to regulate the generation of acoustic energy thereby to sustain the emission generation of the different energy form.
Claim 3
Dependent Claim 30 words
A method as claimed in claim 1 including sealing the container against the ingress or egress at least one of the liquid or gas and forming the bubble after sealing.
Claim 4
Dependent Claim 37 words
A method as claimed in claim 2 including forming the gas bubble by subjecting a selected area of the liquid in the container to a heat sufficient to form a gas from the liquid in the area.
Claim 5
Dependent Claim 21 words
A method as claimed in claim 2 including forming the gas by boiling liquid in an area to form a cavity.
Claim 6
Dependent Claim 19 words
A method as claimed in claim 2 including forming the gas by electrolyzing the liquid to form a gas.
Claim 7
Dependent Claim 20 words
A method as claimed in claim 2 including degassing the liquid to a predetermined level prior to sealing the container.
Claim 8
Dependent Claim 20 words
A method as claimed in claim 2 including introducing a selected gas to the liquid prior to sealing the container.
Claim 9
Dependent Claim 29 words
A method as claimed in claim 2 including degassing the liquid to a predetermined amount and adding a selected gas to a predetermined level prior to sealing the container.
Claim 10
Dependent Claim 15 words
A method as claimed in claim 1 wherein the different energy form is light energy.
Claim 11
Dependent Claim 57 words
A method as claimed in claim 9 wherein the light energy includes pulses of a duration of less than about 100 picoseconds, and having a peak power of about 100 milliwatts, a spectrum of about 200 nanometers to about 700 nanometers and a repetition rate between about 100,000 cycles per second to about 1,000 cycles per second.
Claim 12
Dependent Claim 65 words
A method as claimed in claim 1 wherein the bubble has a maximum radius under the action of the acoustic pressure varies from between about 10 microns to 50 microns at a predetermined time of a first pressure cycle applied by the acoustic pressure to an ambient radius of between about 10 and 2 microns at a second pressure cycle applied by the acoustic pressure.
Claim 13
Dependent Claim 58 words
A method as claimed in claim 1 wherein the bubble has a maximum radius between 10 microns and 50 microns during first predetermined time of the cycle during which pressure is applied by acoustic energy, and is an ambient radius of less than about 2 microns during another time period of when pressure is applied by acoustic energy.
Claim 14
Dependent Claim 48 words
A method as claimed in claim 12 wherein a decrease in the maximum radius from about 10 to 50 microns during the one time of the pressure cycle to an ambient radius of less than about 2 microns in the pressure cycle causes the emission of light energy.
Claim 15
Dependent Claim 25 words
A method as claimed in claim 13 wherein a maximum radius would be about 50 microns and the acoustic pressure would be about 1.3 Atmospheres.
Claim 16
Dependent Claim 23 words
A method as claimed in claim 1 wherein the liquid is selected from the group of water, oil, liquid nitrogen, and liquid argon.
Claim 17
Dependent Claim 32 words
A method as claimed in claim 1 wherein the gas is selected from the group of air, oxygen, xenon, helium, nitrogen, deuterium, tritium, argon, chlorine, neon, krypton, hydrogen and SF 6 .
Claim 18
Dependent Claim 32 words
A method as claimed in claim 16 wherein the gas is selected from the group of air, oxygen, xenon, helium, nitrogen, deuterium, tritium, argon, chlorine, neon, krypton, hydrogen and SF 6 .
Claim 19
Dependent Claim 16 words
A method as claimed in claim 1 including generating heat energy as the different energy form.
Claim 20
Dependent Claim 20 words
A method as claimed in claim 18 wherein the temperature of the heat energy is greater than about 50,000 K.
Claim 21
Dependent Claim 26 words
A method as claimed in claim 1 wherein the acoustic energy causes a bubble to collapse in size to less than about 5 microns ambient radius.
Claim 22
Dependent Claim 26 words
A method as claimed in claim 1 wherein the acoustic energy causes a bubble to collapse in size to less than about 2 microns ambient radius.
Claim 23
Dependent Claim 46 words
A method as claimed in claim 1 wherein prior to generating the different energy form the size of the bubble is greater than about 10 microns and after the generation of the different energy form the size of the bubble is less than about 5 microns.
Claim 24
Dependent Claim 15 words
A method as claimed in claim 22 wherein the different energy form is light energy.
Claim 25
Dependent Claim 45 words
A method as claimed in claim 1 wherein prior to generating the different energy form the size of the bubble is greater than about 10 microns and after the generation of the different energy form the size of the bubble is less than 2 microns.
Claim 26
Dependent Claim 15 words
A method as claimed in claim 24 wherein the different energy form is light energy.
Claim 27
Dependent Claim 23 words
A method as claimed in claim 1 wherein the acoustic energy creates an imploding shock wave emanating in the gas in the bubble.
Claim 28
Dependent Claim 47 words
A method as claimed in claim 1 including applying a spherical imploding shock wave to the bubble, the shock wave having a central focal point and the shock wave creating a temperature adjacent to a focal point in a range of greater than about 10 8 K.
Claim 29
Dependent Claim 31 words
A method as claimed in claim 27 wherein the shock wave reflects from the focal point and attains the temperature greater than 10 8 K. after reflection from the focal point.
Claim 30
Dependent Claim 31 words
A method as claimed in claim 28 wherein the temperature of 10 8 K. is attained at less than about 100 Angstroms from the focal point of the spherical shock wave.
Claim 31
Dependent Claim 26 words
A method as claimed in claim 29 wherein the gas includes at least deuterium and tritium and the different energy form includes the generation of fusion.
Claim 32
Dependent Claim 34 words
A method as claimed in claim 27 including locating deuterium and tritium gas in the bubble and wherein the shock wave generates a different energy form including generating at least one neutron per second.
Claim 33
Dependent Claim 45 words
A method as claimed in claim 1 wherein the characteristic of the different energy form being sensed includes at least one of the repetition rate of the occurrence of different energy form when such energy form are pulses, and the intensity of such energy form.
Claim 34
Dependent Claim 28 words
A method as claimed in claim 32 wherein both the frequency between recurrent pulses of the different energy form and the intensity of the energy form is sensed.
Claim 35
Dependent Claim 33 words
A method as claimed in claim 33 wherein sensing of the characteristic of the different energy form is applied to control the frequency and amplitude of the acoustic energy applied to the liquid.
Claim 36
Dependent Claim 15 words
A method as claimed in claim 33 wherein the different energy form is light energy.
Claim 37
Dependent Claim 33 words
A method as claimed in claim 32 wherein sensing of the characteristic of the different energy form is applied to control the frequency and amplitude of the acoustic energy applied to the liquid.
Claim 38
Dependent Claim 15 words
A method as claimed in claim 36 wherein the different energy form is light energy.
Claim 39
Dependent Claim 15 words
A method as claimed in claim 32 wherein the different energy form is light energy.
Claim 40
Dependent Claim 33 words
A method as claimed in claim 1 wherein sensing of the different characteristic is applied to control at least one of the frequency and amplitude of the acoustic energy applied to the liquid.
Claim 41
Dependent Claim 15 words
A method as claimed in claim 39 wherein the different energy form is light energy.
Claim 42
Dependent Claim 15 words
A method as claimed in claim 39 wherein the different energy form is light energy.
Claim 43
Dependent Claim 27 words
A method as claimed in claim 1 wherein the different energy form outputs energy at the same frequency as the acoustic energy is applied to the liquid.
Claim 44
Dependent Claim 15 words
A method as claimed in claim 42 wherein the different energy form is light energy.
Claim 45
Dependent Claim 78 words
A method of determining the existence of fluorescence in a sample comprising: applying the energy conversion method of claim 1 to generate a light energy, applying the light energy to the sample, obtaining an output of the light energy, obtaining at least one of a temporal characteristic or an output spectrum from the sample and determining a difference between the light energy and the sample temporal characteristic or spectrum as a measure of the fluorescence in the sample.
Claim 46
Dependent Claim 32 words
A method as claimed in claim 44 including obtaining multiple fluorescent spectra or at the same moment from the sample, the multiple spectra being indicative of multiple different fluorescences in the sample.
Claim 47
Dependent Claim 22 words
A method as claimed in claim 45 wherein the spectrum of the light energy is from about 200 nanometers to 700 nanometers.
Claim 48
Dependent Claim 62 words
A method of calibrating a detector comprising applying the method of claim 1 to generate a different energy form wherein the different energy form is light, applying the light to at least one detector, obtaining an output from the light, and from the detector, and calibrating the detector in relation to the difference between the output from the light and the detector.
Claim 49
Dependent Claim 50 words
A method as claimed in claim 47 including calibrating an array of detectors for transit time spread comprising applying the light energy to the multiple detectors and obtaining respective outputs from the detectors, and calibrating the detectors in relation to the respective outputs and the output of the light energy.
Claim 50
Dependent Claim 15 words
A method as claimed in claim 1 including cooling the liquid below about 40° C.
Claim 51
Dependent Claim 15 words
A method as claimed in claim 1 including cooling the liquid below about 10° C.
Claim 52
Dependent Claim 14 words
A method as claimed in claim 1 including the liquid to about 1° C.
Claim 53
Dependent Claim 17 words
A method as claimed in claim 1 including doping the gas bubble with a second selected gas.
Claim 54
Dependent Claim 33 words
A method as claimed in claim 1 wherein the gas is a mixture of deuterium and tritium and wherein the gas is doped with a second gas, such second gas being selectively Argon.
Claim 55
Independent Claim 131 words
An apparatus for converting acoustic energy into a different energy form comprising: a container for a liquid containing a gaseous bubble in a liquid in the container, means for applying acoustic energy to the container thereby locating the bubble in the liquid under the action of the acoustic energy applied to the liquid, means for compressing and decompressing the bubble under the action of resonating pressure applied to the liquid by the acoustic energy, means for increasing the resonating pressure to generate from the bubble an emission of the different energy form, and means for sensing selectively at least one of a characteristic of the different energy form, bubble or acoustic energy and means for feeding back changes in the characteristic thereby to sustain the generation of the different energy form.
Claim 56
Independent Claim 131 words
An apparatus for converting acoustic energy into a different energy form comprising: a container for a liquid containing a gaseous bubble in a liquid in the container, means for applying acoustic energy to the container thereby locating the bubble in the liquid under the action of the acoustic energy applied to the liquid, means for compressing and decompressing the bubble under the action of resonating pressure applied to the liquid by the acoustic energy, means for increasing the resonating pressure to generate from the bubble an emission of the different energy form, and means for sensing selectively at least one of a characteristic of the different energy form, bubble or acoustic energy and means for feeding back changes in the characteristic thereby to sustain the generation of the different energy form.
Claim 57
Dependent Claim 31 words
Apparatus as claimed in claim 54 including means for sealing the container against the ingress or egress of at least one of liquid or gas and forming the bubble after sealing.
Claim 58
Dependent Claim 38 words
Apparatus as claimed in claim 55 including means for forming the gas bubble by subjecting a selected area of the liquid in the container to a heat sufficient to form a gas from the liquid in the area.
Claim 59
Dependent Claim 22 words
Apparatus as claimed in claim 55 including means for forming the gas by boiling liquid in an area to form a cavity.
Claim 60
Dependent Claim 20 words
Apparatus as claimed in claim 55 including means for forming the gas by electrolyzing the liquid to form a gas.
Claim 61
Dependent Claim 21 words
Apparatus as claimed in claim 55 including means for degassing the liquid to a predetermined level prior to sealing the container.
Claim 62
Dependent Claim 21 words
Apparatus as claimed in claim 55 including means for introducing a selected gas to the liquid prior to sealing the container.
Claim 63
Dependent Claim 30 words
Apparatus as claimed in claim 55 including means for degassing the liquid to a predetermined level and adding a selected gas to a predetermined amount prior to sealing the container.
Claim 64
Dependent Claim 14 words
Apparatus as claimed in claim 54 wherein the different energy form is light energy.
Claim 65
Dependent Claim 56 words
Apparatus as claimed in claim 62 wherein the generated light energy includes pulses of a duration of less than about 100 picoseconds, and having a peak power of about 100 milliwatts, a spectrum of about 200 nanometers to about 700 nanometers and a repetition rate between about 100,000 cycles per second to 1,000 cycles per second.
Claim 66
Dependent Claim 63 words
Apparatus as claimed in claim 54 wherein the bubble has a maximum radius under the action of the acoustic pressure varies from between about 10 microns to 50 microns at a predetermined time of first pressure cycle applied by the acoustic pressure to an ambient radius of between about 10 and 2 microns at a second pressure cycle applied by the acoustic pressure.
Claim 67
Dependent Claim 57 words
Apparatus as claimed in claim 54 wherein the bubble has a maximum radius between 10 microns and 50 microns during one predetermined time of the cycle during which pressure is applied by acoustic energy, and is an ambient radius of less than about 2 microns during another time period of when pressure is applied by acoustic energy.
Claim 68
Dependent Claim 47 words
Apparatus as claimed in claim 65 wherein a decrease in the maximum radius from about 10 to 50 microns during the one time of the pressure cycle to an ambient radius of less than about 2 microns in the pressure cycle causes the emission of light energy.
Claim 69
Dependent Claim 23 words
Apparatus as claimed in claim 66 wherein the maximum radius is about 50 microns and the acoustic pressure would be about 1.3 Atmospheres.
Claim 70
Dependent Claim 22 words
Apparatus as claimed in claim 54 wherein a liquid is selected from the group of water, oil, liquid nitrogen and liquid argon.
Claim 71
Dependent Claim 31 words
Apparatus as claimed in claim 54 wherein the gas is selected from the group of air, oxygen, xenon, helium, nitrogen, deuterium, tritium, argon, chlorine, neon, krypton, hydrogen and SF 6 .
Claim 72
Dependent Claim 31 words
Apparatus as claimed in claim 69 wherein the gas is selected from the group of air, oxygen, xenon, helium, nitrogen, deuterium, tritium, argon, chlorine, neon, krypton, hydrogen and SF 6 .
Claim 73
Dependent Claim 15 words
Apparatus as claimed in claim 54 including generating heat energy as the different energy form.
Claim 74
Dependent Claim 19 words
Apparatus as claimed in claim 71 wherein the temperature of the heat energy is greater than about 50,000 K.
Claim 75
Dependent Claim 25 words
Apparatus as claimed in claim 54 wherein the acoustic energy causes a bubble to collapse in size to less than about 5 microns ambient radius.
Claim 76
Dependent Claim 25 words
Apparatus as claimed in claim 54 wherein the acoustic energy causes a bubble to collapse in size to less than about 2 microns ambient radius.
Claim 77
Dependent Claim 44 words
Apparatus as claimed in claim 54 wherein prior to generating the different energy form the size of the bubble is greater than about 10 microns and after the generation of the different energy form the size of the bubble is less than 5 microns.
Claim 78
Dependent Claim 14 words
Apparatus as claimed in claim 75 wherein the different energy form is light energy.
Claim 79
Dependent Claim 14 words
Apparatus as claimed in claim 76 wherein the different energy form is light energy.
Claim 80
Dependent Claim 44 words
Apparatus as claimed in claim 54 wherein prior to generating the different energy form the size of the bubble is greater than about 10 microns and after the generation of the different energy form the size of the bubble is less than 2 microns.
Claim 81
Dependent Claim 22 words
Apparatus as claimed in claim 54 wherein the acoustic energy creates an imploding shock wave emanating in the gas in the bubble.
Claim 82
Dependent Claim 46 words
Apparatus as claimed in claim 54 including applying a spherical imploding shock wave to the bubble, the shock wave having a central focal point and the shock wave creating a temperature adjacent to the focal point in a range of greater than about 10 4 K.
Claim 83
Dependent Claim 30 words
Apparatus as claimed in claim 80 wherein the shock wave reflects from the focal point and attains the temperature greater than 10 4 K. after reflection from the focal point.
Claim 84
Dependent Claim 30 words
Apparatus as claimed in claim 81 wherein the temperature of 10 8 K. is attained at less than about 100 Angstroms from the focal point of the spherical shock wave.
Claim 85
Dependent Claim 34 words
Apparatus as claimed in claim 82 including means for locating deuterium and tritium gas in the bubble and wherein the shock wave generates a different energy form of at least one neutron per second.
Claim 86
Dependent Claim 25 words
Apparatus as claimed in claim 82 wherein the gas includes at least deuterium and tritium and the different energy form includes the generation of fusion.
Claim 87
Dependent Claim 41 words
Apparatus as claimed in claim 54 wherein the sensing means including means for sensing at least one of the repetition rate the occurrence of different energy form when such energy form appear as pulses, and the intensity of such energy form.
Claim 88
Dependent Claim 28 words
Apparatus as claimed in claim 85 including means for sensing both the time between recurrent pulses of the different energy form and the intensity of the energy form.
Claim 89
Dependent Claim 30 words
Apparatus as claimed in claim 86 wherein sensing of the different characteristic is applied to means for controlling at least one of the frequency and amplitude of the acoustic energy.
Claim 90
Dependent Claim 28 words
Apparatus as claimed in claim 86 wherein sensing of the characteristic of the different energy form is applied to control the frequency and amplitude of the acoustic energy.
Claim 91
Dependent Claim 30 words
Apparatus as claimed in claim 85 wherein sensing of the characteristic of the different energy form is applied to means for controlling the frequency and amplitude of the acoustic energy.
Claim 92
Dependent Claim 28 words
Apparatus as claimed in claim 85 wherein sensing of the characteristic of the different energy form is applied to control the frequency and amplitude of the acoustic energy.
Claim 93
Dependent Claim 95 words
Apparatus for determining the existence of fluorescence in a sample comprising means for applying the energy obtained from the apparatus of claim 54 to generate a light energy means for applying the light energy to sample, means for determining an output for the light energy, means for obtaining at least one of a temporal characteristic or an output spectrum from the sample, and means for determining a difference between the light energy and at least one of the temporal characteristic or the sample spectrum as a measure of the characteristics of fluorescence in the sample.
Claim 94
Dependent Claim 68 words
Apparatus for calibrating at least one detector comprising means for applying the energy obtained by the apparatus of claim 54 to obtain a light energy, means for applying the light energy to the detector to obtain an output, means for obtaining from the apparatus an output of the light energy, and means for calibrating the detector in relation to the difference between the output and the detector output.
Claim 95
Dependent Claim 22 words
Apparatus as claimed in claim 54 including means for cooling the liquid below about 40° C., and preferably to about 1° C.
Claim 96
Independent Claim 111 words
A method of measuring a characteristic of a liquid comprising: creating a gaseous bubble in a liquid in a container, the liquid having a quantity of dissolved gas: locating the bubble in a liquid under the action of acoustic energy applied to the liquid: compressing and decompressing the bubble under the action of resonating pressure applied to the liquid by the acoustic energy, scattering a laser light off the bubble to obtain a measure of the radius of the compressing and decompressing bubble as a function of time, and applying a diffusion equation to the varying radius over time to provide a measure of concentration of gas dissolved in the liquid.
Claim 97
Independent Claim 111 words
A method of measuring a characteristic of a liquid comprising: creating a gaseous bubble in a liquid in a container, the liquid having a quantity of dissolved gas: locating the bubble in a liquid under the action of acoustic energy applied to the liquid: compressing and decompressing the bubble under the action of resonating pressure applied to the liquid by the acoustic energy, scattering a laser light off the bubble to obtain a measure of the radius of the compressing and decompressing bubble as a function of time, and applying a diffusion equation to the varying radius over time to provide a measure of concentration of gas dissolved in the liquid.
Claim 98
Independent Claim 52 words
A method of seeding a gas in a liquid to create a bubble of gas in a liquid comprising degassing a liquid to a predetermined level, sealing the liquid against the ingress and egress of liquid, and applying heat to a predetermined area in the liquid to form a cavity or gas.
Claim 99
Independent Claim 52 words
A method of seeding a gas in a liquid to create a bubble of gas in a liquid comprising degassing a liquid to a predetermined level, sealing the liquid against the ingress and egress of liquid, and applying heat to a predetermined area in the liquid to form a cavity or gas.
Claim 100
Dependent Claim 113 words
Apparatus for measuring a characteristic of a liquid comprising: a container for liquid containing a dissolved gas, means for applying acoustic energy to the container for locating the bubble in a liquid under the action of the acoustic energy applied to the liquid: means for compressing and decompressing the bubble under the action of resonating pressure applied to the liquid by the acoustic energy, means for scattering a laser light off the bubble to obtain a measure of the radius of the bubble as a function of time, and means for applying a diffusion equation to the varying radius over time to provide a measure of concentration of gas dissolved in the liquid.
Claim 101
Dependent Claim 113 words
Apparatus for measuring a characteristic of a liquid comprising: a container for liquid containing a dissolved gas, means for applying acoustic energy to the container for locating the bubble in a liquid under the action of the acoustic energy applied to the liquid: means for compressing and decompressing the bubble under the action of resonating pressure applied to the liquid by the acoustic energy, means for scattering a laser light off the bubble to obtain a measure of the radius of the bubble as a function of time, and means for applying a diffusion equation to the varying radius over time to provide a measure of concentration of gas dissolved in the liquid.

References Cited (Backward Citations)

US4333796A Cited
US4948975A Cited
WO1990010935A1 Cited
JPH02281185A Cited
US4968395A Cited
JPH0353195A Cited
JPH0367196A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2000-08-18 2001-02-17 2001-08-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-08-18 2005-02-17 2005-08-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2008-08-18 2009-02-17 2009-08-19 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag