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US5646424A
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Transistor device employing crystallization catalyst
Assignee: Semiconductor Energy Laboratory Co Ltd
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Filing: 1995-06-07
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Granted: 1997-07-08
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Expires: 2015-06-07
Abstract
Abstract A thin film transistor includes a crystallized amorphous silicon film having a gate insulating film and a gate electrode formed thereon. The device includes impurities implanted in a self-aligned manner and a catalyst that accelerates the crystallization of the silicon film. The catalyst is introduced in the silicon film by adhering a coating containing the catalyst element and annealing the resulting structure at a temperature lower than the deformation temperature of the substrate to activate the doped impurities. The catalyst element can also be incorporated into the silicon film by means of ion implantation and the like. Also disclosed is a thin film transistor, which comprises a gate electrode, a gate insulating film, an amorphous silicon film having impurities implanted therein to form source and drain regions as the impurity regions, and a catalyst element introduced into the impurity regions by adhering a coating containing the catalyst element or by means of ion doping and the like, wherein the resulting structure is annealed at a temperature lower than the deformation temperature of the substrate to activate the doped impurities.
Inventors
- 👤 Hongyong Zhang
- 👤 Toru Takayama
- 👤 Yasuhiko Takemura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 07:28
CPC Classifications
H; H10; H10P; H10P30/00; H10P30/20; H10P30/202; H10P30/204; H10D; H10D30/00; H10D30/60; H10D30/67; H10D30/01; H10D30/021; H10D30/031; H10D30/0312; H10D30/0314; H10D30/0316; H10D30/0321; H10D30/6704; H10D30/6713; H10D30/6729; H10D30/673; H10D30/6731; H10D30/6732; H10D30/6737; H10D30/6739; H10D30/674; H10D30/6741; H10D30/6743; H10D30/6745; H10P14/00; H10P14/20; H10P14/34; H10P14/3402; H10P14/3404; H10P14/3411; H10P14/38; H10P14/3802; H10P14/3806; H10P30/208
Claims Analysis
Total Claims: 40
Claim 1
Independent Claim
86 words
A semiconductor device comprising: a semiconductor layer having a crystallinity formed on a substrate; a pair of impurity regions of P or N type conductivity formed in said semiconductor layer and impurity being contained in said pairs of impurity regions, wherein said semiconductor layer contains a catalyst at a concentration not higher than 1×10 20 atoms/cm 3 for promoting a crystallization thereof, and an inner edge of at least one of said impurity regions is substantially aligned with at least one edge of a gate electrode.
Claim 2
Dependent Claim
86 words
A semiconductor device comprising: a semiconductor layer having a crystallinity formed on a substrate; a pair of impurity regions of P or N type conductivity formed in said semiconductor layer and impurity being contained in said pairs of impurity regions, wherein said semiconductor layer contains a catalyst at a concentration not higher than 1×10 20 atoms/cm 3 for promoting a crystallization thereof, and an inner edge of at least one of said impurity regions is substantially aligned with at least one edge of a gate electrode.
Claim 3
Dependent Claim
30 words
The semiconductor device of claim 1 wherein said catalyst is a metal, wherein said metal is at least one selected from the group consisting of nickel, iron, cobalt and platinum.
Claim 4
Dependent Claim
85 words
A semiconductor device comprising: a semiconductor layer including at least a first region and a second region forming a junction therebetween, said first region having an intrinsic conductivity and said second region having P or N type conductivity with a crystallinity, wherein at least said second region contains a catalyst at a concentration not higher than 1×10 20 atoms/cm 3 for promoting a crystallization thereof, and an inner edge of said second region is substantially aligned with at least one edge of a gate electrode.
Claim 5
Dependent Claim
85 words
A semiconductor device comprising: a semiconductor layer including at least a first region and a second region forming a junction therebetween, said first region having an intrinsic conductivity and said second region having P or N type conductivity with a crystallinity, wherein at least said second region contains a catalyst at a concentration not higher than 1×10 20 atoms/cm 3 for promoting a crystallization thereof, and an inner edge of said second region is substantially aligned with at least one edge of a gate electrode.
Claim 6
Dependent Claim
30 words
The semiconductor device of claim 3 wherein said catalyst is a metal, wherein said metal is at least one selected from the group consisting of nickel, iron, cobalt and platinum.
Claim 7
Dependent Claim
84 words
A semiconductor device comprising: a semiconductor layer having a crystallinity and a pair of impurity regions formed in said semiconductor layer and doped with P or N type impurity, formed on a substrate; wherein said semiconductor layer contains a catalyst at a concentration not higher than 1×10 20 atoms/cm 3 for promoting activation of said P or N type impurity, and an inner edge of at least one of said impurity regions is substantially aligned with at least one edge of a gate electrode.
Claim 8
Dependent Claim
84 words
A semiconductor device comprising: a semiconductor layer having a crystallinity and a pair of impurity regions formed in said semiconductor layer and doped with P or N type impurity, formed on a substrate; wherein said semiconductor layer contains a catalyst at a concentration not higher than 1×10 20 atoms/cm 3 for promoting activation of said P or N type impurity, and an inner edge of at least one of said impurity regions is substantially aligned with at least one edge of a gate electrode.
Claim 9
Dependent Claim
30 words
The semiconductor device of claim 5 wherein said catalyst is a metal, wherein said metal is at least one selected from the group consisting of nickel, iron, cobalt and platinum.
Claim 10
Dependent Claim
87 words
A semiconductor device comprising: a semiconductor layer including at least a first region and a second region forming a junction therebetween, said first region having an intrinsic conductivity and said second region having P or N type conductivity with a crystallinity, wherein at least said second region contains a catalyst at a concentration not higher than 1×10 20 atoms/cm 3 for promoting activation of said second region, and an inner edge of said second region is substantially aligned with at least one edge of a gate electrode.
Claim 11
Dependent Claim
87 words
A semiconductor device comprising: a semiconductor layer including at least a first region and a second region forming a junction therebetween, said first region having an intrinsic conductivity and said second region having P or N type conductivity with a crystallinity, wherein at least said second region contains a catalyst at a concentration not higher than 1×10 20 atoms/cm 3 for promoting activation of said second region, and an inner edge of said second region is substantially aligned with at least one edge of a gate electrode.
Claim 12
Dependent Claim
30 words
The semiconductor device of claim 7 wherein said catalyst is a metal, wherein said metal is at least one selected from the group consisting of nickel, iron, cobalt and platinum.
Claim 13
Dependent Claim
104 words
A transistor comprising: a gate electrode; a gate insulating film adjacent to said gate electrode; a semiconductor layer adjacent to said gate insulating film; a pair of impurity regions formed in said semiconductor layer, a catalyst material for accelerating crystallization and impurity being contained in said pair of impurity regions; an active region incorporated between said pair of impurity regions, wherein said catalyst material is contained in said impurity regions at a concentration not higher than 1×10 20 atoms/cm 3 and an inner edge of at least one of said impurity regions is substantially aligned with at least one edge of said gate electrode.
Claim 14
Dependent Claim
104 words
A transistor comprising: a gate electrode; a gate insulating film adjacent to said gate electrode; a semiconductor layer adjacent to said gate insulating film; a pair of impurity regions formed in said semiconductor layer, a catalyst material for accelerating crystallization and impurity being contained in said pair of impurity regions; an active region incorporated between said pair of impurity regions, wherein said catalyst material is contained in said impurity regions at a concentration not higher than 1×10 20 atoms/cm 3 and an inner edge of at least one of said impurity regions is substantially aligned with at least one edge of said gate electrode.
Claim 15
Dependent Claim
30 words
The transistor of claim 9 wherein said catalyst material is a metal, wherein said metal is at least one selected from the group consisting of nickel, iron, cobalt, and platinum.
Claim 16
Dependent Claim
29 words
The transistor of claim 9 wherein the concentration of said catalyst material in said impurity regions is 10 times as large as that in said active region or higher.
Claim 17
Dependent Claim
15 words
The transistor of claim 9 wherein said active region is made substantially of amorphous silicon.
Claim 18
Dependent Claim
17 words
The transistor of claim 9 wherein said impurity regions are a source region and a drain region.
Claim 19
Dependent Claim
20 words
The transistor of claim 9 wherein each of said impurity regions comprise a crystalline semiconductor material having one conductivity type.
Claim 20
Dependent Claim
119 words
A transistor comprising: a gate electrode; a gate insulating film adjacent to said gate electrode; and a semiconductor layer adjacent to said gate insulating film; a pair of impurity regions formed in said semiconductor layer, a catalyst material for accelerating crystallization and impurity being contained in said pair of impurity regions, an active region incorporated between said pair of impurity regions, wherein said impurity regions contain said catalyst material which accelerates crystallization of said semiconductor layer at a concentration not lower than 1×10 17 cm -3 and not higher than 1×10 20 cm -3 , and an inner edge of at least one of said impurity regions is substantially aligned with at least one edge of said gate electrode.
Claim 21
Dependent Claim
119 words
A transistor comprising: a gate electrode; a gate insulating film adjacent to said gate electrode; and a semiconductor layer adjacent to said gate insulating film; a pair of impurity regions formed in said semiconductor layer, a catalyst material for accelerating crystallization and impurity being contained in said pair of impurity regions, an active region incorporated between said pair of impurity regions, wherein said impurity regions contain said catalyst material which accelerates crystallization of said semiconductor layer at a concentration not lower than 1×10 17 cm -3 and not higher than 1×10 20 cm -3 , and an inner edge of at least one of said impurity regions is substantially aligned with at least one edge of said gate electrode.
Claim 22
Dependent Claim
25 words
The transistor of claim 15 wherein the concentration of said catalyst material is defined by a minimum value as measured by secondary ion mass spectroscopy.
Claim 23
Dependent Claim
30 words
The transistor of claim 15 wherein said catalyst material is a metal, wherein said metal is at least one selected from the group consisting of nickel, iron, cobalt, and platinum.
Claim 24
Dependent Claim
17 words
The transistor of claim 15 wherein said impurity regions are a source region and a drain region.
Claim 25
Dependent Claim
20 words
The transistor of claim 15 wherein each of said impurity regions comprise a crystalline semiconductor material having one conductivity type.
Claim 26
Dependent Claim
102 words
A transistor comprising: a crystalline silicon film comprising a source region and a drain region each containing an impurity therein and an active region provided between said source region and said drain region, wherein said source region and said drain region contain a catalyst material for accelerating crystallization at a concentration higher than 1×10 17 cm -3 , and said active region contains the catalyst material at a concentration lower than 1×10 17 cm -3 , and an inner edge of at least one of said source and drain regions is substantially aligned with at least one edge of a gate electrode.
Claim 27
Dependent Claim
102 words
A transistor comprising: a crystalline silicon film comprising a source region and a drain region each containing an impurity therein and an active region provided between said source region and said drain region, wherein said source region and said drain region contain a catalyst material for accelerating crystallization at a concentration higher than 1×10 17 cm -3 , and said active region contains the catalyst material at a concentration lower than 1×10 17 cm -3 , and an inner edge of at least one of said source and drain regions is substantially aligned with at least one edge of a gate electrode.
Claim 28
Dependent Claim
30 words
The transistor of claim 20 wherein the catalyst material is a metal, wherein said metal is at least one selected from the group consisting of nickel, iron, cobalt, and platinum.
Claim 29
Dependent Claim
25 words
The transistor of claim 20 wherein the concentration of the catalyst material is defined by a minimum value as measured by secondary ion mass spectroscopy.
Claim 30
Dependent Claim
24 words
The transistor of claim 20 wherein each of said source region and said drain region comprise a crystalline semiconductor material having one conductivity type.
Claim 31
Dependent Claim
30 words
The transistor of claim 20 wherein said catalyst material is contained in said source region and said drain region at a concentration not higher than 1×10 20 atoms/cm 3 .
Claim 32
Dependent Claim
124 words
A transistor comprising: a crystalline silicon film provided on a substrate and comprising a source region and a drain region each containing an impurity therein; and a gate electrode provided on said crystalline silicon film, wherein said crystalline silicon film comprises a region having substantially the same length as that of said gate electrode and containing a catalyst material for accelerating crystallization at a lower concentration than said source region and said drain region, and wherein said catalyst material is contained in said source and drain regions at a concentration not higher than 1×10 20 atoms/cm 3 , and an inner edge of at least one of said source and drain regions is substantially aligned with at least one edge of said gate electrode.
Claim 33
Dependent Claim
124 words
A transistor comprising: a crystalline silicon film provided on a substrate and comprising a source region and a drain region each containing an impurity therein; and a gate electrode provided on said crystalline silicon film, wherein said crystalline silicon film comprises a region having substantially the same length as that of said gate electrode and containing a catalyst material for accelerating crystallization at a lower concentration than said source region and said drain region, and wherein said catalyst material is contained in said source and drain regions at a concentration not higher than 1×10 20 atoms/cm 3 , and an inner edge of at least one of said source and drain regions is substantially aligned with at least one edge of said gate electrode.
Claim 34
Dependent Claim
30 words
The transistor of claim 25 wherein said catalyst material is a metal, wherein said metal is at least one selected from the group consisting of nickel, iron, cobalt, and platinum.
Claim 35
Dependent Claim
24 words
The transistor of claim 25 wherein each of said source region and said drain region comprise a crystalline semiconductor material having one conductivity type.
Claim 36
Dependent Claim
123 words
A transistor comprising: a gate electrode provided on a substrate; a gate insulating film provided on said gate electrode; and a semiconductor layer provided on said gate insulating film; a pair of impurity regions formed in said semiconductor layer, a catalyst material for accelerating crystallization and impurity being contained in said pair of impurity regions, an active region incorporated between said pair of impurity regions, wherein said impurity regions contain said catalyst material which accelerates activation of said impurity regions at a concentration not lower than 1×10 17 cm -3 and not higher than 1×10 20 cm -3 , and an inner edge of at least one of said impurity regions is substantially aligned with at least one edge of said gate electrode.
Claim 37
Dependent Claim
123 words
A transistor comprising: a gate electrode provided on a substrate; a gate insulating film provided on said gate electrode; and a semiconductor layer provided on said gate insulating film; a pair of impurity regions formed in said semiconductor layer, a catalyst material for accelerating crystallization and impurity being contained in said pair of impurity regions, an active region incorporated between said pair of impurity regions, wherein said impurity regions contain said catalyst material which accelerates activation of said impurity regions at a concentration not lower than 1×10 17 cm -3 and not higher than 1×10 20 cm -3 , and an inner edge of at least one of said impurity regions is substantially aligned with at least one edge of said gate electrode.
Claim 38
Dependent Claim
25 words
The transistor of claim 28 wherein the concentration of said catalyst material is defined by a minimum value as measured by secondary ion mass spectroscopy.
Claim 39
Dependent Claim
30 words
The transistor of claim 28 wherein said catalyst material is a metal, wherein said metal is at least one selected from the group consisting of nickel, iron, cobalt, and platinum.
Claim 40
Dependent Claim
17 words
The transistor of claim 28 wherein said impurity regions are a source region and a drain region.
References Cited (Backward Citations)
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