US5622894A
Expired / Lapsed
US
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Process to minimize a seam in tungsten filled contact holes
Assignee: Taiwan Semiconductor Manufacturing Co TSMC Ltd
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Filing: 1996-03-15
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Granted: 1997-04-22
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Expires: 2016-03-15
Abstract
Abstract A process has been developed in which high aspect ratio contact holes, are filled with chemically vapor deposited tungsten plugs, exhibiting little or no seam at the center of the tungsten plug. The process features protection of the tungsten plug from the final removal and overetch steps, needed to remove residual tungsten from areas outside the contact hole. This is accomplished by delaying the residual removal procedure, until the tungsten plug is protected by an overlying interconnect metallization structure.
Inventors
- 👤 Syun-Ming Jang
- 👤 Yu C. Douglas
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 10:49
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/056
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
360 words
A method for fabricating a MOSFET device, on a semiconductor substrate, using a metal filled contact hole, to provide electrical contact between an underlying conductive region, in said semiconductor substrate, and an overlying interconnect metallization structure, comprising the steps of: providing said underlying conductive region, in said semiconductor substrate; depositing a dielectric layer on said semiconductor substrate, including depositing on said underlying conductive region; photolithographic processing to open a small diameter hole, in a photoresist layer, exposing underlying said dielectric layer, directly over an area of said underlying conductive region; anisotropic etching of said dielectric layer, in opening of said photoresist layer, to create a small diameter contact hole, to said underlying conductive region; removal of said photoresist layer; surface cleaning of said underlying conductive region, in said small diameter contact hole; deposition of an adhesive layer on top surface of said dielectric layer, on sides of said small diameter contact hole, and on said underlying conductive region, in said small diameter contact hole; deposition of a barrier layer on said adhesive layer; deposition of a metal fill layer, on said barrier layer, completely filling said small diameter contact hole; partial removal of said metal fill layer, from top surface of said barrier layer, forming a metal plug in said small diameter contact hole, while leaving metal fill residuals on top surface of said barrier layer; deposition of a interconnect metallization layer, on said metal fill residuals on surface of said barrier layer, and on said metal plug, in said small diameter contact hole; deposition of an anti-reflective layer, on said interconnect metallization layer; photolithographic processing to create a photoresist shape on said anti-reflective layer, directly overlying said metal plug, in said small diameter contact hole; anisotropic removal of said anti-reflective layer, of said interconnect metallization layer, of said metal fill residuals, of said barrier layer, and of said adhesive layer, in areas not covered by said photoresist shape, to create an interconnect metallization structure of said anti-reflective layer, said interconnect metallization layer, said metal fill residuals, said barrier layer, and said adhesive layer, overlying said metal plug, in said small diameter contact hole; and removal of said photoresist shape.
Claim 2
Independent Claim
360 words
A method for fabricating a MOSFET device, on a semiconductor substrate, using a metal filled contact hole, to provide electrical contact between an underlying conductive region, in said semiconductor substrate, and an overlying interconnect metallization structure, comprising the steps of: providing said underlying conductive region, in said semiconductor substrate; depositing a dielectric layer on said semiconductor substrate, including depositing on said underlying conductive region; photolithographic processing to open a small diameter hole, in a photoresist layer, exposing underlying said dielectric layer, directly over an area of said underlying conductive region; anisotropic etching of said dielectric layer, in opening of said photoresist layer, to create a small diameter contact hole, to said underlying conductive region; removal of said photoresist layer; surface cleaning of said underlying conductive region, in said small diameter contact hole; deposition of an adhesive layer on top surface of said dielectric layer, on sides of said small diameter contact hole, and on said underlying conductive region, in said small diameter contact hole; deposition of a barrier layer on said adhesive layer; deposition of a metal fill layer, on said barrier layer, completely filling said small diameter contact hole; partial removal of said metal fill layer, from top surface of said barrier layer, forming a metal plug in said small diameter contact hole, while leaving metal fill residuals on top surface of said barrier layer; deposition of a interconnect metallization layer, on said metal fill residuals on surface of said barrier layer, and on said metal plug, in said small diameter contact hole; deposition of an anti-reflective layer, on said interconnect metallization layer; photolithographic processing to create a photoresist shape on said anti-reflective layer, directly overlying said metal plug, in said small diameter contact hole; anisotropic removal of said anti-reflective layer, of said interconnect metallization layer, of said metal fill residuals, of said barrier layer, and of said adhesive layer, in areas not covered by said photoresist shape, to create an interconnect metallization structure of said anti-reflective layer, said interconnect metallization layer, said metal fill residuals, said barrier layer, and said adhesive layer, overlying said metal plug, in said small diameter contact hole; and removal of said photoresist shape.
Claim 3
Dependent Claim
28 words
The method of claim 1, wherein said underlying conductive region, in said semiconductor substrate, is an N type, heavily doped source and drain region of a MOSFET device.
Claim 4
Dependent Claim
38 words
The method of claim 1, wherein said dielectric layer is silicon oxide, deposited using either LPCVD, PECVD, or APCVD processing, at a temperature between about 400° to 800° C., to a thickness between about 5000 to 10000 Angstroms.
Claim 5
Dependent Claim
50 words
The method of claim 1, wherein said small diameter contact hole is created using anisotropic, RIE processing, using CHF 3 as an etchant, with said small diameter contact hole having an opening with a diameter between about 0.3 to 0.5 uM, resulting in aspect ratios between about 1 to 3.
Claim 6
Dependent Claim
24 words
The method of claim 1, wherein said adhesive layer is titanium, deposited using r.f. sputtering, to a thickness between about 200 to 500 Angstroms.
Claim 7
Dependent Claim
25 words
The method of claim 1, wherein said barrier layer is titanium nitride, deposited using r.f. sputtering, to a thickness between about 500 to 1000 Angstroms.
Claim 8
Dependent Claim
39 words
The method of claim 1, wherein said metal fill layer is tungsten, deposited using LPCVD processing, at a temperature between about 440° to 480° C., to a thickness between about 5000 to 10000 Angstroms, using tungsten hexafluoride and silane.
Claim 9
Dependent Claim
50 words
The method of claim 1, wherein partial removal of said metal fill layer, from top surface of said barrier layer, is accomplished via RIE, using SF 6 as an etchant, leaving between about 400 to 600 Angstroms of said metal fill residuals remaining on top surface of said barrier layer.
Claim 10
Dependent Claim
39 words
The method of claim 1, wherein said interconnect metallization layer is aluminum, containing between about 0.8 to 1.2% copper, and between about 0.4 to 0.6% silicon, deposited using r.f. sputtering, to a thickness between about 4000 to 6000 Angstroms.
Claim 11
Dependent Claim
25 words
The method of claim 1, wherein said anti-reflective layer is titanium nitride, deposited using r.f. sputtering, to a thickness between about 1000 to 1400 Angstroms.
Claim 12
Dependent Claim
29 words
The method of claim 1, wherein said anti-reflective layer, and said interconnect metallization layer, are removed via anisotropic, RIE procedures, using Cl 2 and BCl 3 as an etchant.
Claim 13
Dependent Claim
42 words
The method of claim 1, wherein said metal fill residuals, are removed using anisotropic, RIE procedures, using SF 6 as an etchant, while said barrier and adhesive layers are removed using anisotropic RIE procedures, using Cl 2 and BCl 3 as etchants.
Claim 14
Independent Claim
386 words
A method for fabricating a MOSFET device, on a semiconductor substrate, using a tungsten filled contact hole, to provide electrical contact between an underlying conductive region in said semiconductor substrate, and an overlying interconnect metallization structure, comprising the steps of: providing said underlying conductive region, in said semiconductor substrate; depositing a dielectric layer on said semiconductor substrate, including deposition on said underlying conductive region; photolithographic processing to open a small diameter hole in a photoresist layer, exposing underlying said dielectric layer, directly over an area of said underlying conductive region; anisotropic etching of said dielectric layer, in opening of said photoresist layer, to create a small diameter contact hole, to said underlying conductive region; removal of said photoresist layer; surface cleaning of said underlying conductive region, in said small diameter contact hole; deposition of a titanium layer on the top surface of said dielectric layer, on the sides of said small diameter contact hole, and on said underlying conductive region, in said small diameter contact hole; deposition of a first titanium nitride layer on said titanium layer; deposition of a tungsten layer, on said first titanium nitride layer, completely filling said small diameter contact hole; partial removal of said tungsten layer, from top surface of said first titanium nitride layer, forming a tungsten plug in said small diameter contact hole, while leaving tungsten residuals on top surface of said first titanium nitride layer; deposition of an aluminum based metallization layer, on said tungsten residuals on surface of said first titanium nitride layer, and on said tungsten plug, in said small diameter contact hole; deposition of a second titanium nitride layer on said aluminum based metallization layer; photolithographic processing to create a photoresist shape, on said second titanium nitride layer, directly overlying said tungsten plug, in said small diameter contact hole; anisotropic removal of said second titanium nitride layer, of said aluminum based metallization layer, of said tungsten residuals, of said first titanium nitride layer, and of said titanium layer, in areas not covered by said photoresist shape, to create an interconnect metallization structure of said second titanium nitride layer, of said aluminum based metallization layer, of said tungsten residuals, of said first titanium nitride layer, and of said titanium layer, overlying said tungsten plug, in said small diameter contact hole; and removal of said photoresist shape.
Claim 15
Independent Claim
386 words
A method for fabricating a MOSFET device, on a semiconductor substrate, using a tungsten filled contact hole, to provide electrical contact between an underlying conductive region in said semiconductor substrate, and an overlying interconnect metallization structure, comprising the steps of: providing said underlying conductive region, in said semiconductor substrate; depositing a dielectric layer on said semiconductor substrate, including deposition on said underlying conductive region; photolithographic processing to open a small diameter hole in a photoresist layer, exposing underlying said dielectric layer, directly over an area of said underlying conductive region; anisotropic etching of said dielectric layer, in opening of said photoresist layer, to create a small diameter contact hole, to said underlying conductive region; removal of said photoresist layer; surface cleaning of said underlying conductive region, in said small diameter contact hole; deposition of a titanium layer on the top surface of said dielectric layer, on the sides of said small diameter contact hole, and on said underlying conductive region, in said small diameter contact hole; deposition of a first titanium nitride layer on said titanium layer; deposition of a tungsten layer, on said first titanium nitride layer, completely filling said small diameter contact hole; partial removal of said tungsten layer, from top surface of said first titanium nitride layer, forming a tungsten plug in said small diameter contact hole, while leaving tungsten residuals on top surface of said first titanium nitride layer; deposition of an aluminum based metallization layer, on said tungsten residuals on surface of said first titanium nitride layer, and on said tungsten plug, in said small diameter contact hole; deposition of a second titanium nitride layer on said aluminum based metallization layer; photolithographic processing to create a photoresist shape, on said second titanium nitride layer, directly overlying said tungsten plug, in said small diameter contact hole; anisotropic removal of said second titanium nitride layer, of said aluminum based metallization layer, of said tungsten residuals, of said first titanium nitride layer, and of said titanium layer, in areas not covered by said photoresist shape, to create an interconnect metallization structure of said second titanium nitride layer, of said aluminum based metallization layer, of said tungsten residuals, of said first titanium nitride layer, and of said titanium layer, overlying said tungsten plug, in said small diameter contact hole; and removal of said photoresist shape.
Claim 16
Dependent Claim
28 words
The method of claim 13, wherein said underlying conductive region, in said semiconductor substrate, ia an N type, heavily doped source and drain region of a MOSFET device.
Claim 17
Dependent Claim
38 words
The method of claim 13, wherein said dielectric layer is silicon oxide, deposited using either LPCVD, PECVD, or APCVD processing, at a temperature between about 400° to 800° C., to a thickness between about 5000 to 10000 Angstroms.
Claim 18
Dependent Claim
50 words
The method of claim 13, wherein said small diameter contact hole is created using anisotropic, RIE processing, using CHF 3 as an etchant, with said small diameter contact hole having an opening with a diameter between about 0.3 to 0.5 uM, resulting in aspect ratios between about 1 to 3.
Claim 19
Dependent Claim
23 words
The method of claim 13, wherein said titanium layer is deposited using r.f. sputtering, to a thickness between about 200 to 500 Angstroms.
Claim 20
Dependent Claim
25 words
The method of claim 13, wherein said first titanium nitride layer is deposited using r.f. sputtering, to a thickness between about 500 to 1000 Angstroms.
Claim 21
Dependent Claim
37 words
The method of claim 13, wherein said tungsten layer is deposited using LPCVD processing, at a temperature between about 440° to 480° C., to a thickness between about 5000 to 8000 Angstroms, using tungsten hexafluoride and silane.
Claim 22
Dependent Claim
52 words
The method of claim 13, wherein partial removal of said tungsten layer, from top surface of said first titanium nitride layer, is accomplished via RIE processing, using SF 6 as an etchant, leaving between about 400 to 600 Angstroms of said tungsten residuals remaining on surface of said first titanium nitride layer.
Claim 23
Dependent Claim
40 words
The method of claim 13, wherein said aluminum based metallization layer is aluminum, containing between about 0.8 to 1.2% copper, and between about 0.4 to 0.6% silicon, deposited using r.f. sputtering, to a thickness between about 4000 to 6000 Angstroms.
Claim 24
Dependent Claim
25 words
The method of claim 13, wherein said second titanium nitride layer is deposited using r.f. sputtering, to a thickness between about 1000 to 1400 Angstroms.
Claim 25
Dependent Claim
31 words
The method of claim 13, wherein said second titanium nitride layer, and said aluminum based metallization layer, are removed via anisotropic, RIE procedures, using Cl 2 and BCl 3 as etchants.
Claim 26
Dependent Claim
45 words
The method of claim 13, wherein said tungsten residuals, are removed via anisotropic, RIE procedures, using SF 6 as an etchant, while said first titanium nitride layer and said titanium layer are removed via anisotropic RIE procedures, using Cl 2 and BCl 3 as etchants.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 2000-04-21 | 2000-10-21 | 2001-04-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2004-04-21 | 2004-10-21 | 2005-04-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2008-04-21 | 2008-10-21 | 2009-04-22 | $7700.00 | Window Closed / Lapsed |