Patent US5609022A successfully refreshed from Google Patents.
US5609022A
Expired / Lapsed
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Method of reducing NOx emissions from lean-burn combustion engines
Assignee: GM Global Technology Operations LLC
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Filing: 1994-10-31
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Granted: 1997-03-11
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Expires: 2014-10-31
Abstract
Abstract The invention includes an operating strategy for zeolite-based catalysts used for reduction of NOx from highly lean exhaust conditions. The invention includes a method to enhance the high temperature activity of zeolite-based catalysts by modifying the transient feed composition without changing the overall time-average feed composition. More specifically, a cyclic operation method with alternating feed conditions between rich and lean to enhance the activity of zeolite-based catalysts to remove NO from lean exhaust gases when the overall exhaust composition contains a large amount of excess oxygen, without affecting the catalyst's activity to remove hydrocarbons. The rich to lean transient conditions are created by periodically adding hydrocarbon pulses from a different source to the combustion emissions.
Inventors
- 👤 Byong K. Cho
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 19:45
CPC Classifications
F; F01; F01N; F01N3/00; F01N3/08; F01N3/0807; F01N3/0871; B; B01; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9404; B01D53/9409; B01D53/9445; B01D53/945; F01N3/0814; F01N3/0828; F01N3/0835; F01N3/10; F01N3/18; F01N3/20; F01N3/206; F01N3/2066; F01N2370/00; F01N2370/02; F01N2370/04; F01N2610/00; F01N2610/03; F02; F02B; F02B1/00; F02B1/02; F02B1/04; Y; Y02; Y02T; Y02T10/00; Y02T10/10; Y02T10/12
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
136 words
A method comprising: operating a combustion engine in a lean half cycle having an air/fuel ratio greater than 17, collecting the exhaust including NO x from the combustion engine in an exhaust system and steadily feeding a stream of exhaust to a reactor including a zeolite-based material having a catalyst thereon; operating the catalyst in a rich half cycle by periodically adding hydrocarbon pulses from a source other than the combustion engine to the steady stream of exhaust in the exhaust system prior to the exhaust flowing over the catalyst, and wherein said catalyst has an operating temperature ranging from light-off temperature to about 500° C., so that hydrocarbons are stored in the catalyst during the rich half cycle and thereafter released during the lean half cycle to improve reduction of NO x in the exhaust.
Claim 2
Independent Claim
136 words
A method comprising: operating a combustion engine in a lean half cycle having an air/fuel ratio greater than 17, collecting the exhaust including NO x from the combustion engine in an exhaust system and steadily feeding a stream of exhaust to a reactor including a zeolite-based material having a catalyst thereon; operating the catalyst in a rich half cycle by periodically adding hydrocarbon pulses from a source other than the combustion engine to the steady stream of exhaust in the exhaust system prior to the exhaust flowing over the catalyst, and wherein said catalyst has an operating temperature ranging from light-off temperature to about 500° C., so that hydrocarbons are stored in the catalyst during the rich half cycle and thereafter released during the lean half cycle to improve reduction of NO x in the exhaust.
Claim 3
Dependent Claim
13 words
A method as set forth in claim 1 wherein said catalyst comprises copper.
Claim 4
Dependent Claim
13 words
A method as set forth in claim 1 wherein said catalyst comprises platinum.
Claim 5
Dependent Claim
15 words
A method as set forth in claim 1 wherein said catalyst comprises a noble metal.
Claim 6
Dependent Claim
19 words
A method as set forth in claim 1 wherein said catalyst is deposited on said zeolite-based material by ion-exchange.
Claim 7
Dependent Claim
34 words
A method as set forth in claim 1 further comprising operating the combustion engine is a gasoline engine at an air/fuel ratio of greater than 17 to about 23 during the lean half cycle.
Claim 8
Dependent Claim
35 words
A method as set forth in claim 1 wherein said combustion engine is a diesel engine and further comprising operating the engine at the air/fuel ratio of 35 to 45 during the lean half cycle.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2000-03-10 | 2000-09-09 | 2001-03-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2004-03-10 | 2004-09-09 | 2005-03-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2008-03-10 | 2008-09-09 | 2009-03-11 | $7700.00 | Window Closed / Lapsed |