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US5594076A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrodegradable polyesters

Assignee: Penn State Research Foundation
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Filing: 1995-06-07
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Granted: 1997-01-14
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Expires: 2015-06-07
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Abstract

Abstract Hydrodegradable polyesters based upon the random copolymerization of aromatic and absorbable aliphatic polyesters are disclosed. The hydrodegradable polyesters are useful in preparing a variety of products including disposable containers, disposable diapers, fishing lines and nets, and the like.

Inventors

  • 👤 Bernard Gordon, III
  • 👤 Prabodh P. Sharma

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:54
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/16; C08G63/18; C08G63/181; C08G63/183; Y; Y10; Y10S; Y10S525/00; Y10S525/938

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 192 words
A hydrodegradable polyester copolymer consisting essentially of a substantially non-degradable aromatic polyester subunit and a hydrodegradable oxalate subunit and having the formula ##STR5## wherein R is selected from the group consisting of a straight or branched alkylene of 2 to 16 carbons in length, a polyether of the formula --[(CH 2 ) n --O] x --(CH 2 ) n --, or a mixture thereof, wherein n is a number from 2 to 16 and X is a number from 1 to 1000; R 2 is selected from the group consisting of a straight or branched alkylene of 2 to 16 carbons in length, a polyether of the formula --[(CH 2 ) n --O] x --(CH 2 ) n --, or a mixture thereof, wherein n is a number from 2 to 16 and X is a number from 1 to 1000, said hydrolyzable oxalate subunit being randomly distributed in, and comprising 5-30 weight percent of said copolymer, the balance of said copolymer being said aromatic polyester subunit, and said copolymer exhibiting a significant decrease in intrinsic viscosity when hydrolyzed in water at a temperature of about 50° C. for about 3-4 days.
Claim 2
Dependent Claim 192 words
A hydrodegradable polyester copolymer consisting essentially of a substantially non-degradable aromatic polyester subunit and a hydrodegradable oxalate subunit and having the formula ##STR5## wherein R is selected from the group consisting of a straight or branched alkylene of 2 to 16 carbons in length, a polyether of the formula --[(CH 2 ) n --O] x --(CH 2 ) n --, or a mixture thereof, wherein n is a number from 2 to 16 and X is a number from 1 to 1000; R 2 is selected from the group consisting of a straight or branched alkylene of 2 to 16 carbons in length, a polyether of the formula --[(CH 2 ) n --O] x --(CH 2 ) n --, or a mixture thereof, wherein n is a number from 2 to 16 and X is a number from 1 to 1000, said hydrolyzable oxalate subunit being randomly distributed in, and comprising 5-30 weight percent of said copolymer, the balance of said copolymer being said aromatic polyester subunit, and said copolymer exhibiting a significant decrease in intrinsic viscosity when hydrolyzed in water at a temperature of about 50° C. for about 3-4 days.
Claim 3
Dependent Claim 16 words
As an article of manufacture, the copolyester of claim 1 in the form of fishing line.

References Cited (Backward Citations)

US3413379A Cited
US4032993A Cited
US4139525A Cited
US4311824A Cited
US4419507A Cited
US4532928A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2000-01-14 2000-07-15 2001-01-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-01-14 2004-07-15 2005-01-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2008-01-14 2008-07-15 2009-01-14 $7700.00 Window Closed / Lapsed

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