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US5549847A Expired / Lapsed US ⏱️ 0.0 years remaining

Flowable aqueous dispersions of polycarboxylic acid corrosion inhibitors

Assignee: CIBY-GEIGY Corp
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Filing: 1994-11-23
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Granted: 1996-08-27
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Expires: 2014-11-23
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Abstract

Abstract Highly concentrated flowable dispersions of corrosion inhibitors can be prepared by stirring a filter cake of the corrosion inhibitor with a dispersant and a thickener. These dispersions are storage stable.

Inventors

  • 👤 Martine Goliro
  • 👤 Martin Holer
  • 👤 Sandor Gati

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 22:42
CPC Classifications
C; C23; C23F; C23F11/00; C23F11/08; C23F11/10

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 297 words
A storage-stable, flowable aqueous dispersion of a solid polycarboxylic acid corrosion inhibitor comprising 25-57% by weight of a solid polycarboxylic acid corrosion inhibitor of formula I or II ##STR2## wherein Z is C 1 -C 11 alkylene, cyclohexylene or phenylene, R 1 and R 2 are each independently of the other H, C 1 -C 4 alkyl or a group --Z--COOH, R 3 is C 1 -C 12 alkyl, phenyl or a group --N(R 4 )(R 5 ), --OR 6 or --SR 6 , R 4 and R 5 are each independently of the other H, C 1 -C 12 alkyl, C 2 -C 4 hydroxyalkyl, cyclohexyl, phenyl or a group --Z--COOH, or R 4 and R 5 , when taken together, are C 4 -C 6 alkylene or 3-oxapentylene, R 6 is hydrogen, C 1 -C 12 alkyl or phenyl, m is 0 or 1, X is sulfur, oxygen or NH, R 7 is hydrogen, C 1 -C 4 alkyl, halogen, C 1 -C 4 alkoxy, carboxy, amino or nitro, R 8 , R 9 , R 10 and R 11 are each independently of one another hydrogen, C 1 -C 12 alkyl, C 1 -C 4 hydroxyalkyl, C 2 -C 6 carboxyalkyl, C 2 -C 10 alkoxyalkyl, carboxyl, phenyl or benzyl, or R 8 and R 9 , when taken together, are a direct bond, with the proviso that at least two of the groups R 8 , R 9 , R 10 and R 11 are a carboxyl or carboxylalkyl group, or an alkali metal salt, ammonium salt or amine salt, of such solid polycarboxylic acid corrosion inhibitor of formula I or II, 4- 72% by weight of water, 0.1-2% by weight of a dispersant and 0.01 to 0.5% by weight of a thickener.
Claim 2
Dependent Claim 297 words
A storage-stable, flowable aqueous dispersion of a solid polycarboxylic acid corrosion inhibitor comprising 25-57% by weight of a solid polycarboxylic acid corrosion inhibitor of formula I or II ##STR2## wherein Z is C 1 -C 11 alkylene, cyclohexylene or phenylene, R 1 and R 2 are each independently of the other H, C 1 -C 4 alkyl or a group --Z--COOH, R 3 is C 1 -C 12 alkyl, phenyl or a group --N(R 4 )(R 5 ), --OR 6 or --SR 6 , R 4 and R 5 are each independently of the other H, C 1 -C 12 alkyl, C 2 -C 4 hydroxyalkyl, cyclohexyl, phenyl or a group --Z--COOH, or R 4 and R 5 , when taken together, are C 4 -C 6 alkylene or 3-oxapentylene, R 6 is hydrogen, C 1 -C 12 alkyl or phenyl, m is 0 or 1, X is sulfur, oxygen or NH, R 7 is hydrogen, C 1 -C 4 alkyl, halogen, C 1 -C 4 alkoxy, carboxy, amino or nitro, R 8 , R 9 , R 10 and R 11 are each independently of one another hydrogen, C 1 -C 12 alkyl, C 1 -C 4 hydroxyalkyl, C 2 -C 6 carboxyalkyl, C 2 -C 10 alkoxyalkyl, carboxyl, phenyl or benzyl, or R 8 and R 9 , when taken together, are a direct bond, with the proviso that at least two of the groups R 8 , R 9 , R 10 and R 11 are a carboxyl or carboxylalkyl group, or an alkali metal salt, ammonium salt or amine salt, of such solid polycarboxylic acid corrosion inhibitor of formula I or II, 4- 72% by weight of water, 0.1-2% by weight of a dispersant and 0.01 to 0.5% by weight of a thickener.
Claim 3
Dependent Claim 111 words
A dispersion according to claim 1, wherein Z is C 1 -C 8 alkylene, R 1 and R 2 are hydrogen or C 1 -C 4 alkyl, R 3 is a group --N(R 4 )(R 5 ), R 4 is hydrogen, cyclohexyl or C 1 -C 12 alkyl, R 5 is C 1 -C 12 alkyl, phenyl or a group --Z--COOH, or R 4 and R 5 , when taken together, are 1,5-pentylene or 3-oxa-1,5-pentylene, m is 0 or 1, X is sulfur, R 7 is hydrogen, methyl or chloro, R 8 and R 10 are hydrogen, and R 9 and R 11 are carboxyl or C 2 -C 4 carboxyalkyl.
Claim 4
Dependent Claim 55 words
A dispersion according to claim 1, wherein Z is pentamethylene, R 1 and R 2 are hydrogen, R 3 is a group --NH--(CH 2 ) 5 --COOH, X is sulfur, R 7 is hydrogen, m is 0 or 1, R 8 and R 10 are hydrogen, R 9 is carboxyl and R 11 is carboxymethyl.
Claim 5
Dependent Claim 17 words
A dispersion according to claim 1, wherein the polycarboxylic acid corrosion inhibitor is 2,4,6-tris(5-carboxypentylamino)-1,3,5-triazine or benzothiazol-2-yl-thiosuccinic acid.
Claim 6
Dependent Claim 30 words
A dispersion according to claim 1 comprising 40-53% of a formula I or II, 45-58% of water, 0.1 to 2% of a dispersant and 0.01 to 0.5% of a thickener.
Claim 7
Dependent Claim 15 words
A dispersion according to claim 1, wherein the dispersant is an anionic or nonionic surfactant.
Claim 8
Dependent Claim 13 words
A dispersion according to claim 6, wherein the thickener is a modified polysaccharide.
Claim 9
Dependent Claim 17 words
A dispersion according to claim 1, which additionally comprises 0.05 to 0.5% by weight of a biocide.
Claim 10
Dependent Claim 12 words
A dispersion according to claim 8, wherein the biocide is a fungicide.
Claim 11
Dependent Claim 26 words
A dispersion according to claim 1, which comprises as additional corrosion inhibitor 10-50% by weight, based on the total weight of corrosion inhibitors, of anthranilic acid.
Claim 12
Dependent Claim 26 words
A dispersion according to claim 1, which comprises as additional corrosion inhibitor 20-40% by weight, based on the total weight of corrosion inhibitors, of anthranilic acid.
Claim 13
Dependent Claim 71 words
A process for the preparation of a flowable aqueous dispersion of a polycarboxylic acid corrosion inhibitor of the formula I or II according to claim 1, comprising 25-57% of the corrosion inhibitor, 40-72% of water, 0.1-2% of a dispersant and 0.01 to 0.5% of a thickener, which process comprises mixing a moist corrosion inhibitor, obtained by filtration, with the dispersant and the thickener and stirring the mixture until it is flowable.
Claim 14
Dependent Claim 15 words
A process according to claim 12, wherein the stirring is carried out at room temperature.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-08-27 2000-02-26 2000-08-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-08-27 2004-02-26 2004-08-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-08-27 2008-02-26 2008-08-27 $7700.00 Window Closed / Lapsed

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