PTMEG polyurethane elastomers employing monofunctional polyethers

Claim 2

A polyurethane elastomer, comprising the reaction product of: a) an isocyanate-terminated prepolymer having an NCO group content of from about 2 weight percent to about 20 weight percent, which is the reaction product of a di- or polyisocyanate having a functionality of about 2 to about 2.2; a polytetramethylene ether glycol having a molecular weight between about 600 Da and 6000 Da; and from 1 weight percent to about 10 weight percent, based on the weight of said polyoxytetramethylene ether glycol, of a hydroxyl-functional polyoxyalkylene monol containing in major part oxyalkylene moieties derived from propylene oxide, butylene oxide, and tetrahydrofuran or mixtures thereof, said polyoxyalkylene monol having a molecular weight of from about 500 Da to about 10,000 Da; and b) a glycol chain extender at an isocyanate index of from about 70 to about 130.

Claim 3

The polyurethane elastomer of claim 1 wherein said NCO group content of said prepolymer is from about 4 weight percent to about 16 weight percent.

Claim 4

The polyurethane elastomer of claim 1 wherein said NCO group content of said prepolymer is from about 4 weight percent to about 10 weight percent.

Claim 5

The polyurethane elastomer of claim 1 wherein the weight percentage of said polyoxyalkylene monol is from about 1 weight percent to about 6 weight percent.

Claim 6

The polyurethane elastomer of claim 2 wherein the weight percentage of said polyoxyalkylene monol is from about 1 weight percent to about 6 weight percent.

Claim 7

The polyurethane elastomer of claim 3 wherein the weight percentage of said polyoxyalkylene monol is from about 1 weight percent to about 6 weight percent.

Claim 8

The polyurethane elastomer of claim 1 wherein the oxyalkylene moieties of said polyoxyalkylene monol comprise minimally 90 weight percent oxypropylene moieties.

Claim 9

The polyurethane elastomer of claim 1 wherein said polyoxyalkylene monol is a C 1-20 alkanol initiated polyoxypropylene homopolymer.

Claim 10

The polyurethane elastomer of claim 8 wherein the molecular weight of said polyoxyalkylene monol is from about 1000 Da to about 4000 Da.

Claim 11

The polyurethane elastomer of claim 1 wherein said di- or polyisocyanate is a diisocyanate selected from the group consisting of 2,4- and 2,6-tolune diisocyanate; 2,4'-, 2,2'-, and 4,4'-diphenyl-methane diisocyanate; 2,4'-, 2,2'-, and 4,4'-dicyclohexylmethane diisocyanate; tetramethylxylidene diisocyanate cyanate; 1,6-hexane diisocyanate; isophorone diisocyanate, and mixtures thereof.

Claim 12

The polyurethane elastomer of claim 1 wherein said glycol chain extender is selected from the group consisting of ethylene glycol, 1,2- and 1,3-propanediol, 1,2- and 1,4-butanediol, 1,6-hexanediol, neopentyl glycol, 1,4-cyclohexanediol, 1,4-cyclohexane dimethanol, 2,2,4-trimethylpentane diol, hydroquinone, 0,0'-bis(2-hydroxyethyl)hydroquinone, 4,4'-dihydroxybiphenyl, bisphenol A, bisphenol F, and mixtures thereof.

Claim 13

The polyurethane elastomer of claim 1 wherein said glycol chain extender is selected from the group consisting of ethylene glycol, 1,4-butanediol, diethylene glycol, 1,6-hexanediol, and mixtures thereof.

Claim 14

A polyurethane elastomer having enhanced physical properties, comprising the reaction product of: a) an isocyanate prepolymer having an group content of from about 4 weight percent to about 10 weight percent, which is the reaction product of a di- or poly-isocyanate having a functionality of about 2 to about 2.2; a polytetramethylene ether glycol having a molecular weight between about 1000 Da and about 4000 Da; and from 1 weight percent to about 6 weight percent based on the weight of said polyoxytetramethylene ether glycol of a hydroxyl-functional polyoxyalkylene monol containing in major part oxyalkylene moleties derived from propylene oxide, butylene oxide, and tetrahydrofuran, said polyoxyalkylene monol having a molecular weight of from about 500 Da to about 4000 Da; and b) a glycol chain extender at an isocyanate index of from about 90 to about 110.

Claim 15

A polyurethane elastomer having enhanced physical properties, comprising the reaction product of: a) an isocyanate prepolymer having an group content of from about 4 weight percent to about 10 weight percent, which is the reaction product of a di- or poly-isocyanate having a functionality of about 2 to about 2.2; a polytetramethylene ether glycol having a molecular weight between about 1000 Da and about 4000 Da; and from 1 weight percent to about 6 weight percent based on the weight of said polyoxytetramethylene ether glycol of a hydroxyl-functional polyoxyalkylene monol containing in major part oxyalkylene moleties derived from propylene oxide, butylene oxide, and tetrahydrofuran, said polyoxyalkylene monol having a molecular weight of from about 500 Da to about 4000 Da; and b) a glycol chain extender at an isocyanate index of from about 90 to about 110.

Claim 16

The polyurethane elastomer of claim 13 wherein said glycol chain extender comprises 1,4-butanediol.

Claim 17

A process for enhancing the physical properties of a polytetramethylene ether glycol based polyurethane elastomer prepared by the reaction of an isocyanate terminated prepolymer prepared from polytetramethylene ether glycol with a di- or polyisocyanate followed by reaction with a glycol chain extender, comprising: preparing said prepolymer in the presence of from about 1 weight percent to about 10 weight percent, based on the weight of said polyoxytetramethylene ether glycol, of a hydroxyl-functional polyoxyalkylene monol having a molecular weight of from 500 Da to about 10,000 Da, said polyoxyalkylene monol comprising in excess of 50 weight percent of oxypropylene or oxybutylene moieties, or mixtures thereof.

Claim 18

A process for enhancing the physical properties of a polytetramethylene ether glycol based polyurethane elastomer prepared by the reaction of an isocyanate terminated prepolymer prepared from polytetramethylene ether glycol with a di- or polyisocyanate followed by reaction with a glycol chain extender, comprising: preparing said prepolymer in the presence of from about 1 weight percent to about 10 weight percent, based on the weight of said polyoxytetramethylene ether glycol, of a hydroxyl-functional polyoxyalkylene monol having a molecular weight of from 500 Da to about 10,000 Da, said polyoxyalkylene monol comprising in excess of 50 weight percent of oxypropylene or oxybutylene moieties, or mixtures thereof.

Claim 19

The process of claim 15 wherein said prepolymer contains from about 4 weight percent to about 10 weight percent NCO groups, and said polyoxytetramethylene ether glycol has a molecular weight of from 1000 Da to about 6000 Da.

Claim 20

The process of claim 16 wherein said polyoxyalkylene monol is a C 1-20 alkanol initiated polyoxypropylene monol having a molecular weight from about 500 Da to about 4000 Da.

Claim 21

The process of claim 15 wherein said glycol chain extender is selected from the group consisting of ethylene glycol, 1,4-butanediol, diethylene glycol, 1,6-hexane diol, and mixtures thereof.

Claim 22

The process of claim 15 wherein said polyoxyalkylene monol is present in an amount of from about 1 to about 6 weight percent.

Claim 23

The process of claim 15 wherein said polyoxyalkylene monol is present in an amount of from about 1 to about 4 weight percent.