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High performance passivation for semiconductor devices

Assignee: Teledyne Digital Imaging Inc
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Filing: 1992-08-10
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Granted: 1996-07-30
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Expires: 2012-08-10
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Abstract

Abstract A method of passivating a semiconductor device, comprises depositing a first dielectric passivation layer on the surface of the device, forming at least one planarization layer over the first passivation layer from an inorganic spin-on glass solution containing phosphorus and silicon organometallic molecules that are pre-reacted to form at least one Si.O.P bond between the phosphorus and silicon organometallic molecules, and subsequently depositing a second dielectric passivation layer on said at least one planarization layer(s). This results in improved step coverage of the underlying topography and permits much better protection against moisture related degradation than standard vapor phase deposited passivation layers even when the thickness of such layers is increased.

Inventors

  • 👤 Luc Quellet

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:41
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/69; H10P14/692; H10P14/6921; H10P14/6928; H10P14/63; H10P14/6326; H10P14/6342; H10W; H10W20/00; H10W20/40; H10W20/45; H10W20/48; H10W74/00; H10W74/10; H10W74/131; H10W74/137; H10W74/40; H10W74/47; H10W74/476; H10P14/6328; H10P14/6334; H10P14/6922; H10P14/6923; H10P14/6927; H10P14/694; H10P14/6943; H10P14/69433

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 156 words
A method of passivating a semiconductor device, comprising the steps of depositing a first dielectric passivation layer onto the surface of the device, spinning at least one planarization layer onto said first passivation layer from an inorganic spin-on glass solution containing organometallic molecules of X and silicon, where X is selected from the group consisting of phosphorus, arsenic and antimony, said spin-on glass solution being pre-reacted prior to spinning to form complex organometallic molecules of about 1000 to 5000 u.m.a. of molecular weight with at least one Si.O.X bond between said organometallic molecules of silicon and X, passing the device through successive hot plates in a dry inert gas ambient to remove residual moisture and volatile components, and subsequently depositing a second dielectric passivation layer on said at least one planarization layer, said device being maintained in said dry inert gas ambient after application of the spin-on glass layer until said second dielectric layer is deposited.
Claim 2
Independent Claim 156 words
A method of passivating a semiconductor device, comprising the steps of depositing a first dielectric passivation layer onto the surface of the device, spinning at least one planarization layer onto said first passivation layer from an inorganic spin-on glass solution containing organometallic molecules of X and silicon, where X is selected from the group consisting of phosphorus, arsenic and antimony, said spin-on glass solution being pre-reacted prior to spinning to form complex organometallic molecules of about 1000 to 5000 u.m.a. of molecular weight with at least one Si.O.X bond between said organometallic molecules of silicon and X, passing the device through successive hot plates in a dry inert gas ambient to remove residual moisture and volatile components, and subsequently depositing a second dielectric passivation layer on said at least one planarization layer, said device being maintained in said dry inert gas ambient after application of the spin-on glass layer until said second dielectric layer is deposited.
Claim 3
Dependent Claim 28 words
A method as claimed in claim 1, characterized in that the thickness of the first dielectric passivation layer lies in the range of about 0.2 to 1.0 μm.
Claim 4
Dependent Claim 22 words
A method as claimed in claim 1, characterized in that the thickness of the first dielectric passivation layer is about 0.5 μm.
Claim 5
Dependent Claim 39 words
A method as claimed in any one of claim 1, characterized in that the first layer is selected from the group consisting of: doped silicon nitride, undoped silicon nitride, doped silicon oxinitride, undoped silicon oxinitride, and a combination thereof.
Claim 6
Dependent Claim 42 words
A method as claimed in any one of claim 1, characterized in that the first layer is undoped stoichiometric silicon oxinitride having a compressive stress lower than 2.0E9 dynes/cm 2 and a concentration of Si-H bonds less than 4.0 E21/cm 3 .
Claim 7
Dependent Claim 45 words
A method as claimed in claim 1, characterized in that the spin on glass layer is made from phosphorus-doped spin-on glass solution that permits the formation of a layer having about 1.0 to 5.0 wt % phosphorus after a final cure at about 425° C.
Claim 8
Dependent Claim 26 words
A method as claimed claim 6, characterized in that the thickness of the spin-on glass layer lies in the range of about 35 to 150 nm.
Claim 9
Dependent Claim 20 words
A method as claimed in claim 6, characterized in that the thickness of the spin-on glass layer is 75 nm.
Claim 10
Dependent Claim 16 words
A method as claimed in claim 1, characterized in that the dry inert gas is nitrogen.
Claim 11
Dependent Claim 39 words
A method as claimed in claim 1, characterized in that the temperature of the hot plates at the successive stations increases from a first temperature lower than about 120° C. to a last temperature higher than about 300° C.
Claim 12
Dependent Claim 25 words
A method as claimed in claim 10, characterized in that the first temperature is about 80° C. and the last temperature is about 350° C.
Claim 13
Dependent Claim 36 words
A method as claimed in claim 1, characterized in that the second dielectric layer is selected from the group consisting of: doped silicon nitride, undoped silicon nitride, silicon oxinitride, undoped silicon oxinitride, and a combination thereof.
Claim 14
Dependent Claim 39 words
A method as claimed in claim 1, characterized in that the second layer is silicon nitride having a compressive stress less than about 2.0E9 dynes/cm 2 and a concentration of Si-H bonds less than about 4.0 E21/cm 3 .
Claim 15
Dependent Claim 26 words
A method as claimed in claim 13, characterized in that the thickness of the second layer lies in the range of about 0.5 to 1.5 μm.
Claim 16
Dependent Claim 20 words
A method as claimed in claim 13, characterized in that the thickness of the second layer is about 1.0 μm.
Claim 17
Dependent Claim 29 words
A method as claimed in claim 13, characterized in that the second layer is deposited by plasma enhanced vapour deposition at a temperature of less than about 450° C.

References Cited (Backward Citations)

US4775550A Cited
US4965226A Cited
US5202275A Cited
US5270267A Cited
US5135608A Cited
WO1991009422A1 Cited
US5037777A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-07-30 2000-01-29 2000-07-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-07-30 2004-01-29 2004-07-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-07-30 2008-01-29 2008-07-30 $7700.00 Window Closed / Lapsed

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