US5538536A
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Process and apparatus for separation of a gaseous mixture by successive membranes of different selectivities
Assignee: LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
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Filing: 1995-04-11
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Granted: 1996-07-23
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Expires: 2015-04-11
Abstract
Abstract Process and apparatus for the separation of at least one gas from an entering gaseous mixture (1), of the type in which a membrane separation is conducted with at least two successive membrane separators in the following manner: the entering mixture is passed through a first membrane separator (2) operating at a first operating temperature and all or a portion of the residual mixture (5) from this first membrane separator is passed through a second membrane separator (3) operating at a second operating temperature. A mixture enriched in the gas is obtained from the permeate outlet (6, 4) of each of these two separators. Two separators are used whose selectivities for the gas are different. These may be membranes of different type, or membranes of the same type, if the first operating temperature is different from the second operating temperature.
Inventors
- 👤 François Fuentes
- 👤 Pierre-Olivier Dolle
- 👤 Antoine Willemot
- 👤 Lionel Barry
- 👤 Fr ed eric Fillet
- 👤 Jean-Louis Gelot
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 21:31
CPC Classifications
C; C01; C01B; C01B3/00; C01B3/50; C01B3/501; C01B3/503; B; B01; B01D; B01D53/00; B01D53/22; B01D53/225; B01D53/226; C01B21/00; C01B21/04; C01B21/0405; C01B21/0433; C01B21/0438; B01D2257/00; B01D2257/10; B01D2257/108; C01B2203/00; C01B2203/04; C01B2203/0405; C01B2203/0465; C01B2203/047; C01B2203/048
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
131 words
In a process for the separation of at least one gas from an entering gaseous mixture, wherein a membrane separation is conducted with at least two successive membrane separators, said process comprising: passing an entering mixture through a first of said at least two successive membrane separators, said first membrane separator operating at a first operating temperature and passing at least a portion of a residual mixture from said first membrane separator through a second of said at least two membrane separators, said second membrane separator operating at a second operating temperature, and obtaining a mixture enriched in said gas from a permeate outlet of each of these two separators; the improvement which comprises using as the first and second membrane separators, two separators whose selectivities for said gas are different.
Claim 2
Dependent Claim
131 words
In a process for the separation of at least one gas from an entering gaseous mixture, wherein a membrane separation is conducted with at least two successive membrane separators, said process comprising: passing an entering mixture through a first of said at least two successive membrane separators, said first membrane separator operating at a first operating temperature and passing at least a portion of a residual mixture from said first membrane separator through a second of said at least two membrane separators, said second membrane separator operating at a second operating temperature, and obtaining a mixture enriched in said gas from a permeate outlet of each of these two separators; the improvement which comprises using as the first and second membrane separators, two separators whose selectivities for said gas are different.
Claim 3
Dependent Claim
19 words
Process according to claim 1, wherein there is used for the first and second separators membranes of different type.
Claim 4
Dependent Claim
32 words
Process according to claim 1, wherein there is used for the first and second separators membranes of the same type, and said first operating temperature is different from said second operating temperature.
Claim 5
Dependent Claim
83 words
Process according to claim 3, wherein said first operating temperature is higher than said second operating temperature, and the residual mixture from the first membrane separator is cooled, before its arrival at the second membrane separator, by passage through an exchanger with at least two passages, wherein through a second passageway of the exchanger is passed a permeate mixture obtained on the permeate outlet of the second separator, and into which permeate mixture water has been sprayed before its arrival at said exchanger.
Claim 6
Dependent Claim
32 words
Process according to claim 4, wherein said exchanger is an exchanger with at least three passages, the third passage being used for the passage of the residual mixture from the second separator.
Claim 7
Dependent Claim
51 words
Process according to claim 3, wherein the entering mixture is air, and said first operating temperature is higher by at least 20° C. than said second operating temperature, the nitrogen concentration of the gaseous mixture obtained on the residual side of the second membrane separator being greater than 99% by volume.
Claim 8
Dependent Claim
29 words
Process according to claim 1, wherein the selectivity for said gas of the first membrane separator is greater than the selectivity for said gas of the second membrane separator.
Claim 9
Dependent Claim
29 words
Process according to claim 7, wherein the membrane of the first membrane separator is made of polyaramide and the membrane of the second membrane separator is made of polyimide.
Claim 10
Dependent Claim
29 words
Process according to claim 1, wherein the selectivity for said gas of the first membrane separator is lower than the selectivity for said gas of the second membrane separator.
Claim 11
Dependent Claim
29 words
Process according to claim 1, wherein said gas is hydrogen, and said gaseous medium contains at least one of the gases of the group constituted by CO and hydrocarbons.
Claim 12
Dependent Claim
64 words
Process according to claim 10, wherein said gaseous medium is mostly comprised by hydrogen and hydrocarbons, and wherein the dew point of the gaseous mixture obtained on a residual side of the first separator is below said first operating temperature, and the dew point of the gaseous mixture obtained on a residual side of said second separator is lower than said second operating temperature.
Claim 13
Dependent Claim
18 words
Process according to claim 11, wherein said first operating temperature is no higher than said second operating temperature.
Claim 14
Dependent Claim
29 words
Process according to claim 11, wherein the membrane of the first membrane separator is made of polyimide and the membrane of the second membrane separator is made of polyaramide.
Claim 15
Dependent Claim
21 words
Process according to claim 1, for the production of CO, wherein said gaseous mixture is mostly comprised by hydrogen and CO.
Claim 16
Dependent Claim
60 words
Process according to claim 1, for the production of hydrogen, so as to supply two utilization stations requiring two hydrogen streams of different characteristics, wherein said gaseous mixture is mostly comprised by hydrogen and hydrocarbons, and wherein there are directed toward the two utilization stations, two mixtures enriched in hydrogen obtained at the permeate outlet of the two membrane separators.
Claim 17
Dependent Claim
58 words
Process according to claim 1, for the production of hydrogen for the supply of a utilization station, wherein said gaseous mixture is mostly comprised of hydrogen and hydrocarbons, and wherein the mixtures enriched in hydrogen obtained at the permeate outlet of the two separators are reunited in a single stream, which is then directed to said utilization station.
Claim 18
Dependent Claim
113 words
Apparatus for the separation of gas, for the supply of a utilization station with gas, comprising: a first membrane separator having a first selectivity for said gas, a second membrane separator having a second selectivity for said gas higher than said first selectivity, and a cooling system for gas, disposed in one of the following locations: a) along a conduit connecting a residual outlet of the first separator to an inlet of the second separator; b) along a conduit connecting a residual outlet of the second separator to the utilization station of said gas; c) along a conduit connecting a permeate outlet of the second separator to a inlet of the first separator.
Claim 19
Dependent Claim
113 words
Apparatus for the separation of gas, for the supply of a utilization station with gas, comprising: a first membrane separator having a first selectivity for said gas, a second membrane separator having a second selectivity for said gas higher than said first selectivity, and a cooling system for gas, disposed in one of the following locations: a) along a conduit connecting a residual outlet of the first separator to an inlet of the second separator; b) along a conduit connecting a residual outlet of the second separator to the utilization station of said gas; c) along a conduit connecting a permeate outlet of the second separator to a inlet of the first separator.
Claim 20
Dependent Claim
103 words
Apparatus according to claim 17, wherein the cooling system is disposed along the conduit connecting the residual outlet of the first separator to the inlet of the second separator, said apparatus further comprising an exchanger having passages and being so located that one of the passages of the exchanger is used to pass a residual mixture from the first separator between the first separator and the cooling system, the other passages being used to pass a permeate mixture from the second separator to the inlet of the first separator, and to pass a residual mixture from the second separator to the utilization station.
Claim 21
Dependent Claim
108 words
Apparatus according to claim 17, wherein the cooling system is disposed along the conduit connecting the residual outlet of the second separator to the utilization station of the gas, said apparatus further comprising an exchanger having passages and being so located that one of the passages of the exchanger is used to pass a residual mixture from the second separator between the cooling system and the utilization station, the other passages of the exchanger being used to pass a residual mixture from the first separator between the first separator and the second separator, and a permeate mixture from the second separator to the inlet of the first separator.
Claim 22
Dependent Claim
124 words
Apparatus according to claim 17, wherein the cooling system is disposed along the conduit connecting the permeate outlet of the second separator to the inlet of the first separator, said apparatus further comprising an exchanger having passages, said cooling system comprising means for injecting water into a permeate mixture from the second separator, the permeate mixture into which has been injected the water passing then through one of the passages of the exchanger, before reaching the inlet of the first separator, the other passages of the exchanger being used to pass a residual mixture from the first separator between the first separator and the second separator, and to pass a residual mixture from the second separator between the second separator and the utilization station.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1999-07-23 | 2000-01-22 | 2000-07-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2003-07-23 | 2004-01-22 | 2004-07-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2007-07-23 | 2008-01-22 | 2008-07-23 | $7700.00 | Window Closed / Lapsed |