US5425801A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Membrane nitrogen with temperature tracking
Assignee: Praxair Technology Inc
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Filing: 1993-12-21
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Granted: 1995-06-20
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Expires: 2013-12-21
Abstract
Abstract Advanced membrane compositions having high permeability characteristics, and optimal operating temperatures above ambient during only a portion of the year, are operated with a controlled reduction in operating feed air pressure under rising ambient temperature conditions. The overall efficiency of the air separation process is enhanced, and power requirements are significantly reduced.
Inventors
- 👤 Ravi Prasad
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 00:55
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/22; B01D53/225; B01D53/226; B01D2256/00; B01D2256/10; C; C01; C01B; C01B21/00; C01B21/04; C01B21/0405; C01B21/0433; C01B21/0438
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
429 words
An improved gas separation process for the operation of high permeability membranes having optimum operating temperatures above cool ambient temperatures prevailing during a portion of an operating year at a gas separation location, the optimum operating temperature being below the ambient temperature during the remainder of the operating year, comprising the steps of: (a) compressing feed gas to a predetermined feed gas operating pressure in a feed gas compressor of a feed gas compresser/membrane gas separation system combination at a plant location in which cool ambient temperature conditions prevail during a portion of the year, with higher ambient conditions prevailing during the remainder of the year, a design feed gas operating pressure being a desired feed gas pressure pertaining to said cool ambient temperature conditions; (b) adjusting the feed gas at said predetermined feed gas operating pressure, using an aftercooler unit of the feed gas compressor and heater means to maintain a desired optimum operating temperature above said cool ambient temperature conditions during the portion of the year in which said cool ambient temperature conditions prevail; (c) passing the feed gas, at said predetermined feed gas operating pressure and adjusted to a desired optimum operating temperature in step (b) above, to said membrane gas separation system for the isothermal separation of a less permeable component thereof at said desired optimum operating temperature, said membrane gas separation system being capable of selectively permeating the more permeable component of feed gas and comprising membrane separation material having a desired optimum operating temperature above said cool ambient temperature conditions; (d) recovering non-permeate gas and permeate gas from the membrane gas separation system at said optimum operating temperature above said cool ambient temperature conditions; (e) adjusting the thus compressed feed gas, using the aftercooler unit of the feed gas compressor and heater means, but allowing the operating temperature to rise in response to higher ambient temperature conditions in the portion of the year in which the ambient temperature rises to above the optimum operating temperature conditions prevailing during the other portion of the year; (f) decreasing the feed gas operating pressure below said predetermined feed gas operating pressure that prevails at said cool ambient temperature conditions during the portion of the year in which the operating temperature is allowed to rise in step (e), in response to higher ambient temperature conditions, so as to maintain desired product conditions in step (d), whereby membrane gas separation operations are carried out for the production of product gas under varying ambient temperature conditions without the use of external refrigeration and at desirable reduced power consumption levels.
Claim 2
Dependent Claim
429 words
An improved gas separation process for the operation of high permeability membranes having optimum operating temperatures above cool ambient temperatures prevailing during a portion of an operating year at a gas separation location, the optimum operating temperature being below the ambient temperature during the remainder of the operating year, comprising the steps of: (a) compressing feed gas to a predetermined feed gas operating pressure in a feed gas compressor of a feed gas compresser/membrane gas separation system combination at a plant location in which cool ambient temperature conditions prevail during a portion of the year, with higher ambient conditions prevailing during the remainder of the year, a design feed gas operating pressure being a desired feed gas pressure pertaining to said cool ambient temperature conditions; (b) adjusting the feed gas at said predetermined feed gas operating pressure, using an aftercooler unit of the feed gas compressor and heater means to maintain a desired optimum operating temperature above said cool ambient temperature conditions during the portion of the year in which said cool ambient temperature conditions prevail; (c) passing the feed gas, at said predetermined feed gas operating pressure and adjusted to a desired optimum operating temperature in step (b) above, to said membrane gas separation system for the isothermal separation of a less permeable component thereof at said desired optimum operating temperature, said membrane gas separation system being capable of selectively permeating the more permeable component of feed gas and comprising membrane separation material having a desired optimum operating temperature above said cool ambient temperature conditions; (d) recovering non-permeate gas and permeate gas from the membrane gas separation system at said optimum operating temperature above said cool ambient temperature conditions; (e) adjusting the thus compressed feed gas, using the aftercooler unit of the feed gas compressor and heater means, but allowing the operating temperature to rise in response to higher ambient temperature conditions in the portion of the year in which the ambient temperature rises to above the optimum operating temperature conditions prevailing during the other portion of the year; (f) decreasing the feed gas operating pressure below said predetermined feed gas operating pressure that prevails at said cool ambient temperature conditions during the portion of the year in which the operating temperature is allowed to rise in step (e), in response to higher ambient temperature conditions, so as to maintain desired product conditions in step (d), whereby membrane gas separation operations are carried out for the production of product gas under varying ambient temperature conditions without the use of external refrigeration and at desirable reduced power consumption levels.
Claim 3
Dependent Claim
29 words
The process of claim 1 in which, during step (e), the operating temperature is allowed to rise approximately 5° F. to 15° F. higher than the prevailing ambient temperature.
Claim 4
Dependent Claim
44 words
The process of claim 1 in which, during step (f), the operating pressure is decreased in response to a rise in ambient temperature so as to maintain product purity and/or flow conditions essentially at purity and/or flow conditions prevailing under cool ambient temperature conditions.
Claim 5
Dependent Claim
44 words
The process of claim 1 in which said feed gas comprises air, and said membrane gas separation system comprises a membrane air separation system capable of selectively permeating oxygen as the more permeable component of feed air, with recovery of non-permeate nitrogen product gas.
Claim 6
Dependent Claim
14 words
The process of claim 4 in which said product gas is about 99% nitrogen.
Claim 7
Dependent Claim
18 words
The process of claim 4 in which said membrane air separation system comprises a two stage membrane system.
Claim 8
Dependent Claim
25 words
The process of claim 4 in which said membrane separation material has a permeability for oxygen of at least about 0.5 Barrers at 100° F.
Claim 9
Dependent Claim
24 words
The process of claim 4 in which said membrane air separation system comprises more than one individual membrane modules adapted for parallel flow therethrough.
Claim 10
Dependent Claim
19 words
The process of claim 8 in which said membrane air separation system contains a multiplicity of individual membrane modules.
Claim 11
Dependent Claim
69 words
The process of claim 8 in which, in step (f), the feed air operating pressure is decreased to not more than a predetermined lower operating pressure level for said feed air compressor, and including isolating at least one of said individual membrane modules from the flow of feed air to the membrane air separation system, in response to the rise in operating temperature at said higher ambient temperature conditions.
Claim 12
Dependent Claim
29 words
The process of claim 10 in which, during step (e), the operating temperature is allowed to rise approximately 5° F. to 15° F. higher than the prevailing ambient temperature.
Claim 13
Dependent Claim
38 words
The process of claim 10 and including increasing the feed air operating pressure in conjunction with the isolating of at least one individual membrane module prior to further decreasing of said feed air operating pressure in step (f).
Claim 14
Dependent Claim
24 words
The process of claim 12 in which said feed air operating pressure is increased to the predetermined feed air operating pressure of step (a).
Claim 15
Dependent Claim
96 words
The process of claim 1 and including: (i) monitoring the quantity and/or purity of the product gas recovered, and the temperature and/or pressure of the compressed feed gas passing to the membrane gas separation system; (ii) sending process variable signals proportional to the process conditions monitored in (i) above to a process computer/controller system adapted to send corresponding output signals to the feed gas compressor and/or the aftercooler unit thereof, and/or said heater means, for control of feed gas compression and/or adjustment in steps (a) and (b) in response to changes in said ambient temperature conditions.
Claim 16
Dependent Claim
44 words
The process of claim 14, in which said feed gas comprises air, and said membrane gas separation system comprises a membrane air separation system capable of selectively permeating oxygen as the more permeable component of feed air, with recovery of non-permeate nitrogen product gas.
Claim 17
Dependent Claim
43 words
The process of cliam 1 in which the cool ambient temperature conditions below the optimum operating temperature prevail at least about 1/2 of an operating year, the ambient temperature rising to above said optimum operating temperature during the remainder of the operating year.
Claim 18
Dependent Claim
43 words
The process of cliam 1 in which the cool ambient temperature conditions below the optimum operating temperature prevail at least about 1/2 of an operating year, the ambient temperature rising to above said optimum operating temperature during the remainder of the operating year.
Claim 19
Dependent Claim
45 words
The process of claim 1 and including removing condensate from the feed gas passing from the aftercooler unit of the feed gas compressor, the compressed feed gas passing from the heater means comprising superheated gas, thereby preventing undesired condensation in the membrane gas separation system.
Claim 20
Dependent Claim
44 words
The process of claim 17 in which said feed gas comprises air, and said membrane gas separation system comprises a membrane air separation system capable of selectively permeating oxygen as the more permeable component of feed air, with recovery of the non-permeate nitrogen product.
Claim 21
Dependent Claim
22 words
The process of claim 1 in which the surface area of the membrane gas separation system is maintained constant during steps (c)-(f).
Claim 22
Dependent Claim
12 words
The process of claim 1 in which said feed gas comprises air.
References Cited (Backward Citations)
US3930814A
Cited
US3930813A
Cited
US4397661A
Cited
US4421529A
Cited
US4781907A
Cited
US4806132A
Cited
USRE33678E
Cited
US4857082A
Cited
US4881953A
Cited
US4894068A
Cited
US5118327A
Cited
US5053058A
Cited
US5077029A
Cited
US5102432A
Cited
US5226931A
Cited
US5266101A
Cited
US5284506A
Cited
US5290341A
Cited
US5302189A
Cited
US5281253A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1998-06-19 | 1998-12-19 | 1999-06-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2002-06-19 | 2002-12-19 | 2003-06-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2006-06-19 | 2006-12-19 | 2007-06-20 | $7700.00 | Window Closed / Lapsed |