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US5529607A Expired / Lapsed US ⏱️ 0.0 years remaining

PSA process with dynamic purge control

Assignee: Messer LLC
•
Filing: 1995-03-15
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Granted: 1996-06-25
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Expires: 2015-03-15
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Abstract

Abstract Oxygen of uniform purity is produced in a two-bed air-fed oxygen pressure swing adsorption process in which the beds are operated out of phase. The steps of the adsorption cycle include a pressurization/production step and a bed regeneration step, with the bed undergoing regeneration being purged with a low pressure stream of the oxygen-enriched gas produced as the nonadsorbed product of the process. The oxygen concentration in the purged gas effluent is continuously periodically monitored, and the maximum oxygen concentration in the effluent during selected purge steps is compared with the maximum oxygen concentration in the effluent during a previous purge step, and the difference is used to adjust the timing and duration of a purge step following the selected purge step in a manner that reduces the difference between the oxygen concentration in the sequential purge steps.

Inventors

  • 👤 Ziming Tan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 03:47
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/02; B01D53/04; B01D53/047; B01D2253/00; B01D2253/10; B01D2253/106; B01D2253/108; B01D2253/25; B01D2256/00; B01D2256/12; B01D2257/00; B01D2257/10; B01D2257/102; B01D2259/00; B01D2259/40; B01D2259/40007; B01D2259/40009; B01D2259/40011; B01D2259/40013; B01D2259/40015; B01D2259/4002; B01D2259/40022; B01D2259/40028; B01D2259/4003; B01D2259/40035; B01D2259/40037; B01D2259/40043; B01D2259/40045; B01D2259/4005; B01D2259/40052; B01D2259/40058; B01D2259/40073; B01D2259/40077; B01D2259/40081; B01D2259/402; B01D2259/403

Claims Analysis

Total Claims: 30
Claim 1
Independent Claim 315 words
A cyclic PSA process for recovering first component-enriched gas from a gas mixture containing first and second components in a system comprised of a battery of two or more beds of adsorbent which more strongly adsorb the second component than the first component, said beds being arranged in parallel and operated out of phase such that at least one bed is in adsorption service while at least one other bed is being regenerated, wherein a specific event occurs during each period of bed regeneration, comprising the following steps: (a) flowing said gas mixture into said at least one bed, thereby pressurizing said at least one bed to a selected adsorption pressure and producing first component-enriched gas as a nonadsorbed product, while regenerating said at least one other bed by desorbing second component-enriched gas therefrom at a selected vent pressure, said at least one other bed being purged with first component-enriched gas during at least part of the period of regeneration of said at least one other bed; (b) repeating step (a) with the roles of said at least one bed and said at least one other bed being changed until all beds of said system have undergone step (a); (c) periodically determining the absolute difference between the concentration of first component in the second component-enriched gas being desorbed from said at least one other bed upon the occurrence of said specific event during a period of regeneration of said at least one other bed and the concentration of first component in the second component-enriched gas being desorbed from said at least one bed upon the occurrence of said specific event during a period of regeneration of said at least one bed, and (d) periodically adjusting the duration of purge in one or more of said at least one bed and said at least one other bed in a manner that will reduce said absolute difference.
Claim 2
Dependent Claim 315 words
A cyclic PSA process for recovering first component-enriched gas from a gas mixture containing first and second components in a system comprised of a battery of two or more beds of adsorbent which more strongly adsorb the second component than the first component, said beds being arranged in parallel and operated out of phase such that at least one bed is in adsorption service while at least one other bed is being regenerated, wherein a specific event occurs during each period of bed regeneration, comprising the following steps: (a) flowing said gas mixture into said at least one bed, thereby pressurizing said at least one bed to a selected adsorption pressure and producing first component-enriched gas as a nonadsorbed product, while regenerating said at least one other bed by desorbing second component-enriched gas therefrom at a selected vent pressure, said at least one other bed being purged with first component-enriched gas during at least part of the period of regeneration of said at least one other bed; (b) repeating step (a) with the roles of said at least one bed and said at least one other bed being changed until all beds of said system have undergone step (a); (c) periodically determining the absolute difference between the concentration of first component in the second component-enriched gas being desorbed from said at least one other bed upon the occurrence of said specific event during a period of regeneration of said at least one other bed and the concentration of first component in the second component-enriched gas being desorbed from said at least one bed upon the occurrence of said specific event during a period of regeneration of said at least one bed, and (d) periodically adjusting the duration of purge in one or more of said at least one bed and said at least one other bed in a manner that will reduce said absolute difference.
Claim 3
Dependent Claim 19 words
The process of claim 1, wherein said battery comprises one or more pairs of alternately operated beds of adsorbent.
Claim 4
Dependent Claim 50 words
The process of claim 1 or 2, wherein said specific event is the occurrence of an extreme concentration of first component in the second component-enriched gas being desorbed from a bed being regenerated or the passage of a specific period of time after initiating purge of a bed being regenerated.
Claim 5
Dependent Claim 31 words
The process of claim 3, wherein said specific event is the occurrence of an extreme concentration of first component in the second component-enriched gas being desorbed from a bed being regenerated.
Claim 6
Dependent Claim 37 words
The process of claim 4, wherein said occurrence of an extreme concentration of first component is the occurrence of a maximum concentration of first component in the second component-enriched gas being desorbed from a bed being regenerated.
Claim 7
Dependent Claim 36 words
The process of claim 1 or claim 2, wherein the periods of regeneration in which step (c) is conducted are separated by a fixed number of periods of regeneration in which step (c) is not conducted.
Claim 8
Dependent Claim 20 words
The process of claim 6, wherein said fixed number of periods is in the range of 0 to about 5.
Claim 9
Dependent Claim 18 words
The process of claim 1 or claim 2, wherein step (c) is conducted more frequently than step (d).
Claim 10
Dependent Claim 26 words
The process of claim 1 or claim 2, wherein step (d) is conducted only when the absolute difference determined in step (c) exceeds a selected value.
Claim 11
Dependent Claim 36 words
The process of claim 1 or claim 2, wherein the periods of regeneration in which step (c) is conducted are separated by a variable number of periods of regeneration in which step (c) is not conducted.
Claim 12
Dependent Claim 21 words
The process of claim 10, wherein said variable number of periods is in the range of about 1 to about 5.
Claim 13
Dependent Claim 47 words
The process of claim 1 or claim 2, wherein said period of regeneration of said at least one bed which precedes said selected period of regeneration of said one other bed and said selected period of regeneration of said one other bed are consecutive bed regeneration periods.
Claim 14
Dependent Claim 37 words
The process of claim 12, wherein said selected period of regeneration of said at least one other bed and the period of regeneration in which the adjustment of step (d) is implemented are consecutive bed regeneration periods.
Claim 15
Dependent Claim 11 words
The process of claim 13, wherein said gas mixture is air.
Claim 16
Dependent Claim 15 words
The process of claim 14, wherein said adsorbent is selected from synthetic and natural zeolites.
Claim 17
Dependent Claim 21 words
The process of claim 15, wherein said adsorbent is a synthetic zeolite selected from type X zeolite and type A zeolite.
Claim 18
Dependent Claim 30 words
The process of claim 16, wherein said zeolite has exchangeable cations selected from ions of Group 1A, Group 2A, Group 3A, Group 3B, the lanthanide series and mixtures of these.
Claim 19
Dependent Claim 33 words
The process of claim 16, wherein said zeolite is type X zeolite selected from lithium-exchanged type X zeolite, calcium-exchanged type X zeolite, lithium- and calcium- exchanged type X zeolite and combinations of these.
Claim 20
Dependent Claim 21 words
The process of claim 16, wherein said adsorbent is selected from zeolite 5A, zeolite 10X, zeolite 13X and mixtures of these.
Claim 21
Dependent Claim 40 words
The process of claim 1 or claim 2, wherein said selected period of regeneration of said at least one other bed and the period of regeneration in which the adjustment of step (d) is implemented are consecutive bed regeneration periods.
Claim 22
Dependent Claim 25 words
The process of claim 1 or claim 2, wherein said selected adsorption pressure is in the range of about atmospheric pressure to about 20 bara.
Claim 23
Dependent Claim 20 words
The process of claim 1 or claim 2, wherein said first component is oxygen and said second component is nitrogen.
Claim 24
Dependent Claim 22 words
The process of claim 22, wherein said selected adsorption pressure is in the range of about atmospheric pressure to about 3 bara.
Claim 25
Dependent Claim 20 words
The process of claim 1 or claim 2, wherein said first component is nitrogen and said second component is oxygen.
Claim 26
Dependent Claim 47 words
The process of claim 1 or claim 2, wherein prior to step (a) said at least one bed is partially pressurized and said at least one other bed is partially depressurized by flowing gas from said at least one other bed to said at least one bed.
Claim 27
Dependent Claim 46 words
The process of claim 25, wherein between the additional step of claim 25 and step (a) said at least one bed is further pressurized by flowing part of said nonadsorbed product thereinto while said at least one other bed is further depressurized by venting gas therefrom.
Claim 28
Dependent Claim 43 words
The process of claim 1 or claim 2, wherein prior to step (a) said at least one bed is partially pressurized by flowing part of said nonadsorbed product thereinto while said at least one other bed is partially depressurized by venting gas therefrom.
Claim 29
Dependent Claim 54 words
The process of claim 1 or claim 2, wherein said battery comprises at least three beds of adsorbent that are operated sequentially in a cycle, and steps (c) and (d) are conducted recurrently with each bed periodically playing the role of said one bed and periodically playing the role of said one other bed.
Claim 30
Dependent Claim 31 words
The process of claim 1 or claim 2, wherein the production portion of step (a) is carried out at a temperature in the range of about 0° to about 100° C.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-06-25 1999-12-25 2000-06-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-06-25 2003-12-25 2004-06-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-06-25 2007-12-25 2008-06-25 $7700.00 Window Closed / Lapsed

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