Reflection preventing film and process for forming resist pattern using the same

Claim 2

A reflection preventing film which comprises a copolymer comprising, at least one recurring unit of the following formula (1), ##STR4## R 1 , R 2 , and R 3 may be the same or different and individually represent a hydrogen atom or an organic group; at least one recurring unit of the following formula (2), ##STR5## wherein R 1 , R 2 , and R 3 may be the same or different and individually represent a hydrogen atom or an organic group, and R 4 is an organic group containing an epoxy group; and at least one recurring unit of the following formula (3), ##STR6## wherein R 1 , R 2 , and R 3 may be the same or different and individually represent a hydrogen atom or an organic group, X represents a divalent group or a single bond, R 5 and R 6 may be the same or different and individually represent a hydrogen atom, a halogen atom, a hydroxy group, an amino group, a nitro group, or an organic group, R 7 and R 8 may be the same or different and individually represent a hydrogen atom, a halogen atom, an amino group, or an organic group, n is an integer of 1-4, and m is an integer of 1-5.

Claim 3

The reflection preventing film according to claim 1, wherein the organic group represented by R 1 , R 2 , or R 3 is selected from alkyl groups, carboxyl group, carboxyl alkyl groups, alkoxycarbonyl groups, acyloxy groups, aryl groups, aralkyl groups, alkoxy groups, cyclic alkyl groups, cyano groups, and amide groups; the epoxy group-containing organic group represented by R 4 is selected from epoxy group-containing alkyl groups, epoxy group-containing ether groups consisting of said epoxy group-containing alkyl group bonded to a carbon atom in the main chain constructing said recurring unit of said formula (2) via --O-- or --OR 9 --, wherein R 9 is an alkylene group, and epoxy group-containing ester groups consisting of said epoxy group-containing alkyl group bonded to a carbon atom in the main chain constructing said recurring unit of said formula (2) via --COO-- or --COOR 9 --, wherein R 9 is an alkylene group; the divalent group represented by X is a group --COO--, --COOR 9 --, --O--, or --OR 9 --, wherein R 9 is an alkylene group; the organic group represented by R 5 or R 6 is selected from alkyl groups, carboxyl group, carboxyl alkyl groups, alkoxycarbonyl groups, acyloxy groups, aryl groups, aralkyl groups, alkoxy groups, cyclic alkyl groups, cyano groups, amide groups, alkenyl groups, and cyclic alkyloxy groups; the organic group represented by R 7 or R 8 is selected from alkyl groups, carboxyl group, carboxyl alkyl groups, alkoxycarbonyl groups, acyloxy groups, aryl groups, aralkyl groups, alkoxy groups, cyclic alkyl groups, cyano groups, and amide groups.

Claim 4

The reflection preventing film according to claim 1, wherein said copolymer comprises copolymerized monomers corresponding to the recurring units represented by said formulas (1), (2), and (3) at a proportion of 2-50:5-60:2-60 mol %.

Claim 5

The reflection preventing film according to claim 1, wherein said copolymer comprises copolymerized monomers corresponding to the recurring units represented by said formulas (1), (2), and (3) at a proportion of 5-45:10-50:5-50 mol %.

Claim 6

The reflection preventing film according to claim 1, wherein said copolymer comprises copolymerized monomers corresponding to the recurring units represented by said formulas (1), (2), and (3) at a proportion of 10-40:15-45:10-45 mol %.

Claim 7

The reflection preventing film according to claim 3, wherein said copolymer further comprises one or more copolymerized monomers with a bulky group.

Claim 8

The reflection preventing film according to claim 6, wherein said monomer with a bulky group is selected from the group consisting of styrene, α-methylstyrene, 4-methylstyrene, 2-hydroxystyrene, 4-hydroxystyrene, 4-t-butylstyrene, chloromethylstyrene, divinylbenzene, dimethylvinylstyrylsilane, isopropenylstyrene, 1-vinylnaphthalene, 2-vinylnaphthalene, 9-vinylanthracene, 9-vinylcarbazole, vinylcyclohexene, ethylidenenorbornene, cyclopentadiene, tert-butyl (meth)acrylate, cyclohexyl (meth)acrylate, adamantyl (meth)acrylate, 1-naphthyl (meth)acrylate, 2-naphthyl (meth)acrylate, dicyclopentanyl (meth)acrylate, tricyclodecenyl (meth)acrylate, tricyclodecenyloxyethyl (meth)acrylate, tricyclodecanyl (meth)acrylate, 2-methacryloyloxyethyl phthalate, and 2-methacryloyloxyethyl hexahydrophthalate.

Claim 9

The reflection preventing film according to claim 3, wherein said copolymer further comprises one or more copolymerized monomers selected from the group consisting of vinyl esters of carboxylic acid, cyanated vinyl compounds, esters of unsaturated carboxylic acid, olefins, halogenated olefins, dienes, unsaturated group-containing unsaturated carboxylic acid esters, halogen-containing vinyl compounds, hydroxy group-containing vinyl compounds, amide group-containing vinyl compounds, and carboxyl group-containing vinyl compounds.

Claim 10

A process for forming a resist pattern which comprises forming the reflection preventing film defined in claim 1 on a substrate, coating a resist on said reflection preventing film to form a resist coating film, irradiating the resist coating film with a radiation in a desired pattern form, and developing the resist coating film to form a resist pattern.

Claim 11

The process according to claim 9, wherein said reflection preventing film is formed by a process comprising: preparing a solution by dissolving the copolymer defined in claim 1 in a solvent to make a solid component concentration of 5-50% by weight, filtering this solution through a filter, applying the filtrate to a substrate to form a film and baking the film to cure it.