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US5510011A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for forming a functional deposited film by bias sputtering process at a relatively low substrate temperature

Assignee: Canon Inc
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Filing: 1994-12-22
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Granted: 1996-04-23
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Expires: 2014-12-22
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Abstract

Abstract In a bias sputtering method comprising generating a plasma of a sputtering gas between a target electrode having a target thereon and a substrate electrode having a substrate for film formation thereon in a vacuum vessel with the use of a high frequency energy from a high frequency power source and sputtering said target with said plasma while applying a direct current voltage from a direct current power source to at least one of said target electrode or said substrate electrode thereby causing the formation of a film on said substrate, the improvement which comprises alternately repeating a deposition step and a non-deposition step, said deposition step comprising sputtering said target with said plasma while irradiating said substrate with ions of said plasma while depositing a film on said substrate, and said non-deposition step comprising irradiating said substrate with ions of said plasma without sputtering said target, thereby forming a high quality functional deposited film on said substrate.

Inventors

  • 👤 Nobuyuki Okamura
  • 👤 Atsushi Yamagami

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 18:39
CPC Classifications
C; C23; C23C; C23C14/00; C23C14/22; C23C14/34; C23C14/3435; C23C14/345; H; H01; H01J; H01J37/00; H01J37/32; H01J37/32431; H01J37/32697; H01J37/32706; H01J37/34; H01J37/3402; H01J37/3405; H01J37/3464; H01J37/3473; H10; H10D; H10D10/00; H10D10/01; H10D10/051; H10D10/054; H10P; H10P14/00; H10P14/20; H10P14/22; H10P14/29; H10P14/2901; H10P14/2902; H10P14/2905; H10P14/34; H10P14/3402; H10P14/3404; H10P14/3411

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 176 words
A process for forming a functional epitaxial film on a substrate by a bias sputtering method comprising generating a plasma of a sputtering gas between a target electrode having a target thereon and a substrate electrode having a substrate for film formation thereon in a vacuum vessel with the use of a high frequency energy with a frequency of 50 MHz to 300 MHz from a high frequency power source and sputtering said target with said plasma while applying a direct current voltage from a direct current power source to at least one of said target electrode and said substrate electrode thereby causing the formation of a film on said substrate, wherein a deposition step and a non-deposition step are alternately repeated, said deposition step comprising sputtering said target with said plasma while irradiating said substrate with ions of said plasma while depositing a film on said substrate, and said non-deposition step comprising irradiating said substrate with ions of said plasma without sputtering said target, thereby forming a high quality functional epitaxial film on said substrate.
Claim 2
Dependent Claim 176 words
A process for forming a functional epitaxial film on a substrate by a bias sputtering method comprising generating a plasma of a sputtering gas between a target electrode having a target thereon and a substrate electrode having a substrate for film formation thereon in a vacuum vessel with the use of a high frequency energy with a frequency of 50 MHz to 300 MHz from a high frequency power source and sputtering said target with said plasma while applying a direct current voltage from a direct current power source to at least one of said target electrode and said substrate electrode thereby causing the formation of a film on said substrate, wherein a deposition step and a non-deposition step are alternately repeated, said deposition step comprising sputtering said target with said plasma while irradiating said substrate with ions of said plasma while depositing a film on said substrate, and said non-deposition step comprising irradiating said substrate with ions of said plasma without sputtering said target, thereby forming a high quality functional epitaxial film on said substrate.
Claim 3
Dependent Claim 45 words
The process for forming a functional epitaxial film according to claim 1, wherein the direct current power source is electrically connected to the target electrode, and the deposition step and the non-deposition step are switched between each other by controlling the direct current power source.
Claim 4
Dependent Claim 23 words
The process for forming a functional epitaxial film according to claim 2, wherein the controlling comprises on-off controlling the direct current power source.
Claim 5
Dependent Claim 34 words
The process for forming a functional epitaxial film according to claim 2, wherein the controlling comprises generating a pulse signal using a microcomputer and inputting said pulse signal to the direct current power source.
Claim 6
Dependent Claim 29 words
The process for forming a functional epitaxial film according to claim 1, wherein a direct current voltage of -100 V to -500 V is applied to the target electrode.
Claim 7
Dependent Claim 30 words
The process for forming a functional epitaxial film according to claim 1, wherein the inside of the vacuum vessel is maintained at a pressure of 1 mTorr to 50 mTorr.
Claim 8
Dependent Claim 26 words
The process for forming a functional epitaxial film according to claim 1, wherein the substrate is maintained at a temperature of 250° C. to 500° C.
Claim 9
Dependent Claim 26 words
The process for forming a functional epitaxial film according to claim 7, wherein the substrate is maintained at a temperature of 250° C. to 380° C.
Claim 10
Dependent Claim 26 words
The process for forming a functional epitaxial film according to claim 1, wherein the functional epitaxial film formed on the substrate is an epitaxial silicon film.
Claim 11
Dependent Claim 93 words
The process for forming a functional epitaxial film according to claim 9, wherein the alternate repetition of the deposition step and the non-deposition step is conducted so as to satisfy the following two equations: Td≦5.43/N and Td≦Ta, with N being the deposition rate of the film deposited on the substrate in each deposition step, Td being the film formation period during which the film is deposited on the substrate in each deposition step, and Ta being the period during which the substrate is irradiated with ions of the plasma during each non-deposition step.

References Cited (Backward Citations)

US4874494A Cited
US4999096A Cited
US4963239A Cited
US5194398A Cited
US5242561A Cited
JPH09109161A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
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