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US5507891A Expired / Lapsed US ⏱️ 0.0 years remaining

Propellant composition for automotive safety applications

Assignee: Northrop Grumman Innovation Systems LLC
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Filing: 1995-08-11
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Granted: 1996-04-16
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Expires: 2015-08-11
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Abstract

Abstract Clean burning, non-self extinguishing propellant compositions for use in hybrid automotive air bag systems are disclosed. The propellant compositions are based on a mixture of a crystalline nitramine propellant, an energetic or non-energetic binder and one or a combination of an oxidizing propellant and an energetic plasticizer.

Inventors

  • 👤 Edward H. Zeigler

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 05:39
CPC Classifications
C; C06; C06B; C06B25/00; C06B25/34; C06D; C06D5/00; C06D5/06

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 184 words
A crash bag propellant system comprising a source of compressed, oxygen-containing inert gas and a propellant composition in functional proximity to ignition means for effecting ignition of said propellant within said gas, said propellant composition consisting essentially of a uniform mixture of: a) from about 40 to about 80% by weight of a crystalline particulate propellant selected from the group consisting of cyclotrimethylenetrinitramine, cyclotetramethylenetetranitramine and mixtures thereof; b) from 0 up to about 35% by weight of a crystalline particulate oxidant selected from the group consisting of ammonium nitrate, triamino-guanidinium nitrate, pentaerythritol tetranitrate and mixtures thereof; c) from about 8 to about 30% by weight of an inert or energetic binder; d) from 0 to about 15% by weight of an energetic plasticizer selected from the group consisting of trimethylolethane trinitrate, tri(ethylene glycol)dinitrate, butane triol trinitrate, bis-dinitropropyl acetyl, bis-dinitropropyl formal, glycidal azide, 1,5-diazido-3-nitraza pentane, and mixtures thereof; provided however, that where said binder component (c) does not comprise an energetic binder, the mixture contains at least about 5% by weight of component (b) or component (d) or a mixture of components (b) and (d).
Claim 2
Dependent Claim 184 words
A crash bag propellant system comprising a source of compressed, oxygen-containing inert gas and a propellant composition in functional proximity to ignition means for effecting ignition of said propellant within said gas, said propellant composition consisting essentially of a uniform mixture of: a) from about 40 to about 80% by weight of a crystalline particulate propellant selected from the group consisting of cyclotrimethylenetrinitramine, cyclotetramethylenetetranitramine and mixtures thereof; b) from 0 up to about 35% by weight of a crystalline particulate oxidant selected from the group consisting of ammonium nitrate, triamino-guanidinium nitrate, pentaerythritol tetranitrate and mixtures thereof; c) from about 8 to about 30% by weight of an inert or energetic binder; d) from 0 to about 15% by weight of an energetic plasticizer selected from the group consisting of trimethylolethane trinitrate, tri(ethylene glycol)dinitrate, butane triol trinitrate, bis-dinitropropyl acetyl, bis-dinitropropyl formal, glycidal azide, 1,5-diazido-3-nitraza pentane, and mixtures thereof; provided however, that where said binder component (c) does not comprise an energetic binder, the mixture contains at least about 5% by weight of component (b) or component (d) or a mixture of components (b) and (d).
Claim 3
Dependent Claim 33 words
The system of claim 1 wherein said binder component (c) is an inert binder selected from the group consisting of cellulose acetate, cellulose acetate butyrate, ethyl cellulose, an elastomeric polymer and mixtures thereof.
Claim 4
Dependent Claim 20 words
The system of claim 2 wherein said propellant composition contains from about 5 to 15% by weight of component (d).
Claim 5
Dependent Claim 11 words
The system of claim 3 wherein component (d) is trimethylolethane trinitrate.
Claim 6
Dependent Claim 11 words
The system of claim 3 wherein component (d) is glycidal azide.
Claim 7
Dependent Claim 20 words
The system of claim 2 wherein said propellant composition contains from about 70 to 80% by weight of component (a).
Claim 8
Dependent Claim 21 words
The system of claim 2 wherein said propellant composition contains from about 5 to about 35% by weight of component (b).
Claim 9
Dependent Claim 24 words
The system of claim 7 wherein component (b) is ammonium nitrate present at a level of from about 5 to about 15% by weight.
Claim 10
Dependent Claim 24 words
The system of claim 7 wherein component (b) is triaminoguanidinium nitrate present at a level of from about 20 to about 35% by weight.
Claim 11
Dependent Claim 11 words
The system of claim 2 wherein said binder is cellulose acetate.
Claim 12
Dependent Claim 35 words
The system of claim 1 wherein said binder component (c) comprises an energetic binder selected from the group consisting of cured glycidyl azide polymer, cured glycidal nitrate polymers, cured 3-nitrato-methyl-3-methyl oxetane polymers, and mixtures thereof.
Claim 13
Dependent Claim 14 words
The system of claim 11 wherein said energetic binder comprises a glycidyl azide polymer.
Claim 14
Dependent Claim 20 words
The system of claim 1 wherein said propellant composition contains from about 70 to 80% by weight of component (a).
Claim 15
Dependent Claim 32 words
The system of claim 1 wherein said propellant contains from about 40 to about 55% by weight of component (a) and from about 20 to about 35% by weight of component (b).
Claim 16
Dependent Claim 11 words
The system of claim 14 wherein component (b) is triaminoguanidinium nitrate.
Claim 17
Dependent Claim 20 words
The system of claim 1 wherein said compressed gas is argon containing up to about 20% by volume of oxygen.
Claim 18
Dependent Claim 21 words
The system of claim 16 wherein said gas is maintained under a pressure of from about 2000 to about 5,000 psi.
Claim 19
Dependent Claim 51 words
The system of claim 1 comprising a mixture of from about 70 to 80% by weight of cyclotrimethylenetrinitramine, from about 10 to 15% by weight of cellulose acetate binder and from about 10 to 15% by weight of a plasticizer selected from the group consisting of glycidal azide and trimethylolethane trinitrate.
Claim 20
Dependent Claim 11 words
The system of claim 17 wherein said plasticizer is trimethylolethane trinitrate.
Claim 21
Dependent Claim 12 words
The system of claim 1 wherein said propellant component (a) is cyclotrimethylenetrinitramine.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-04-16 1999-10-16 2000-04-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-04-16 2003-10-16 2004-04-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-04-16 2007-10-16 2008-04-16 $7700.00 Window Closed / Lapsed

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