US5507856A
Expired / Lapsed
US
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Hydrogen recovery by adsorbent membranes
Assignee: NATIONAL INSTITUTE FOR STRATEGIC TECHNOLOGY ACQUISITION AND COMMERCIALIZATION
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Filing: 1994-09-08
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Granted: 1996-04-16
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Expires: 2014-09-08
Abstract
Abstract A composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate is utilized to separate hydrogen-hydrocarbon mixtures and a sweep gas comprising some of the same hydrocarbons is passed across the low pressure side of the membrane to enhance hydrocarbon permeability. Methane is an effective sweep gas which promotes the permeation of heavier hydrocarbons even when methane is present in the membrane feed.
Inventors
- 👤 Madhukar B. Rao
- 👤 Shivaji Sircar
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 20:25
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/22; B01D53/228; B01D53/229; B01D67/00; B01D67/0039; B01D67/0046; B01D69/00; B01D69/04; B01D69/10; B01D69/108; B01D69/12; B01D71/00; B01D71/02; B01D71/028; B01D71/0281; C; C01; C01B; C01B3/00; C01B3/50; C01B3/501; C10; C10G; C10G70/00; C10G70/04; C10G70/045; B01D2323/00; B01D2323/08; B01D2323/081; C01B2203/00; C01B2203/04; C01B2203/0405; C01B2203/0465; C01B2203/047; C01B2203/0475; C01B2203/048; C01B2203/0495
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
195 words
A method for the recovery of hydrogen from a gaseous feed mixture comprising said hydrogen and one or more hydrocarbons, wherein said hydrocarbons are more strongly adsorbed on an adsorbent material than said hydrogen, said method comprising: (a) passing said feed mixture into a separator containing a composite semipermeable membrane consisting essentially of microporous adsorbent material supported by a porous substrate, said membrane having a feed side and a permeate side, and withdrawing from said separator a nonpermeate product stream enriched in said hydrogen, wherein portions of said hydrocarbons are selectively adsorbed by said microporous adsorbent material and diffuse from the feed side to the permeate side of said membrane as an adsorbed fluid phase, and further wherein contacting of said gaseous feed mixture with said membrane and permeation of components through said membrane occur in the absence of chemical reaction; (b) withdrawing from the permeate side of said membrane a permeate comprising said hydrocarbons; and (c) passing a sweep gas across the permeate side of said membrane and withdrawing from said separator a sweep gas/permeate effluent stream, wherein said sweep gas comprises one or more of the same hydrocarbons present in said feed mixture.
Claim 2
Independent Claim
195 words
A method for the recovery of hydrogen from a gaseous feed mixture comprising said hydrogen and one or more hydrocarbons, wherein said hydrocarbons are more strongly adsorbed on an adsorbent material than said hydrogen, said method comprising: (a) passing said feed mixture into a separator containing a composite semipermeable membrane consisting essentially of microporous adsorbent material supported by a porous substrate, said membrane having a feed side and a permeate side, and withdrawing from said separator a nonpermeate product stream enriched in said hydrogen, wherein portions of said hydrocarbons are selectively adsorbed by said microporous adsorbent material and diffuse from the feed side to the permeate side of said membrane as an adsorbed fluid phase, and further wherein contacting of said gaseous feed mixture with said membrane and permeation of components through said membrane occur in the absence of chemical reaction; (b) withdrawing from the permeate side of said membrane a permeate comprising said hydrocarbons; and (c) passing a sweep gas across the permeate side of said membrane and withdrawing from said separator a sweep gas/permeate effluent stream, wherein said sweep gas comprises one or more of the same hydrocarbons present in said feed mixture.
Claim 3
Dependent Claim
32 words
The method of claim 1 wherein said feed mixture comprises one or more hydrocarbons selected from the group consisting of methane, ethane, ethylene, propane, propylene, butane, isobutane, butylene, isobutylene, and mixtures thereof.
Claim 4
Dependent Claim
32 words
The method of claim 1 wherein said sweep gas comprises one or more hydrocarbons selected from the group consisting of methane, ethane, ethylene, propane, propylene, butane, isobutane, butylene, isobutylene, and mixtures thereof.
Claim 5
Dependent Claim
11 words
The method of claim 3 wherein said sweep gas comprises methane.
Claim 6
Dependent Claim
12 words
The method of claim 1 wherein said sweep gas is natural gas.
Claim 7
Dependent Claim
12 words
The method of claim 1 wherein said sweep gas further comprises hydrogen.
Claim 8
Dependent Claim
19 words
The method of claim 1 wherein said feed mixture is supplied at a pressure between 20 and 300 psig.
Claim 9
Dependent Claim
18 words
The method of claim 7 wherein the pressure of said sweep gas is between 2 and 50 psig.
References Cited (Backward Citations)
US4002042A
Cited
US4077779A
Cited
US4398926A
Cited
US4732583A
Cited
US4732583B1
Cited
US4654063A
Cited
US4690695A
Cited
US4765804A
Cited
US4701187A
Cited
US4934148A
Cited
US4981676A
Cited
US5104425A
Cited
US5354547A
Cited
US5332424A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1999-04-16 | 1999-10-16 | 2000-04-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2003-04-16 | 2003-10-16 | 2004-04-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2007-04-16 | 2007-10-16 | 2008-04-16 | $7700.00 | Window Closed / Lapsed |