US5354547A
Expired / Lapsed
US
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Hydrogen recovery by adsorbent membranes
Assignee: NATIONAL INSTITUTE FOR STRATEGIC TECHNOLOGY ACQUISITION AND COMMERCIALIZATION
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Filing: 1992-08-03
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Granted: 1994-10-11
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Expires: 2012-08-03
Abstract
Abstract A composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate is operated in series with a pressure swing adsorption (PSA) system and the PSA reject gas is used as a sweep gas to improve membrane performance. The integrated membrane-PSA system is particularly useful for recovering high-purity hydrogen from a mixture of hydrogen and hydrocarbons, and is well-suited for integration with a steam-methane reformer.
Inventors
- 👤 Madhukar B. Rao
- 👤 Shivaji Sircar
- 👤 Joseph M. Abrardo
- 👤 William F. Baade
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 14:58
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/22; B01D53/229; B01D53/02; B01D53/04; B01D53/047; B01D53/228; B01D67/00; B01D67/0039; B01D67/0046; B01D67/0072; B01D67/0081; B01D67/0088; B01D69/00; B01D69/04; B01D69/10; B01D69/12; B01D71/00; B01D71/02; B01D71/028; B01D71/0281; C; C01; C01B; C01B3/00; C01B3/50; C01B3/501; C10; C10G; C10G70/00; C10G70/04; C10G70/045; B01D2323/00; B01D2323/08; B01D2323/081; C01B2203/00; C01B2203/04; C01B2203/0405; C01B2203/0465; C01B2203/048
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
219 words
A method for the recovery of one or more primary components from a gaseous feed mixture comprising said primary components and one or more secondary components, wherein said secondary components are more strongly adsorbed on an adsorbent material than said primary components, said method comprising: (a) passing said feed mixture into a separator containing a composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate, said membrane having a feed side and a permeate side, and withdrawing from said separator a nonpermeate intermediate product stream enriched in said primary components, wherein portions of said secondary components are selectively adsorbed by said microporous adsorbent material and diffuse from the feed side to the permeate side of said membrane as an adsorbed fluid phase; (b) withdrawing from the permeate side of said membrane a permeate comprising said secondary components; (c) separating said nonpermeate intermediate product stream into a high-purity product stream comprising said primary components and a reject stream comprising an additional portion of said secondary components; and (d) passing at least a portion of said reject stream across the permeate side of said membrane as a sweep gas and withdrawing from said separator a sweep gas/permeate effluent stream, thereby increasing the recovery of said primary components and increasing the permeation rate of said secondary components through said membrane.
Claim 2
Independent Claim
219 words
A method for the recovery of one or more primary components from a gaseous feed mixture comprising said primary components and one or more secondary components, wherein said secondary components are more strongly adsorbed on an adsorbent material than said primary components, said method comprising: (a) passing said feed mixture into a separator containing a composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate, said membrane having a feed side and a permeate side, and withdrawing from said separator a nonpermeate intermediate product stream enriched in said primary components, wherein portions of said secondary components are selectively adsorbed by said microporous adsorbent material and diffuse from the feed side to the permeate side of said membrane as an adsorbed fluid phase; (b) withdrawing from the permeate side of said membrane a permeate comprising said secondary components; (c) separating said nonpermeate intermediate product stream into a high-purity product stream comprising said primary components and a reject stream comprising an additional portion of said secondary components; and (d) passing at least a portion of said reject stream across the permeate side of said membrane as a sweep gas and withdrawing from said separator a sweep gas/permeate effluent stream, thereby increasing the recovery of said primary components and increasing the permeation rate of said secondary components through said membrane.
Claim 3
Dependent Claim
55 words
The method of claim 1 wherein said intermediate product stream is separated in step (c) by passing the stream into a pressure swing adsorption system wherein remaining secondary components are selectively adsorbed, and withdrawing therefrom said high purity product comprising the primary components and said reject stream comprising an additional portion of said secondary components.
Claim 4
Dependent Claim
13 words
The method of claim 2 wherein said primary components comprise at least hydrogen.
Claim 5
Dependent Claim
29 words
The method of claim 3 wherein said secondary components comprise hydrocarbons selected from the group consisting of methane, ethane, ethylene, propane, propylene, butane, isobutane, butylene, isobutylene, and mixtures thereof.
Claim 6
Dependent Claim
18 words
The method of claim 4 wherein the pressure of said feed stream is between 20 and 300 psig.
Claim 7
Dependent Claim
19 words
The method of claim 5 wherein the pressure of said intermediate product stream is between 15 and 295 psig.
Claim 8
Dependent Claim
23 words
The method of claim 4 wherein the pressure of said reject stream used as said sweep gas is between 2 and 50 psig.
Claim 9
Dependent Claim
47 words
The method of claim 4 which further comprises reforming a methane-containing feed stream in a steam-methane reformer to produce a synthesis gas comprising hydrogen, carbon oxides, water, and unreacted methane, and combining said synthesis gas with said intermediate product stream prior to said pressure swing adsorption system.
Claim 10
Dependent Claim
25 words
The method of claim 8 which further comprises utilizing at least a portion of said sweep gas/permeate effluent stream as fuel in said steam-methane reformer.
Claim 11
Dependent Claim
68 words
The method of claim 4 which further comprises passing at least a portion of said sweep gas/permeate effluent stream into a dephlegmator, withdrawing therefrom a hydrocarbon product stream containing C 3 and heavier hydrocarbons, also withdrawing therefrom an intermediate light hydrocarbon stream containing components lighter than C 3 , and combining said intermediate light hydrocarbon stream with said intermediate product stream prior to said pressure swing adsorption system.
Claim 12
Independent Claim
237 words
A method for the production of hydrogen from a methane-containing feed gas and a gas mixture containing hydrogen and hydrocarbons, wherein said method comprises: (a) passing said gas mixture into a separator containing a composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate, said membrane having a feed side and a permeate side, and withdrawing from said separator an intermediate product stream enriched in hydrogen, wherein portions of said hydrocarbons are selectively adsorbed by said microporous adsorbent material and diffuse from the feed side to the permeate side of said membrane as an adsorbed fluid phase; (b) withdrawing from the permeate side of said membrane a permeate comprising said hydrocarbons; (c) reforming a portion of said methane-containing feed gas in a steam-methane reformer to produce a synthesis gas comprising hydrogen, carbon oxides, water, and unreacted methane, and combining said synthesis gas with said intermediate product stream; (d) passing the resulting combined stream of step (c) into a pressure swing adsorption system wherein hydrocarbons and carbon oxides are selectively adsorbed, and withdrawing therefrom a high purity hydrogen product and a reject stream comprising hydrocarbons and carbon oxides; and (e) passing the remaining portion of said methane-containing feed gas across the permeate side of said membrane as a sweep gas and withdrawing from said separator a sweep gas/permeate effluent stream, thereby increasing the recovery of hydrogen and increasing the permeation rate of hydrocarbons through said membrane.
Claim 13
Independent Claim
237 words
A method for the production of hydrogen from a methane-containing feed gas and a gas mixture containing hydrogen and hydrocarbons, wherein said method comprises: (a) passing said gas mixture into a separator containing a composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate, said membrane having a feed side and a permeate side, and withdrawing from said separator an intermediate product stream enriched in hydrogen, wherein portions of said hydrocarbons are selectively adsorbed by said microporous adsorbent material and diffuse from the feed side to the permeate side of said membrane as an adsorbed fluid phase; (b) withdrawing from the permeate side of said membrane a permeate comprising said hydrocarbons; (c) reforming a portion of said methane-containing feed gas in a steam-methane reformer to produce a synthesis gas comprising hydrogen, carbon oxides, water, and unreacted methane, and combining said synthesis gas with said intermediate product stream; (d) passing the resulting combined stream of step (c) into a pressure swing adsorption system wherein hydrocarbons and carbon oxides are selectively adsorbed, and withdrawing therefrom a high purity hydrogen product and a reject stream comprising hydrocarbons and carbon oxides; and (e) passing the remaining portion of said methane-containing feed gas across the permeate side of said membrane as a sweep gas and withdrawing from said separator a sweep gas/permeate effluent stream, thereby increasing the recovery of hydrogen and increasing the permeation rate of hydrocarbons through said membrane.
Claim 14
Dependent Claim
25 words
The method of claim 11 which further comprises utilizing at least a portion of said sweep gas/permeate effluent stream as fuel in said steam-methane reformer.
Claim 15
Dependent Claim
26 words
The method of claim 11 which further comprises utilizing at least a portion of said sweep gas/permeate effluent stream as additional feed in said steam-methane reformer.
Claim 16
Dependent Claim
29 words
The method of claim 11 which further comprises utilizing at least a portion of said reject stream from said pressure swing absorption system as fuel in said steam-methane reformer.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-10-10 | 1998-04-11 | 1998-10-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-10-10 | 2002-04-11 | 2002-10-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-10-10 | 2006-04-11 | 2006-10-11 | $7700.00 | Window Closed / Lapsed |