US5503965A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for development of black-and-white- silver halide photographic material
Assignee: Fujifilm Holdings Corp
•
Filing: 1994-09-27
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Granted: 1996-04-02
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Expires: 2014-09-27
Abstract
Abstract The present invention improves the running stability of a developer comprising an ascorbic acid instead of hydroquinone as a developing agent. The present invention provides a process for development of a black-and-white silver halide photographic material, which comprises use of a development replenisher for black-and-white silver halide photographic material comprising an ascorbic acid and/or derivative thereof which has a pH value of at least 0.5 higher than that of the development starting solution.
Inventors
- 👤 Eiichi Okutsu
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 22:57
CPC Classifications
G; G03; G03C; G03C5/00; G03C5/26; G03C5/29; G03C5/305; G03C5/30; G03C5/31; G03C1/00; G03C1/005; G03C1/0051; G03C1/035; G03C2200/00; G03C2200/01; G03C2200/03
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
80 words
A process for developing an exposed black-and-white silver halide photographic material with an automatic developing machine, which comprises processing the black-and-white silver halide photographic material in a development starting solution and adding a development replenisher solution to the development starting solution, wherein each of said development starting solution and development replenisher solution comprises ascorbic acid and/or a derivative thereof, and the development replenisher solution has a pH value of at least 0.5 higher than that of the development starting solution.
Claim 2
Dependent Claim
80 words
A process for developing an exposed black-and-white silver halide photographic material with an automatic developing machine, which comprises processing the black-and-white silver halide photographic material in a development starting solution and adding a development replenisher solution to the development starting solution, wherein each of said development starting solution and development replenisher solution comprises ascorbic acid and/or a derivative thereof, and the development replenisher solution has a pH value of at least 0.5 higher than that of the development starting solution.
Claim 3
Dependent Claim
92 words
A process for developing an exposed black-and-white silver halide photographic material with an automatic developing machine, which comprises processing the black-and-white silver halide photographic material in a development starting solution and adding a development replenisher solution to the development starting solution, wherein each of said development starting solution and development replenisher solution comprises ascorbic acid and/or a derivative thereof and a carbonate in an amount of not less than 0.5 mol/l, and the development replenisher solution has a pH value of at least 0.3 higher than that of the development starting solution.
Claim 4
Dependent Claim
92 words
A process for developing an exposed black-and-white silver halide photographic material with an automatic developing machine, which comprises processing the black-and-white silver halide photographic material in a development starting solution and adding a development replenisher solution to the development starting solution, wherein each of said development starting solution and development replenisher solution comprises ascorbic acid and/or a derivative thereof and a carbonate in an amount of not less than 0.5 mol/l, and the development replenisher solution has a pH value of at least 0.3 higher than that of the development starting solution.
Claim 5
Dependent Claim
172 words
The process as in claim 1, wherein said development replenisher solution contains a silver stain inhibitor represented by formula (I) and/or (II) and the replenishment rate is not more than 300 ml/m 2 : ##STR22## wherein R 1 and R 2 each represent a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, a hydroxyl group, a mercapto group, a carboxyl group, a sulfo group, a phosphono group, a nitro group, a cyano group, a halogen atom, an alkoxycarbonyl group, an aryloxycarbonyl group, a carbamoyl group, a sulfamoyl group or an alkoxy group, provided that the sum of the number of carbon atoms contained in R 1 and R 2 is from 2 to 20; and R 1 and R 2 may be connected to each other to form a saturated cyclic structure; ##STR23## wherein X represents a hydrogen atom or a sulfonic group; M 1 represents a hydrogen atom or an alkaline metal atom; and M 2 represents a hydrogen atom, an alkaline metal atom or an ammonium group.
Claim 6
Dependent Claim
28 words
The process as in claim 1, wherein said development replenisher solution contains ascorbic acid and/or a derivative thereof in a range of 1 to 100 g per liter.
Claim 7
Dependent Claim
28 words
The process as in claim 2, wherein said development replenisher solution contains ascorbic acid and/or a derivative thereof in a range of 1 to 100 g per liter.
Claim 8
Dependent Claim
30 words
The process as in claim 3, wherein the development replenisher solution contains said silver stain inhibitor represented by formula (I) and/or (II) in a range of 0.01 to 50 mmol/l.
Claim 9
Dependent Claim
18 words
The process as in claim 1, wherein said development replenisher solution contains a 3-pyrazolidone or p-aminophenol developing agent.
Claim 10
Dependent Claim
33 words
The process as in claim 1, wherein the development replenisher solution is added to the development starting solution in an amount of not more than 300 ml/m 2 of the processed photographic material.
Claim 11
Dependent Claim
33 words
The process as in claim 2, wherein the development replenisher solution is added to the development starting solution in an amount of not more than 300 ml/m 2 of the processed photographic material.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1999-04-02 | 1999-10-02 | 2000-04-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2003-04-02 | 2003-10-02 | 2004-04-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2007-04-02 | 2007-10-02 | 2008-04-02 | $7700.00 | Window Closed / Lapsed |