Patent US5500306A successfully refreshed from Google Patents.
US5500306A
Expired / Lapsed
US
⏱️ 0.0 years remaining
High efficiency energy conversion and treatment of organic waste
Assignee: ZTEK Corp
•
Filing: 1993-10-06
•
Granted: 1996-03-19
•
Expires: 2013-10-06
Abstract
Abstract A system and method for converting organic material to electricity includes the steps of collecting a quantity of organic material, generating biogas from the material, and passing the biogas through an energy converter. Biogas is generated from the organic material by an anaerobic filter, and electricity is converted from the biogas by an energy converter, such as a high efficiency solid oxide fuel cell. To further increase the efficiency of the system, an anaerobic digester is used for treating a solid or sludge component of the organic material to generate additional biogas. In one embodiment of the invention, solar energy is used to maintain the anaerobic digester at an elevated temperature. Further efficiency enhancing measures include the recirculation of both the sludge and liquid components of the organic material to obtain additional biogas. After all of the biogas generating potential of the organic material has been utilized, the liquid component thereof is suitable for irrigation or discharge, while the solid component thereof is suitable for use as soil conditioner.
Inventors
- 👤 Michael S. Hsu
- 👤 Irvine W. Wei
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 11:13
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/06; H01M8/0606; H01M8/0612; C; C02; C02F; C02F3/00; C02F3/28; C02F3/2806; C05; C05F; C05F17/00; C05F3/00; H01M8/10; H01M8/12; H01M2008/1293; H01M2300/00; H01M2300/0017; H01M2300/0065; H01M2300/0068; H01M2300/0071; H01M2300/0074; Y; Y02; Y02A; Y02A40/00; Y02A40/10; Y02A40/20; Y02E; Y02E50/00; Y02E50/30; Y02E60/00; Y02E60/30; Y02E60/50; Y02P; Y02P20/00; Y02P20/10; Y02P20/133; Y02P20/141; Y02P20/145; Y02W; Y02W10/00; Y02W10/30; Y02W10/37; Y02W30/00; Y02W30/40
Claims Analysis
Total Claims: 39
Claim 1
Independent Claim
72 words
A method for high efficiency conversion of organic material to electricity, the method comprising the steps of collecting a quantity of organic material, generating an redefined biogas component containing sulfur from said collected quantity of organic material, and introducing the sulfur-containing unrefined biogas component into a high-temperature sulfur-tolerant fuel cell, the fuel cell converting the biogas component to electricity by an electrochemical process without significantly degrading the performance of the fuel cell.
Claim 2
Independent Claim
72 words
A method for high efficiency conversion of organic material to electricity, the method comprising the steps of collecting a quantity of organic material, generating an redefined biogas component containing sulfur from said collected quantity of organic material, and introducing the sulfur-containing unrefined biogas component into a high-temperature sulfur-tolerant fuel cell, the fuel cell converting the biogas component to electricity by an electrochemical process without significantly degrading the performance of the fuel cell.
Claim 3
Dependent Claim
19 words
A method as set forth in claim 1 wherein said generating step is performed by a biological treatment process.
Claim 4
Dependent Claim
17 words
A method as set forth in claim 2 wherein said biological treatment process involves an anaerobic filter.
Claim 5
Dependent Claim
50 words
A method as set forth in claim 1 further comprising, before said introducing step, the step of controlling the presence of sulfur in said biogas component by removing at least a portion of said sulfur from said biogas, such that said sulfur content in said biogas is below 10,000 ppm.
Claim 6
Dependent Claim
25 words
A method as set forth in claim 1 wherein the step of converting said biogas component to electricity is performed by a solid-oxide fuel cell.
Claim 7
Dependent Claim
50 words
A method as set forth in claim 1 further comprising the step of, prior to said generating step, separating a first liquid of said quantity of organic material from a solid component of said quantity of organic material, wherein a first biogas component is generated from said first liquid component.
Claim 8
Dependent Claim
53 words
A method as set forth in claim 6 further comprising the steps of generating a second biogas component from said solid component, further separating solid component into a second liquid component and a compost component, and mixing said second liquid component with said first liquid component prior to generating said first biogas component.
Claim 9
Dependent Claim
23 words
A method as set forth in claim 7 wherein said step of generating said second biogas component is performed by an anaerobic digester.
Claim 10
Dependent Claim
19 words
A method as set forth in claim 7 wherein said further separating step is performed by an anaerobic digester.
Claim 11
Dependent Claim
26 words
A method as set forth in claim 8 wherein said anaerobic digester is maintained at a temperature ranging from about 20 to about 55 degrees centigrade.
Claim 12
Dependent Claim
16 words
A method as set forth in claim 10 wherein said temperature is maintained by solar energy.
Claim 13
Independent Claim
74 words
A method for high efficiency conversion of organic material to electricity, the method comprising the steps of collecting a quantity of organic material, generating an unrefined biogas component containing sulfur from said collected quantity of organic material, applying said unrefined biogas component to a high-temperature sulfur-tolerant fuel cell, the fuel cell being operable on said sulfur-containing biogas component without significantly degrading the performance of said fuel cell, and converting the biogas component to electricity.
Claim 14
Independent Claim
74 words
A method for high efficiency conversion of organic material to electricity, the method comprising the steps of collecting a quantity of organic material, generating an unrefined biogas component containing sulfur from said collected quantity of organic material, applying said unrefined biogas component to a high-temperature sulfur-tolerant fuel cell, the fuel cell being operable on said sulfur-containing biogas component without significantly degrading the performance of said fuel cell, and converting the biogas component to electricity.
Claim 15
Dependent Claim
19 words
A method as set forth in claim 12 wherein said generating step is performed by a biological treatment process.
Claim 16
Dependent Claim
17 words
A method as set forth in claim 13 wherein said biological treatment process involves an anaerobic filter.
Claim 17
Dependent Claim
17 words
A method as set forth in claim 12 wherein said electrochemical converter is a solid-oxide fuel cell.
Claim 18
Dependent Claim
51 words
A method as set forth in claim 12 further comprising the step of, prior to said generating step, separating a first liquid component of said quantity of organic material from a solid component of said quantity of organic material, wherein a first biogas component is generated from said first liquid component.
Claim 19
Dependent Claim
54 words
A method as set forth in claim 16 further comprising the steps of generating a second biogas component from said solid component, further separating said solid component into a second liquid component and a compost component, and mixing said second liquid component with said first liquid component prior to generating said first biogas component.
Claim 20
Dependent Claim
28 words
A method as set forth in claim 17 wherein said step of generating said second biogas component and said further separating step is performed by an anaerobic digester.
Claim 21
Dependent Claim
28 words
A method as set forth in one of claim 18 wherein said anaerobic digester is maintained at a temperature ranging from about 20 to about 55 degrees centigrade.
Claim 22
Dependent Claim
16 words
A method as set forth in claim 19 wherein said temperature is maintained by solar energy.
Claim 23
Independent Claim
114 words
A method for high efficiency conversion of organic material to electricity, the method comprising the steps of separating a quantity of said organic material into a solid component and a liquid component, introducing said liquid component into an anaerobic filter to generate a first unrefined biogas component, anaerobically digesting said solid component of said organic material to produce a second unrefined biogas component, at least one of said first and second unrefined biogas components containing sulfur, introducing said first and second sulfur-containing unrefined biogas components into a high-temperature sulfur-tolerant fuel cell capable of converting said unrefined biogas component without significantly degrading the performance of the fuel cell, and converting said biogas components to electricity.
Claim 24
Independent Claim
114 words
A method for high efficiency conversion of organic material to electricity, the method comprising the steps of separating a quantity of said organic material into a solid component and a liquid component, introducing said liquid component into an anaerobic filter to generate a first unrefined biogas component, anaerobically digesting said solid component of said organic material to produce a second unrefined biogas component, at least one of said first and second unrefined biogas components containing sulfur, introducing said first and second sulfur-containing unrefined biogas components into a high-temperature sulfur-tolerant fuel cell capable of converting said unrefined biogas component without significantly degrading the performance of the fuel cell, and converting said biogas components to electricity.
Claim 25
Dependent Claim
49 words
A method according to claim 21 further comprising the steps of separating said solid component into a compost component and a second liquid component, and introducing said second liquid component into said anaerobic filter to produce an additional unrefined biogas component for conversion into electricity by said fuel cell.
Claim 26
Dependent Claim
23 words
A method according to claim 21 wherein said anaerobic digestion occurs at a temperature ranging from about 20° C. to about 55° C.
Claim 27
Dependent Claim
15 words
A method according to claim 21 wherein said temperature range is maintained by solar energy.
Claim 28
Dependent Claim
15 words
A method according to claim 21 wherein said fuel cell is a solid-oxide fuel cell.
Claim 29
Independent Claim
126 words
A method for high efficiency conversion of organic material to electricity, the method comprising the steps of thickening an initial quantity of organic material. separating said organic material into a sludge component and a first liquid component, introducing said liquid component into an anaerobic filter to generate a first unrefined biogas component and a processed liquid component, anaerobically digesting said sludge component of said organic material to produce a second unrefined biogas component, at least one of said first and second unrefined biogas components containing sulfur, introducing said first and second unrefined biogas components into a high-temperature sulfur-tolerant fuel cell, said fuel cell being operable on said sulfur-containing biogas components without significantly degrading the performance of said fuel cell, and convening said biogas components to electricity.
Claim 30
Independent Claim
126 words
A method for high efficiency conversion of organic material to electricity, the method comprising the steps of thickening an initial quantity of organic material. separating said organic material into a sludge component and a first liquid component, introducing said liquid component into an anaerobic filter to generate a first unrefined biogas component and a processed liquid component, anaerobically digesting said sludge component of said organic material to produce a second unrefined biogas component, at least one of said first and second unrefined biogas components containing sulfur, introducing said first and second unrefined biogas components into a high-temperature sulfur-tolerant fuel cell, said fuel cell being operable on said sulfur-containing biogas components without significantly degrading the performance of said fuel cell, and convening said biogas components to electricity.
Claim 31
Dependent Claim
38 words
A method according to claim 26 further comprising the steps of separating said anaerobically;digested sludge component into a compost component and a second liquid component, and introducing said second liquid component into said initial quantity of organic material.
Claim 32
Dependent Claim
66 words
A method according to claim 26 further comprising the steps of introducing said processed liquid component into a trickling filter to produce a filtered liquid component, introducing said filtered liquid component into a final clarifier to produce an effluent liquid and a second sludge component, and anaerobically digesting said second sludge component to produce an additional biogas component for conversion into electricity by said fuel cell.
Claim 33
Dependent Claim
27 words
A method according to claim 28 further comprising the step of recirculating said effluent liquid by introducing said effluent liquid to said trickling filter for further purification.
Claim 34
Dependent Claim
21 words
A method according to claim 29 wherein said effluent liquid is suitably low in biochemical oxygen demands and total suspended solids.
Claim 35
Dependent Claim
23 words
A method according to claim 26 wherein said anaerobic digestion occurs at a temperature ranging from about 20° C. to about 55° C.
Claim 36
Dependent Claim
15 words
A method according to claim 31 wherein said temperature range is maintained by solar energy.
Claim 37
Dependent Claim
34 words
A method according to claim 26 wherein said fuel cell is selected from a group consisting of solid oxide fuel cells, molten carbonate fuel cells, phosphoric acid fuel cells, and solid polymer fuel cells.
Claim 38
Independent Claim
76 words
A method for high efficiency conversion of organic material to electricity, the method comprising the steps of collecting a quantity of organic material, generating an unrefined biogas component containing sulfur from said collected quantity of organic material, and introducing the sulfur-containing unrefined biogas component into a high-temperature solid-oxide fuel cell, operable upon the sulfur-containing biogas component without permanently degrading the performance of the fuel cell to convert the biogas component to electricity by an electrochemical process.
Claim 39
Independent Claim
76 words
A method for high efficiency conversion of organic material to electricity, the method comprising the steps of collecting a quantity of organic material, generating an unrefined biogas component containing sulfur from said collected quantity of organic material, and introducing the sulfur-containing unrefined biogas component into a high-temperature solid-oxide fuel cell, operable upon the sulfur-containing biogas component without permanently degrading the performance of the fuel cell to convert the biogas component to electricity by an electrochemical process.
References Cited (Backward Citations)
US3466138A
Cited
US3841851A
Cited
US4302546A
Cited
US4248941A
Cited
US4614628A
Cited
US4565552A
Cited
US4750454A
Cited
US4638629A
Cited
US4714661A
Cited
EP0282473A1
Cited
DE3840517A1
Cited
US5094928A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1999-03-19 | 1999-09-18 | 2000-03-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2003-03-19 | 2003-09-18 | 2004-03-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2007-03-19 | 2007-09-18 | 2008-03-19 | $7700.00 | Window Closed / Lapsed |