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US5499121A Expired / Lapsed US ⏱️ 0.0 years remaining

Color variance polymer matrix display having two scattering states or N.sub.<or> both NE and NO

Assignee: Boit Inc
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Filing: 1993-03-18
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Granted: 1996-03-12
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Expires: 2013-03-18
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Abstract

Abstract Liquid crystal polymer matrix displays are disclosed, one of which is capable of changing from a first color to a second color and shades of color therebetween, and the other of which is capable of changing from a first color to a true colorless state and to lower intensities of said first color. Droplets of liquid crystal material containing a dye mixture comprising a positive order parameter dye and a negative order parameter dye, or a positive order parameter dye and a zero order parameter dye, or a negative order parameter dye and a zero order parameter dye, are dispersed in the polymer matrix. The color changes are attained by varying the magnitude of an electric field across the polymer matrix. The optic axes of the liquid crystal material can be partially of fully aligned in one direction during the curing of the polymer matrix thereby enhancing possible color changes.

Inventors

  • 👤 Donald R. Brewer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 21:16
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/01; G02F1/13; G02F1/137; G02F1/13725; G02F1/133; G02F1/1333; G02F1/1334

Claims Analysis

Total Claims: 39
Claim 1
Independent Claim 184 words
A color variance polymer dispersed liquid crystal display comprising: a polymer matrix; droplets of liquid crystal material dispersed in said polymer matrix, said liquid crystal material having optic axes uniformly aligned in one direction upon application of an electric field of sufficient magnitude to said polymer matrix; a mixture of dyes incorporated in said liquid crystal droplets such that the polymer matrix exhibits color changes ranging between a first color and a second color in response to changes in the magnitude of the electric field to said polymer matrix; wherein each index of refraction of said liquid crystal droplets is greater or less than the index of refraction of said polymer matrix; whereby said display will produce said first color in the absence of an electric field to said polymer matrix and said second color when an electric field of sufficient magnitude is applied to said polymer matrix; and whereby said display will produce shades of color between said first and second colors upon application of an electric field having a magnitude above zero and less than said sufficient magnitude to said polymer matrix.
Claim 2
Dependent Claim 184 words
A color variance polymer dispersed liquid crystal display comprising: a polymer matrix; droplets of liquid crystal material dispersed in said polymer matrix, said liquid crystal material having optic axes uniformly aligned in one direction upon application of an electric field of sufficient magnitude to said polymer matrix; a mixture of dyes incorporated in said liquid crystal droplets such that the polymer matrix exhibits color changes ranging between a first color and a second color in response to changes in the magnitude of the electric field to said polymer matrix; wherein each index of refraction of said liquid crystal droplets is greater or less than the index of refraction of said polymer matrix; whereby said display will produce said first color in the absence of an electric field to said polymer matrix and said second color when an electric field of sufficient magnitude is applied to said polymer matrix; and whereby said display will produce shades of color between said first and second colors upon application of an electric field having a magnitude above zero and less than said sufficient magnitude to said polymer matrix.
Claim 3
Dependent Claim 27 words
The color variance polymer liquid crystal display of claim 1 wherein said mixture of dyes comprises a positive order parameter dye and a negative order parameter dye.
Claim 4
Dependent Claim 27 words
The color variance polymer liquid crystal display of claim 1 wherein said mixture of dyes comprises a positive order parameter dye and a zero order parameter dye.
Claim 5
Dependent Claim 27 words
The color variance polymer liquid crystal display of claim 1 herein said mixture of dyes comprises a negative order parameter dye and a zero order parameter dye.
Claim 6
Dependent Claim 17 words
The color variance polymer liquid crystal display of claim 1 wherein said liquid crystal material is nematic.
Claim 7
Dependent Claim 19 words
The color variance polymer liquid crystal display of claim 1 wherein said liquid crystal material exhibits positive dielectric anisotropy.
Claim 8
Dependent Claim 19 words
The color variance polymer liquid crystal display of claim 1 wherein said liquid crystal material exhibits negative dielectric anisotropy.
Claim 9
Dependent Claim 36 words
The color variance polymer liquid crystal display of claim 1 wherein said liquid crystal material exhibits positive dielectric anisotropy or selectively negative dielectric anisotropy depending upon the frequency of a voltage applied across said polymer matrix.
Claim 10
Dependent Claim 21 words
The color variance polymer liquid crystal display of claim 1 wherein said polymer matrix is a resin, thermoplastic, epoxy or latex.
Claim 11
Dependent Claim 32 words
The color variance polymer liquid crystal display of claim 1 wherein said liquid crystal droplets have optic axes with random alignment in the absence of an electric field across said polymer matrix.
Claim 12
Dependent Claim 33 words
The color variance polymer liquid crystal display of claim 1 wherein said liquid crystal droplets have optic axes with at least partial alignment in the absence of electric field across said polymer matrix;
Claim 13
Dependent Claim 31 words
The color variance polymer liquid crystal display of claim 1 wherein said liquid crystal droplets have optic axes uniformly aligned in the absence of said electric field across said polymer matrix.
Claim 14
Dependent Claim 39 words
The color variance polymer liquid crystal display of claim 1 wherein the index of refraction of said polymer matrix is substantially close to all indexes of refraction of said liquid crystal droplets so as to produce two non-scattering states.
Claim 15
Dependent Claim 41 words
The color variance polymer liquid crystal display of claim 1 wherein the index of refraction of said polymer matrix and the indexes of refraction of said liquid crystal-droplets are such that said display produces a scattering state and a non-scattering state.
Claim 16
Dependent Claim 161 words
A color variance polymer matrix display comprising: a polymer matrix; droplets of liquid crystal material dispersed in said polymer matrix to produce two fully scattering states, said liquid crystals having optic axes uniformly aligned in one direction upon application of an electric field of sufficient magnitude to said polymer matrix; a mixture of dyes incorporated in said liquid crystal droplets such that the polymer matrix exhibits color changes ranging between a first color and a second color in response to changes in the magnitude of the electric field matrix; whereby said display will produce said first color in the absence of an electric field to said polymer matrix and said second color when an electric field of sufficient magnitude is applied to said polymer matrix; and whereby said display will produce shades of color between said first and second colors upon application of an electric field having a magnitude above zero and less than said sufficient magnitude to said polymer matrix.
Claim 17
Dependent Claim 161 words
A color variance polymer matrix display comprising: a polymer matrix; droplets of liquid crystal material dispersed in said polymer matrix to produce two fully scattering states, said liquid crystals having optic axes uniformly aligned in one direction upon application of an electric field of sufficient magnitude to said polymer matrix; a mixture of dyes incorporated in said liquid crystal droplets such that the polymer matrix exhibits color changes ranging between a first color and a second color in response to changes in the magnitude of the electric field matrix; whereby said display will produce said first color in the absence of an electric field to said polymer matrix and said second color when an electric field of sufficient magnitude is applied to said polymer matrix; and whereby said display will produce shades of color between said first and second colors upon application of an electric field having a magnitude above zero and less than said sufficient magnitude to said polymer matrix.
Claim 18
Dependent Claim 26 words
The color variance polymer matrix display of claim 15 wherein said mixture of dyes comprises a positive order parameter dye and a negative order parameter dye.
Claim 19
Dependent Claim 26 words
The color variance polymer matrix display of claim 15 wherein said mixture of dyes comprises a positive order parameter dye and a zero order parameter dye.
Claim 20
Dependent Claim 26 words
The color variance polymer matrix display of claim 15 wherein said mixture of dyes comprises a negative order parameter dye and a zero order parameter dye.
Claim 21
Dependent Claim 16 words
The color variance polymer matrix display of claim 15 wherein said liquid crystal material is nematic.
Claim 22
Dependent Claim 18 words
The color variance polymer matrix display of claim 15 wherein said liquid crystal material exhibits positive dielectric anisotropy.
Claim 23
Dependent Claim 18 words
The color variance polymer matrix display of claim 15 wherein said liquid crystal material exhibits negative dielectric anisotropy.
Claim 24
Dependent Claim 35 words
The color variance polymer matrix display of claim 15 wherein said liquid crystal material exhibits positive dielectric anisotropy or selectively negative dielectric anisotropy depending upon the frequency of a voltage applied across said polymer matrix.
Claim 25
Dependent Claim 20 words
The color variance polymer matrix display of claim 15 wherein said polymer matrix is a resin, thermoplastic, epoxy or latex.
Claim 26
Dependent Claim 206 words
A color modulating device changes from a first color to a true colorless state, said device comprising: a transparent superstrate; a substrate spaced from said superstrate, a polymer matrix interposed between and in contract with said superstrate and substrate; droplets of liquid crystal material dispersed in said polymer matrix, said liquid crystal material having optic axes uniformly aligned in one direction upon application of an electric field across said polymer matrix; a mixture of dyes incorporated in said liquid crystal droplets such that the polymer matrix exhibits color changes ranging between a first color and a true colorless state in response to changes in magnitude of said electric field; wherein each index of refraction of said liquid crystal droplets is greater or less than the index of refraction of said polymer matrix; whereby said display will produce said first color in the absence of an electric field across said polymer matrix and will attain a true colorless state when an electric field of sufficient magnitude is applied across said polymer matrix; and whereby said display will produce said color in reduced levels of intensity upon application of an electric field having a magnitude above zero and less than the said sufficient magnitude across said polymer matrix.
Claim 27
Dependent Claim 206 words
A color modulating device changes from a first color to a true colorless state, said device comprising: a transparent superstrate; a substrate spaced from said superstrate, a polymer matrix interposed between and in contract with said superstrate and substrate; droplets of liquid crystal material dispersed in said polymer matrix, said liquid crystal material having optic axes uniformly aligned in one direction upon application of an electric field across said polymer matrix; a mixture of dyes incorporated in said liquid crystal droplets such that the polymer matrix exhibits color changes ranging between a first color and a true colorless state in response to changes in magnitude of said electric field; wherein each index of refraction of said liquid crystal droplets is greater or less than the index of refraction of said polymer matrix; whereby said display will produce said first color in the absence of an electric field across said polymer matrix and will attain a true colorless state when an electric field of sufficient magnitude is applied across said polymer matrix; and whereby said display will produce said color in reduced levels of intensity upon application of an electric field having a magnitude above zero and less than the said sufficient magnitude across said polymer matrix.
Claim 28
Dependent Claim 24 words
The color modulating device of claim 24 wherein said mixture of dyes comprises a positive order parameter dye and a negative order parameter dye.
Claim 29
Dependent Claim 24 words
The color modulating device of claim 24 wherein said mixture of dyes comprises a positive order parameter dye and a zero order parameter dye.
Claim 30
Dependent Claim 24 words
The color modulating device of claim 24 wherein said mixture of dyes comprises a negative order parameter dye and a zero order parameter dye.
Claim 31
Dependent Claim 14 words
The color modulating device of claim 24 wherein said liquid crystal material is nematic.
Claim 32
Dependent Claim 16 words
The color modulating device of claim 24 wherein said liquid crystal material exhibits positive dielectric anisotropy.
Claim 33
Dependent Claim 16 words
The color modulating device of claim 24 wherein said liquid crystal material exhibits negative dielectric anisotropy.
Claim 34
Dependent Claim 32 words
The color modulating device of claim 24 wherein said liquid crystal material exhibits positive dielectric anisotropy or selectively negative dielectric anisotropy depending upon the frequency of a voltage applied across said electrodes.
Claim 35
Dependent Claim 36 words
The color modulating device of claim 24 wherein the index of refraction of said polymer matrix is substantially close to all indexes of refraction of said liquid crystal droplets so as to produce two non-scattering states.
Claim 36
Dependent Claim 39 words
The color modulating device of claim 24 wherein the index of refraction of said polymer matrix and the indexes of refraction of said liquid crystal droplets are such that said display produces a scattering state and a non-scattering state.
Claim 37
Dependent Claim 29 words
The color modulating device of claim 24 wherein said liquid crystal droplets have optic axes with random alignment in the absence of an electric field across said polymer matrix.
Claim 38
Dependent Claim 31 words
The color modulating device of claim 24 wherein said liquid crystal droplets have optic axes with at least partial alignment in the absence of an electric field across said polymer matrix.
Claim 39
Dependent Claim 28 words
The color modulating device of claim 24 wherein said liquid crystal droplets have optic axes uniformly aligned in the absence of said electric field across said polymer matrix.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-03-12 1999-09-11 2000-03-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-03-12 2003-09-11 2004-03-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-03-12 2007-09-11 2008-03-12 $7700.00 Window Closed / Lapsed

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