US4944576A
Expired / Lapsed
US
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Film with partial pre-alignment of polymer dispersed liquid crystals for electro-optical devices, and method of forming the same
Assignee: Victor Company of Japan Ltd
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Filing: 1988-03-21
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Granted: 1990-07-31
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Expires: 2008-03-21
Abstract
Abstract A polymer dispersed liquid crystal (PDLC) film, along with various fabrication methods that enable partial prealignment of the film's LC bubbles, are described. The film is formed with a matrix of liquid crystal bubbles. Individual liquid crystals within the bubbles are partially, but substantially less than fully, aligned in a given direction. Partial alignment is attained by the controlled application of an electric or magnetic field, or a mechanical flow, during photopolymerization. The resulting films retain the positive qualities of prior PDLCs, and in addition exhibit generally lower threshold and operating voltages, and can be used as tunable birefringent films in the infrared region.
Inventors
- 👤 Anna M. Lacker
- 👤 J. David Margerum
- 👤 Elena Ramos
- 👤 Willis H. Smith, Jr.
- 👤 Khoon C. Lim
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 00:05
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/52; C09K19/54; C09K19/542; C09K19/544; G; G02; G02F; G02F1/00; G02F1/01; G02F1/13; G02F1/133; G02F1/1333; G02F1/1334; Y; Y10; Y10S; Y10S359/00; Y10S359/90
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
104 words
A method for forming a polymer dispersed liquid crystal (LC) film, comprising: forming a solution of a LC dissolved in a polymerizable monomer system, polymerizing said solution to form a polymerized film having a dispersion of LC bubbles therein, causing the LC molecules within said bubbles to partially align in a predetermined direction during said polymerization, and controlling said direction of the LC molecules during polymerization so that substantially less than full alignment in said predetermined direction is achieved, thereby providing the film with a relatively low threshold voltage for optical transmission, and a relatively high optical contrast ratio over a predetermined voltage range.
Claim 2
Independent Claim
104 words
A method for forming a polymer dispersed liquid crystal (LC) film, comprising: forming a solution of a LC dissolved in a polymerizable monomer system, polymerizing said solution to form a polymerized film having a dispersion of LC bubbles therein, causing the LC molecules within said bubbles to partially align in a predetermined direction during said polymerization, and controlling said direction of the LC molecules during polymerization so that substantially less than full alignment in said predetermined direction is achieved, thereby providing the film with a relatively low threshold voltage for optical transmission, and a relatively high optical contrast ratio over a predetermined voltage range.
Claim 3
Dependent Claim
45 words
The method of claim 1, wherein said LC molecules are partially aligned within said bubbles by applying an electric field to said solution during polymerization, the field strength being sufficient to partially align but substantially less than that necessary to fully align the LC molecules.
Claim 4
Independent Claim
44 words
The method of claim wherein said LC molecules are partially aligned within said bubbles by applying a magnetic field to said solution during polymerization, the field strength being sufficient to partially align but substantially less than that necessary to fully align the LC molecules.
Claim 5
Dependent Claim
40 words
The method of claim 1, wherein said LC molecules are partially aligned within said bubbles by polymerizing said solution and simultaneously flowing it in a given direction with a flow sufficient to partially align the LC in the flow direction.
Claim 6
Dependent Claim
43 words
The method of claim 4, wherein the flow of the said solution during polymerization is obtained by placing the said solution between sheets, and squeezing the sheets together by passing them between a pair of opposed rollers as the solution is being polymerized.
Claim 7
Dependent Claim
98 words
The method of claim 1, the LC molecules comprising a crossover LC having a positive dielectric anisotropy below a crossover frequency and a negative dielectric anisotropy above said crossover frequency, wherein said LC molecules are partially aligned within said bubbles by applying an electric or magnetic AC field to said solution during polymerization, the field strength being sufficient to partially align but substantially less than that necessary to fully align the LC molecules , and the frequency of the applied field is selected relative to said crossover frequency in accordance with the desired operating characteristics for the film.
Claim 8
Independent Claim
92 words
A method of forming a polymer dispersed liquid crystal (LC) film having a birefringence that is tunable in accordance with the magnitude of a voltage applied across the film, comprising: forming a solution of a LC dissolved in a polymerizable monomer system, photopolymerizing said solution with ultraviolet light exposure to form a polymerized film having a dispersion of LC bubbles therein, and partially aligning the LC molecules within said bubbles in a predetermined direction so that the birefringence of the polymer dispersed LC film can be varied with an applied electrical field.
Claim 9
Independent Claim
92 words
A method of forming a polymer dispersed liquid crystal (LC) film having a birefringence that is tunable in accordance with the magnitude of a voltage applied across the film, comprising: forming a solution of a LC dissolved in a polymerizable monomer system, photopolymerizing said solution with ultraviolet light exposure to form a polymerized film having a dispersion of LC bubbles therein, and partially aligning the LC molecules within said bubbles in a predetermined direction so that the birefringence of the polymer dispersed LC film can be varied with an applied electrical field.
Claim 10
Dependent Claim
45 words
The method of claim 7, wherein said LC molecules are partially aligned within said bubbles by applying an electric field to said solution during polymerization, the field strength being sufficient to partially align but substantially less than that necessary to fully align the LC molecules.
Claim 11
Dependent Claim
45 words
The method of claim 7, wherein said LC molecules are partially aligned within said bubbles by applying a magnetic field to said solution during polymerization, the field strength being sufficient to partially align but substantially less than that necessary to fully align the LC molecules.
Claim 12
Dependent Claim
45 words
The method of claim 7, wherein said LC molecules are partially aligned within said bubbles by forming said solution in a sheet, and squeezing said sheet during polymerization sufficiently to cause said solution to flow and partially align the LC molecules in the flow direction.
Claim 13
Dependent Claim
19 words
The method of claim 10, wherein said sheet is compressed by passing it between a pair of opposed rollers.
Claim 14
Dependent Claim
96 words
The method of claim 6, the LC comprising a dual frequency LC having a positive dielectric anisotropy below a crossover frequency and a negative dielectric anisotropy above said crossover frequency, wherein said LC molecules are partially aligned within said bubbles by applying an electric or magnetic field to said solution during polymerization, the field strength being sufficient to partially align but substantially less than that necessary to fully align the LC molecules, and the frequency of the applied field is selected relative to said crossover frequency in accordance with the desired operating characteristics for the film.
Claim 15
Dependent Claim
90 words
A polymer dispersed liquid crystal (LC) film having improved threshold and operating voltage characteristics, comprising: a polymerized monomer system in the form of a film, and an array of LC bubbles dispersed through said system, said bubbles each comprising a plurality of LC molecules that are partially aligned in a predetermined direction, the degree of LC alignment being great enough to substantially reduce the voltage threshold for optical transmission through the film relative to nonaligned LC molecules, but less than that at which the film becomes transparent in the off-state.
Claim 16
Dependent Claim
90 words
A polymer dispersed liquid crystal (LC) film having improved threshold and operating voltage characteristics, comprising: a polymerized monomer system in the form of a film, and an array of LC bubbles dispersed through said system, said bubbles each comprising a plurality of LC molecules that are partially aligned in a predetermined direction, the degree of LC alignment being great enough to substantially reduce the voltage threshold for optical transmission through the film relative to nonaligned LC molecules, but less than that at which the film becomes transparent in the off-state.
Claim 17
Dependent Claim
21 words
The polymer dispersed LC film of claim 13, wherein the LC molecules are partially aligned generally parallel to the film plane.
Claim 18
Dependent Claim
21 words
The polymer dispersed LC film of claim 13, wherein the LC molecules are partially aligned generally perpendicular to the film plane.
References Cited (Backward Citations)
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