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US5498668A Expired / Lapsed US ⏱️ 0.0 years remaining

Blends of certain polyesters with acrylics

Assignee: Eastman Chemical Co
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Filing: 1994-10-31
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Granted: 1996-03-12
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Expires: 2014-10-31
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Abstract

Abstract This invention relates to a blend comprising: (A) an aliphatic or cycloaliphatic polyester or copolyester and (B) an acrylic polymer or copolymer.

Inventors

  • 👤 Christopher E. Scott

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 04:49
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 281 words
A two-phase blend comprising: (A) from 99% to 1% by weight of cycloaliphatic polyester or copolyester, and (B) from 1% to 99% by weight of an acrylic polymer or copolymer, wherein components (A) and (B) of said blend are selected from one of the following combinations: (1) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 90-50 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 10-50 mole % of 1,4-cyclohexanedimethanol; and (B) poly(methyl methacrylate); (2) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 40-1 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 60-99 mole % of 1,4-cyclohexanedimethanol; and (B) poly(cyclohexylmethacrylate); (3) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and a glycol selected from the group consisting of neopentyl glycol and ethylene glycol; and (B) poly(methyl methacrylate); (4) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 40-60 mole % 1,6-hexanediol and 60-40 mole % 1,8-octanediol; and (B) poly(methyl methacrylate); (5) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) poly(methyl methacrylate); (6) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) poly(methyl methacrylate) and methyl acrylate; (7) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) 65-85 mole % methyl acrylate and 35-15 mole % cyclohexyl methacrylate; and (8) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) 70-90 mole % butyl acrylate and 30-10 mole % styrene, and further wherein an article prepared from said blend is visually clear having a diffuse transmittance value of 40% or greater as determined by ASTM Method D1003.
Claim 2
Dependent Claim 281 words
A two-phase blend comprising: (A) from 99% to 1% by weight of cycloaliphatic polyester or copolyester, and (B) from 1% to 99% by weight of an acrylic polymer or copolymer, wherein components (A) and (B) of said blend are selected from one of the following combinations: (1) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 90-50 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 10-50 mole % of 1,4-cyclohexanedimethanol; and (B) poly(methyl methacrylate); (2) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 40-1 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 60-99 mole % of 1,4-cyclohexanedimethanol; and (B) poly(cyclohexylmethacrylate); (3) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and a glycol selected from the group consisting of neopentyl glycol and ethylene glycol; and (B) poly(methyl methacrylate); (4) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 40-60 mole % 1,6-hexanediol and 60-40 mole % 1,8-octanediol; and (B) poly(methyl methacrylate); (5) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) poly(methyl methacrylate); (6) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) poly(methyl methacrylate) and methyl acrylate; (7) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) 65-85 mole % methyl acrylate and 35-15 mole % cyclohexyl methacrylate; and (8) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) 70-90 mole % butyl acrylate and 30-10 mole % styrene, and further wherein an article prepared from said blend is visually clear having a diffuse transmittance value of 40% or greater as determined by ASTM Method D1003.
Claim 3
Dependent Claim 30 words
A blend according to claim 1 comprising: (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 90-50 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 10-50 mole % of 1,4-cyclohexanedimethanol; and (B) poly(methyl methacrylate).
Claim 4
Dependent Claim 29 words
A blend according to claim 1 comprising: (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 40-1 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 60-99 mole % of 1,4-cyclohexanedimethanol; and (B) poly(cyclohexylmethacrylate).
Claim 5
Dependent Claim 32 words
A blend according to claim 1 comprising: (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and a glycol selected from the group consisting of neopentyl glycol and ethylene glycol; and (B) poly(methyl methacrylate).
Claim 6
Dependent Claim 28 words
A blend according to claim 1 comprising: (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 40-60 mole % 1,6-hexanediol and 60-40 mole % 1,8-octanediol; and (B) poly(methyl methacrylate).
Claim 7
Dependent Claim 29 words
A blend according to claim 1 comprising: (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) poly(methyl methacrylate).
Claim 8
Dependent Claim 32 words
A blend according to claim 1 comprising: (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) poly(methyl methacrylate) and methyl acrylate.
Claim 9
Dependent Claim 37 words
A blend according to claim 1 comprising: (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) 65-85 mole % methyl acrylate and 35-15 mole % cyclohexylmethacrylate.
Claim 10
Dependent Claim 37 words
A blend according to claim 1 comprising: (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) 70-90 mole % butyl acrylate and 30-10 mole % styrene.
Claim 11
Dependent Claim 34 words
The blend according to claim 1 wherein Component (A) is present in the amount of 85% to 20% by weight and Component (B) is present in the amount of 15% to 80% by weight.
Claim 12
Dependent Claim 34 words
The blend according to claim 10 wherein Component (A) is present in the amount of 60% to 40% by weight and Component (B) is present in the amount of 40% to 60% by weight.
Claim 13
Dependent Claim 25 words
The blend according to claim 1 wherein said absolute value of the difference in refractive indices for Components (A) and (B) is 0.006 or less.
Claim 14
Dependent Claim 26 words
The blend according to claim 12 wherein the absolute value of the difference in refractive indices for Components (A) and (B) is less than about 0.008.
Claim 15
Dependent Claim 11 words
A thermoplastic molding composition comprising the blend according to claim 1.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-03-12 1999-09-11 2000-03-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-03-12 2003-09-11 2004-03-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-03-12 2007-09-11 2008-03-12 $7700.00 Window Closed / Lapsed

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