US5472991A
Expired / Lapsed
US
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Two-stage photocuring process for a dental composition
Assignee: 3M Deutschland GmbH
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Filing: 1994-07-21
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Granted: 1995-12-05
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Expires: 2014-07-21
Abstract
Abstract The invention relates to photopolymerizable dental compositions of ethylenically unsaturated monomers and/or polymers thereof which are curable in two curing steps. Besides being comprised of fillers, said compositions also contain a photoinitiator component I having a light absorption maximum of <450 nm and a molar extinction of the light absorption of <10 at wavelengths of 470 nm or higher, and a photoinitiator component II having a molar extinction of the light absorption of >20 at least at one wavelength of at least >450 nm.
Inventors
- 👤 Werner Schmitt
- 👤 Peter Jochum
- 👤 Klaus Ellrich
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 22:31
CPC Classifications
A; A61; A61K; A61K6/00; A61K6/60; A61K6/62; Y; Y10; Y10S; Y10S522/00; Y10S522/908; Y10S522/913
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
193 words
A process for curing a photocurable dental composition comprising: first irradiating said dental composition comprising: (a) 5 to 70% by weight based on the weight of and (b), of an ethylenically unsaturated polymerizable monomer, an unsaturated polymer of said monomer or a mixture thereof, wherein said ethylenically unsaturated polymerizable monomer is an acrylate or a methacrylate, (b) 30 to 95% by weight, based on the weight of (a) and (b), of fillers, (c) 0.05 to 3% by weight, based on the weight of (a), of a photoinitiator (I) having a light absorption maximum of <450 nm and a molar extinction coefficient of <10 at wavelengths of 470 nm or higher, (d) 0.05 to 3% by weight, based on the weight of (a), of a photoinitiator (II) having a molar extinction coefficient of >20 at a wavelength of >450 nm, and (e) optionally pigments, X-ray-opaque additives, thixotropy adjuvants or mixtures thereof; with light of wavelengths >450 nm to effect partial curing of said dental composition to between 50 and 70% of its maximum hardness; and subsequently irradiating said dental composition with light including wavelengths <450 nm to effect complete curing of said dental composition.
Claim 2
Dependent Claim
193 words
A process for curing a photocurable dental composition comprising: first irradiating said dental composition comprising: (a) 5 to 70% by weight based on the weight of and (b), of an ethylenically unsaturated polymerizable monomer, an unsaturated polymer of said monomer or a mixture thereof, wherein said ethylenically unsaturated polymerizable monomer is an acrylate or a methacrylate, (b) 30 to 95% by weight, based on the weight of (a) and (b), of fillers, (c) 0.05 to 3% by weight, based on the weight of (a), of a photoinitiator (I) having a light absorption maximum of <450 nm and a molar extinction coefficient of <10 at wavelengths of 470 nm or higher, (d) 0.05 to 3% by weight, based on the weight of (a), of a photoinitiator (II) having a molar extinction coefficient of >20 at a wavelength of >450 nm, and (e) optionally pigments, X-ray-opaque additives, thixotropy adjuvants or mixtures thereof; with light of wavelengths >450 nm to effect partial curing of said dental composition to between 50 and 70% of its maximum hardness; and subsequently irradiating said dental composition with light including wavelengths <450 nm to effect complete curing of said dental composition.
Claim 3
Dependent Claim
29 words
The process according to claim 1, further comprising the step of removing excess amounts of said dental composition after said first irradiation step, but before said subsequent irradiation step.
Claim 4
Dependent Claim
31 words
The process according to claim 1, wherein said photoinitiator (II) and any activators therefor, are selected such that the surface hardness of said dental composition after partial curing is <200 MPa.
Claim 5
Dependent Claim
13 words
The process according to claim 3, wherein said photoinitiator (II) is an α-diketone.
Claim 6
Dependent Claim
12 words
The process according to claim 4, wherein said photoinitiator is camphor quinone.
Claim 7
Dependent Claim
19 words
The process according to claim 1, wherein said photoinitiator (I) has an absorption maximum from 360 to 410 nm.
Claim 8
Dependent Claim
19 words
The process according to claim 6, wherein said photoinitiator (I) has a molar extinction coefficient >25 at 400 nm.
Claim 9
Dependent Claim
14 words
The process according to claim 7, wherein said photoinitiator (I) is a bisacylphosphine oxide.
Claim 10
Dependent Claim
163 words
The process according to claim 8, wherein said bisacylphosphine oxide is represented by the formula: ##STR2## wherein R 1 is a straight-chain or branched C 1-18 -alkyl radical, a cyclohexyl, cyclopentyl, phenyl, naphthyl or biphenylyl radical; a cyclohexyl, cyclopentyl, phenyl, naphthyl or biphenylyl radical substituted with F, Cl, Br, I, C 1 -C 12 -alkyl, C 1 -C 12 -alkoxyl, or mixtures thereof; a S or N containing 5-membered or 6-membered heterocyclic ring, and R 2 and R 3 , which may be identical or different, each represents a cyclohexyl, cyclopentyl, phenyl, naphthyl, or biphenylyl radical; a cyclopentyl, cyclohexyl, phenyl, naphthyl, or biphenylyl radical substituted with F, Cl, Br, I, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxyl, or mixtures thereof; a S or N containing 5-membered or 6-membered heterocyclic ring; or R 2 and R 3 are joined to form a ring containing from 4 to 10 carbon atoms and optionally substituted by 1 to 6 C 1-4 -alkyl radicals.
Claim 11
Dependent Claim
46 words
The process according to claim 1, wherein the wavelengths of said first irradiation step are obtained by filtering out light with wavelengths <450 nm with a suitable optical cut-off filter and the wavelengths of said subsequent irradiation step are obtained by omitting said optical cutoff filter.
Claim 12
Dependent Claim
232 words
A process of preparing a dental tooth filling, said method comprising the steps of: Step 1) providing a two-stage curable dental composition comprising: (a) 5 to 70% by weight based on the weight of (a) and (b), of an ethylenically unsaturated polymerizable monomer, an unsaturated polymer of said monomer or a mixture thereof, wherein said ethylenically unsaturated polymerizable monomer is an acrylate or a methacrylate, (b) 30 to 95% by weight, based on the weight of (a) and (b), of fillers, (c) 0.05 to 3% by weight, based on the weight of (a), of a photoinitiator (I) having a light absorption maximum of <450 nm and a molar extinction coefficient of <10 at wavelengths of 470 nm or higher, (d) 0.05 to 3% by weight, based on the weight of (a), of a photoinitiator (II) having a molar extinction coefficient of >20 at a wavelength of >450 nm, and (e) optionally pigments, X-ray-opaque additives, thixotropy adjuvants or mixtures thereof; Step 2) shaping the dental composition to the desired shape; Step 3) irradiating said dental composition with light of wavelengths >450 nm, thus obtaining a partially-cured dental composition, with up to 70% of its maximum hardness; Step 4) removing any excess amount of said dental composition with carving tools; Step 5) irradiating said remaining dental compositions with light including wavelengths <450 nm, to obtain a fully-cured, dental tooth filling at its final hardness.
Claim 13
Dependent Claim
232 words
A process of preparing a dental tooth filling, said method comprising the steps of: Step 1) providing a two-stage curable dental composition comprising: (a) 5 to 70% by weight based on the weight of (a) and (b), of an ethylenically unsaturated polymerizable monomer, an unsaturated polymer of said monomer or a mixture thereof, wherein said ethylenically unsaturated polymerizable monomer is an acrylate or a methacrylate, (b) 30 to 95% by weight, based on the weight of (a) and (b), of fillers, (c) 0.05 to 3% by weight, based on the weight of (a), of a photoinitiator (I) having a light absorption maximum of <450 nm and a molar extinction coefficient of <10 at wavelengths of 470 nm or higher, (d) 0.05 to 3% by weight, based on the weight of (a), of a photoinitiator (II) having a molar extinction coefficient of >20 at a wavelength of >450 nm, and (e) optionally pigments, X-ray-opaque additives, thixotropy adjuvants or mixtures thereof; Step 2) shaping the dental composition to the desired shape; Step 3) irradiating said dental composition with light of wavelengths >450 nm, thus obtaining a partially-cured dental composition, with up to 70% of its maximum hardness; Step 4) removing any excess amount of said dental composition with carving tools; Step 5) irradiating said remaining dental compositions with light including wavelengths <450 nm, to obtain a fully-cured, dental tooth filling at its final hardness.
Claim 14
Dependent Claim
171 words
The method of claim 11, wherein in the two-stage curable dental composition: the photoinitiator (I) comprises a bisacylphosphine oxide of the general formula: ##STR3## wherein R 1 is a straight-chain or branched C 1-18 -alkyl radical, a cyclohexyl, cyclopentyl, phenyl, naphthyl or biphenylyl radical; a cyclohexyl, cyclopentyl, phenyl, naphthyl or biphenylyl radical substituted with F, Cl, Br, I, C 1 -C 12 -alkyl, C 1 -C 12 -alkoxyl, or mixtures thereof; a S or N containing 5-membered or 6-membered heterocyclic ring, and R 2 and R 3 , which may be identical or different, each represents a cyclohexyl, cyclopentyl, phenyl, naphthyl, or biphenylyl radical; a cyclopentyl, cyclohexyl, phenyl, naphthyl, or biphenylyl radical substituted with F, Cl, Br, I, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxyl, or mixtures thereof; a S or N containing 5-membered or 6-membered heterocyclic ring; or R 2 and R 3 are joined to form a ring containing from 4 to 10 carbon atoms and optionally substituted by 1 to 6 C 1-4 -alkyl radicals.
Claim 15
Dependent Claim
234 words
A process for mounting sufficiently transparent dental inlays, onlays and facing shells, comprising the following steps: Step 1) fastening said inlay, onlay or facing shell to a tooth with a composition comprising; (a) 5 to 70% by weight based on the weight of (a) and (b), of an ethylenically unsaturated polymerizable monomer, a polymer of said monomer or a mixture thereof, wherein said ethylenically unsaturated polymerizable monomer is an acrylate or a methacrylate, (b) 30 to 95% by weight, based on the weight of (a) and (b), of fillers, (c) 0.05 to 3% by weight, based on the weight of (a), of a photoinitiator (I) having a light absorption maximum of <450 nm and a molar extinction coefficient of <10 at wavelengths of 470 nm or higher, (d) 0.05 to 3% by weight, based on the weight of (a), of a photoinitiator (II) having a molar extinction coefficient of >20 at a wavelength of >450 nm, and (e) optionally pigments, X-ray-opaque additives, thixotropy adjuvants or mixtures thereof; Step 2) irradiating the composition in a first curing step with light of wavelengths >450 nm, forming a resultant mounted product; Step 3) carving any excess composition from the rim of the mounted product with carving instruments, to form a finished product; and Step 4) irradiating the finished product in a final curing step with light including wavelengths <450 nm, securing the finished product to the tooth.
Claim 16
Dependent Claim
234 words
A process for mounting sufficiently transparent dental inlays, onlays and facing shells, comprising the following steps: Step 1) fastening said inlay, onlay or facing shell to a tooth with a composition comprising; (a) 5 to 70% by weight based on the weight of (a) and (b), of an ethylenically unsaturated polymerizable monomer, a polymer of said monomer or a mixture thereof, wherein said ethylenically unsaturated polymerizable monomer is an acrylate or a methacrylate, (b) 30 to 95% by weight, based on the weight of (a) and (b), of fillers, (c) 0.05 to 3% by weight, based on the weight of (a), of a photoinitiator (I) having a light absorption maximum of <450 nm and a molar extinction coefficient of <10 at wavelengths of 470 nm or higher, (d) 0.05 to 3% by weight, based on the weight of (a), of a photoinitiator (II) having a molar extinction coefficient of >20 at a wavelength of >450 nm, and (e) optionally pigments, X-ray-opaque additives, thixotropy adjuvants or mixtures thereof; Step 2) irradiating the composition in a first curing step with light of wavelengths >450 nm, forming a resultant mounted product; Step 3) carving any excess composition from the rim of the mounted product with carving instruments, to form a finished product; and Step 4) irradiating the finished product in a final curing step with light including wavelengths <450 nm, securing the finished product to the tooth.
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