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US5472831A Expired / Lapsed US ⏱️ 0.0 years remaining

Silver halide photographic material

Assignee: Fujifilm Corp
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Filing: 1994-10-03
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Granted: 1995-12-05
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Expires: 2014-10-03
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Abstract

Abstract A silver halide light-sensitive material is described, including an embodiment containing a polyester film support having thereon at least one light-sensitive layer, wherein the polyester film support satisfies the following relationships: Tg≦32.1A.sup.2 +55 X≧-0.74Tg+71.7 wherein Tg is a glass transition temperature (°C.); A is an equivalent water content (%) after moisture conditioning at 25° C. and 50% RH for 10 days; and X is a degree of crystallinity.

Inventors

  • 👤 Yosuke Nishiura
  • 👤 Yukio Shinagawa
  • 👤 Kiyokazu Hashimoto
  • 👤 Junichi Yamanouchi
  • 👤 Yasuo Mukunoki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 23:32
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/795; G03C1/7954; G03B; G03B2217/00; G03B2217/26; G03B2217/265; G03C11/00; G03C11/02; G03C2200/00; G03C2200/10; G03C3/00; Y; Y10; Y10S; Y10S430/00; Y10S430/131; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31786

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 188 words
A silver halide photographic material comprising on a polyester film support at least one light-sensitive layer, wherein said polyester film support satisfies the following relationships: Tg≦32.1A.sup.2 +55 X≧31 0.74Tg+71.7 wherein Tg is glass transition temperature (°C.); A is equilibrium water content (%) after moisture conditioning at 25° C. and 50% RH for 10 days; and X is degree of crystallinity; wherein said silver halide photographic material further comprises on at least one side of the support a magnetic recording layer containing a ferromagnetic powder in an amount of 4×10 -3 to 1 g per m 2 of the support and having a coercive force of not less than 400 Oe coated over the surface of said side or coated in stripes, and said silver halide photographic material is a roll film in a cartridge system wherein the end of the roll film wound around a spool is fed out of a cartridge body from a film outlet by turning the spool rotatably attached to the cartridge body in the film feed direction; and wherein a pair of ribs are provided on the inner side of the cartridge body.
Claim 2
Dependent Claim 188 words
A silver halide photographic material comprising on a polyester film support at least one light-sensitive layer, wherein said polyester film support satisfies the following relationships: Tg≦32.1A.sup.2 +55 X≧31 0.74Tg+71.7 wherein Tg is glass transition temperature (°C.); A is equilibrium water content (%) after moisture conditioning at 25° C. and 50% RH for 10 days; and X is degree of crystallinity; wherein said silver halide photographic material further comprises on at least one side of the support a magnetic recording layer containing a ferromagnetic powder in an amount of 4×10 -3 to 1 g per m 2 of the support and having a coercive force of not less than 400 Oe coated over the surface of said side or coated in stripes, and said silver halide photographic material is a roll film in a cartridge system wherein the end of the roll film wound around a spool is fed out of a cartridge body from a film outlet by turning the spool rotatably attached to the cartridge body in the film feed direction; and wherein a pair of ribs are provided on the inner side of the cartridge body.
Claim 3
Dependent Claim 21 words
A silver halide photographic material as in claim 1, wherein said polyester film support comprises a polyester having a hydrophilic group.
Claim 4
Dependent Claim 102 words
A silver halide photographic material as in claim 2, wherein said polyester having a hydrophilic group is obtained by reacting a dibasic acid and a glycol, wherein the hydrophilic group in said polyester having a hydrophilic group is present in either of the dibasic acid or the glycol, and the hydrophilic group is selected from the group consisting of a sulfo group, a sulfino group, a phosphono group, a carboxyl group, a salt of a sulfo group, a salt of a sulfino group, a salt of a phosphono group, a salt of a carboxyl group, a polyalkyleneoxy group, and a disulfonamido group.
Claim 5
Dependent Claim 67 words
A silver halide photographic material as in claim 1, wherein said cartridge system satisfies the equation 2mm≧b/2-a/2-c·d-t wherein a is the outer diameter of said spool, b is the inner diameter of said cartridge body, t is the thickness of a rib on the inner side of said cartridge body, c is the thickness of said film, and d is the number of turns of said film.
Claim 6
Dependent Claim 226 words
A silver halide photographic material comprising on a polyester film support at least one photographic layer, wherein said polyester film support satisfies the following relationships: Tg≦32.1A.sup.2 +55 X≧-0.74Tg+71.7 S≧13 T≦0.25 K≧80 wherein Tg is glass transition temperature (°C.); A is equilibrium water content (%) after moisture conditioning at 25° C. and 50% RH for 10 days; X is degree of crystallinity; S is stiffness (g) with a thickness of 70 μm; T is average percent thermal resistance (%) in the transverse direction and the machine direction; and K is percent transmission (%) at a wavelength of 400 nm; wherein said silver halide photographic material further comprises on at least one side of the support a magnetic recording layer containing a ferromagnetic powder in an amount of 4×10 -3 to 1 g per m 2 of the support and having a coercive force of not less than 400 Oe coated over the surface of said side or coated in stripes, and said silver halide photographic material is a roll film in a cartridge system wherein the end of the roll film wound around a spool is fed out of a cartridge body from a film outlet by turning the spool rotatably attached to the cartridge body in the film feed direction; and wherein a pair of ribs are provided on the inner side of the cartridge body.
Claim 7
Dependent Claim 226 words
A silver halide photographic material comprising on a polyester film support at least one photographic layer, wherein said polyester film support satisfies the following relationships: Tg≦32.1A.sup.2 +55 X≧-0.74Tg+71.7 S≧13 T≦0.25 K≧80 wherein Tg is glass transition temperature (°C.); A is equilibrium water content (%) after moisture conditioning at 25° C. and 50% RH for 10 days; X is degree of crystallinity; S is stiffness (g) with a thickness of 70 μm; T is average percent thermal resistance (%) in the transverse direction and the machine direction; and K is percent transmission (%) at a wavelength of 400 nm; wherein said silver halide photographic material further comprises on at least one side of the support a magnetic recording layer containing a ferromagnetic powder in an amount of 4×10 -3 to 1 g per m 2 of the support and having a coercive force of not less than 400 Oe coated over the surface of said side or coated in stripes, and said silver halide photographic material is a roll film in a cartridge system wherein the end of the roll film wound around a spool is fed out of a cartridge body from a film outlet by turning the spool rotatably attached to the cartridge body in the film feed direction; and wherein a pair of ribs are provided on the inner side of the cartridge body.
Claim 8
Dependent Claim 21 words
A silver halide photographic material as in claim 5, wherein said polyester film support comprises a polyester having a hydrophilic group.
Claim 9
Dependent Claim 102 words
A silver halide photographic material as in claim 6, wherein said polyester having a hydrophilic group is obtained by reacting a dibasic acid and a glycol, wherein the hydrophilic group in said polyester having a hydrophilic group is present in either of the dibasic acid or the glycol, and the hydrophilic group is selected from the group consisting of a sulfo group, a sulfino group, a phosphono group, a carboxyl group, a salt of a sulfo group, a salt of a sulfino group, a salt of a phosphono group, a salt of a carboxyl group, a polyalkyleneoxy group, and a disulfonamido group.
Claim 10
Dependent Claim 67 words
A silver halide photographic material as in claim 5, wherein said cartridge system satisfies the equation 2mm≧b/2-a/2-c·d-t wherein a is the outer diameter of said spool, b is the inner diameter of said cartridge body, t is the thickness of a rib on the inner side of said cartridge body, c is the thickness of said film, and d is the number of turns of said film.
Claim 11
Dependent Claim 149 words
A silver halide photographic material comprising on a polyester film support at least one light-sensitive layer, wherein said polyester film support comprises a mixture of (i) polyethylene terephthalate and (ii) a polyester having a hydrophilic group; and wherein said silver halide photographic material further comprises on at least one side of the support a magnetic recording layer containing a ferromagnetic powder in an amount of 4×10 -3 to 1 g per m 2 of the support and having a coercive force of not less than 400 Oe coated over the surface of said side or coated in stripes, and said silver halide photographic material is a roll film in a cartridge system wherein the end of the roll film wound around a spool is fed out of a cartridge body from a film outlet by turning the spool rotatably attached to the cartridge body in the film feed direction.
Claim 12
Dependent Claim 149 words
A silver halide photographic material comprising on a polyester film support at least one light-sensitive layer, wherein said polyester film support comprises a mixture of (i) polyethylene terephthalate and (ii) a polyester having a hydrophilic group; and wherein said silver halide photographic material further comprises on at least one side of the support a magnetic recording layer containing a ferromagnetic powder in an amount of 4×10 -3 to 1 g per m 2 of the support and having a coercive force of not less than 400 Oe coated over the surface of said side or coated in stripes, and said silver halide photographic material is a roll film in a cartridge system wherein the end of the roll film wound around a spool is fed out of a cartridge body from a film outlet by turning the spool rotatably attached to the cartridge body in the film feed direction.
Claim 13
Dependent Claim 102 words
A silver halide photographic material as in claim 9, wherein said polyester having a hydrophilic group is obtained by reacting a dibasic acid and a glycol, wherein the hydrophilic group in said polyester having a hydrophilic group is present in either of the dibasic acid or the glycol, and the hydrophilic group is selected from the group consisting of a sulfo group, a sulfino group, a phosphono group, a carboxyl group, a salt of a sulfo group, a salt of a sulfino group, a salt of a phosphono group, a salt of a carboxyl group, a polyalkyleneoxy group, and a disulfonamido group.
Claim 14
Dependent Claim 168 words
A silver halide photographic material comprising on a polyester film support at least one light-sensitive layer, wherein said polyester film support is a laminate film composed of at least one layer comprising a polyester having a Tg of not lower than 63° C. and at least one layer comprising a polyester having a hydrophilic group; and wherein said silver halide photographic material further comprises on at least one side of the support a magnetic recording layer containing a ferromagnetic powder in an amount of 4×10 -3 to 1 g per m 2 of the support and having a coercive force of not less than 400 Oe coated over the surface of said side or coated in stripes, and said silver halide photographic material is a roll film in a cartridge system wherein the end of the roll film wound around a spool is fed out of a cartridge body from a film outlet by turning the spool rotatably attached to the cartridge body in the film feed direction.
Claim 15
Dependent Claim 168 words
A silver halide photographic material comprising on a polyester film support at least one light-sensitive layer, wherein said polyester film support is a laminate film composed of at least one layer comprising a polyester having a Tg of not lower than 63° C. and at least one layer comprising a polyester having a hydrophilic group; and wherein said silver halide photographic material further comprises on at least one side of the support a magnetic recording layer containing a ferromagnetic powder in an amount of 4×10 -3 to 1 g per m 2 of the support and having a coercive force of not less than 400 Oe coated over the surface of said side or coated in stripes, and said silver halide photographic material is a roll film in a cartridge system wherein the end of the roll film wound around a spool is fed out of a cartridge body from a film outlet by turning the spool rotatably attached to the cartridge body in the film feed direction.
Claim 16
Dependent Claim 102 words
A silver halide photographic material as in claim 11, wherein said polyester having a hydrophilic group is obtained by reacting a dibasic acid and a glycol, wherein the hydrophilic group in said polyester having a hydrophilic group is present in either of the dibasic acid or the glycol, and the hydrophilic group is selected from the group consisting of a sulfo group, a sulfino group, a phosphono group, a carboxyl group, a salt of a sulfo group, a salt of a sulfino group, a salt of a phosphono group, a salt of a carboxyl group, a polyalkyleneoxy group, and a disulfonamido group.
Claim 17
Dependent Claim 41 words
A silver halide photographic material as in claim 11, wherein said at least one layer comprising a polyester having a hydrophilic is present within a depth of 20 μm from the surface of at least one side of said laminate film.
Claim 18
Dependent Claim 75 words
A silver halide photographic material as in claim 11, wherein said at least one layer comprising a polyester having a hydrophilic group is laminated on both sides of said layer comprising a polyester having a Tg of not lower than 63° C., and said at least one layer comprising a polyester having a hydrophilic group is present within a depth of 20 μm from the surface of at least one side of said laminate film.
Claim 19
Dependent Claim 172 words
A silver halide photographic material comprising on a polyester film support at least one light-sensitive layer, wherein said support comprises polyester which is obtained by reacting a dibasic acid and a glycol, wherein either the dibasic acid or the glycol has a hydrophilic group, said silver halide photographic material further comprising on at least one side of the support a magnetic recording layer containing a ferromagnetic powder in an amount of from 4×10 -3 to 1 g per m 2 of the support and having a coercive force of not less than 400 Oe either coated over the surface of said side or coated in stripes, and said silver halide photographic material is a roll film in a cartridge system wherein the end of the roll film wound around a spool is fed out of a cartridge body from a film outlet by turning the spool rotatably attached to the cartridge body in the film feed direction; wherein a pair of ribs are provided on the inner side of the cartridge body.
Claim 20
Dependent Claim 172 words
A silver halide photographic material comprising on a polyester film support at least one light-sensitive layer, wherein said support comprises polyester which is obtained by reacting a dibasic acid and a glycol, wherein either the dibasic acid or the glycol has a hydrophilic group, said silver halide photographic material further comprising on at least one side of the support a magnetic recording layer containing a ferromagnetic powder in an amount of from 4×10 -3 to 1 g per m 2 of the support and having a coercive force of not less than 400 Oe either coated over the surface of said side or coated in stripes, and said silver halide photographic material is a roll film in a cartridge system wherein the end of the roll film wound around a spool is fed out of a cartridge body from a film outlet by turning the spool rotatably attached to the cartridge body in the film feed direction; wherein a pair of ribs are provided on the inner side of the cartridge body.
Claim 21
Dependent Claim 82 words
A silver halide photographic material as in claim 15, wherein said polyester film support is a laminate film composed of at least one layer comprising the polyester having a hydrophilic group is laminated on both sides of a polyester layer having a Tg of not lower than 63° C., and said at least one layer comprising the polyester having a hydrophilic group is present within a depth of 20 μm from the surface of at least one side of said laminate film.
Claim 22
Dependent Claim 55 words
A silver halide photographic material as in claim 16, wherein (i) the dibasic acid comprises a benzene ring or a naphthalene ring, and a carboxyl group, a sulfo group, a sulfino group, a phosphonic acid group, a salt of any of these groups, or a hydroxyl group, and (ii) the glycol comprises polyoxyalkylene or polyoxyglycerin.
Claim 23
Dependent Claim 56 words
A silver halide photographic material as in claim 15, wherein (i) the dibasic acid comprises a benzene ring or a naphthalene ring, and a carboxyl group, a sulfo group, a sulfino group, a phosphonic acid group, a salt of any of these groups, or a hydroxyl group, and (ii) the glycol component comprises polyoxyalkylene or polyoxyglycerin.
Claim 24
Dependent Claim 67 words
A silver halide photographic material as in claim 15, wherein said cartridge system satisfied the equation 2mm≧b/2-a/2-c·d-t wherein a is the outer diameter of said spool, b is the inner diameter of said cartridge body, t is the thickness of a rib on the inner side of said cartridge body, c is the thickness of said film, and d is the number of turns of said film.
Claim 25
Dependent Claim 98 words
A silver halide photographic material comprising on a polyester film support at least one light-sensitive layer, wherein said support comprises polyester which comprises a mixture of (i) polyethylene terephthalate and (ii) a polyester having a hydrophilic group, said silver halide photographic material further comprising on at least one side of the support a magnetic recording layer containing a ferromagnetic powder in an amount of from 4×10 -3 to 1 g per m 2 of the support and having a coercive force of not less than 400 Oe coated over the surface of said side or coated in stripes.
Claim 26
Dependent Claim 98 words
A silver halide photographic material comprising on a polyester film support at least one light-sensitive layer, wherein said support comprises polyester which comprises a mixture of (i) polyethylene terephthalate and (ii) a polyester having a hydrophilic group, said silver halide photographic material further comprising on at least one side of the support a magnetic recording layer containing a ferromagnetic powder in an amount of from 4×10 -3 to 1 g per m 2 of the support and having a coercive force of not less than 400 Oe coated over the surface of said side or coated in stripes.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-12-04 1999-06-05 1999-12-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-12-04 2003-06-05 2003-12-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-12-04 2007-06-05 2007-12-05 $7700.00 Window Closed / Lapsed

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