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US5472829A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of forming a resist pattern by using an anti-reflective layer

Assignee: Sony Corp
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Filing: 1994-10-11
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Granted: 1995-12-05
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Expires: 2014-10-11
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Abstract

Abstract A method of determining an optimum condition of an anti-reflective layer upon forming a resist pattern by exposure with a monochromatic light, a method of forming the anti-reflective layer therewith and a method of forming a resist pattern using a novel anti-reflective layer obtained therewith. The optimum condition of the anti-reflective layer is determined and the anti-reflective layer is formed by the methods described below. Further, an optimal anti-reflective layer is obtained by the method which is used for forming the resist pattern. The method comprises (I) forming an equi-contour line for the amount of absorbed light regarding a photoresist of an optional film thickness using the optical condition of the anti-reflective layer as a parameter, (II) conducting the same procedure as in (I) above for a plurality of resist film thicknesses, (III) finding a common region for the amount of absorbed light with respect to each of the traces obtained, thereby determining the optical condition for the anti-reflective layer, (IV) applying same procedures as described above while changing the condition of the anti-reflective layer, thereby determining the optical condition for the anti-reflective layer, and (V) determining the optimum optical condition such as the kind and the thickness of the anti-reflective layer under a certain condition of the anti-reflective layer.

Inventors

  • 👤 Tohru Ogawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 22:21
CPC Classifications
H; H10; H10P; H10P70/00; H10P70/20; H10P70/27; H10P70/273; G; G03; G03F; G03F7/00; G03F7/004; G03F7/09; G03F7/091; G03F7/70; G03F7/70691; H10P50/00; H10P50/20; H10P50/26; H10P50/264; H10P50/266; H10P50/267; H10P50/268; H10P50/71; H10P76/00; H10P76/20; H10P76/204; H10P76/2041; H10P76/2042; H10P76/2043; H10W; H10W20/00; H10W20/01; H10W20/031; Y; Y10; Y10S; Y10S430/00; Y10S430/151

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 123 words
A method of forming a photoresist pattern, comprising the steps of: forming a first layer, forming an anti-reflective layer of Si x O y N z having a thickness d with 15 nm≦d≦150 nm on said first layer, wherein X>0, Y>0 and Z>0, forming a photoresist layer on said anti-reflective layer, exposing said photoresist selectively by a monochromatic light having a wavelength of 150-450 nm to form exposed and non-exposed imagewise areas, developing said photoresist after said exposing and removing some of the imagewise areas to uncover the layer under the photoresist layer, said anti-reflective layer having a reflective refractive index n and absorption refractive index k with 1.78≦n≦3.0 and 0.1≦k≦1.15 so that standing wave effect in said photoresist during exposing is minimized.
Claim 2
Independent Claim 123 words
A method of forming a photoresist pattern, comprising the steps of: forming a first layer, forming an anti-reflective layer of Si x O y N z having a thickness d with 15 nm≦d≦150 nm on said first layer, wherein X>0, Y>0 and Z>0, forming a photoresist layer on said anti-reflective layer, exposing said photoresist selectively by a monochromatic light having a wavelength of 150-450 nm to form exposed and non-exposed imagewise areas, developing said photoresist after said exposing and removing some of the imagewise areas to uncover the layer under the photoresist layer, said anti-reflective layer having a reflective refractive index n and absorption refractive index k with 1.78≦n≦3.0 and 0.1≦k≦1.15 so that standing wave effect in said photoresist during exposing is minimized.
Claim 3
Dependent Claim 32 words
A method according to claim 1, which includes performing a step of forming a second layer between the step of forming the anti-reflective layer and the step of forming the photoresist layer.
Claim 4
Dependent Claim 15 words
A method according to claim 2, wherein said second layer is a silicon oxide layer.
Claim 5
Dependent Claim 46 words
A method of forming a photoresist pattern according to claim 1, wherein said first layer is selected from a group consisting of a refractory metal layer, a refractory metal silicide layer, a metal layer, a metal silicide layer, a metal alloy layer, and a silicon layer.
Claim 6
Dependent Claim 59 words
A method of forming a photoresist pattern according to claim 1, wherein said first layer is selected from a group consisting of a refractory metal layer and a refractory metal silicide layer, and said anti-reflective layer has a reflection refractive index n, an absorption refractive index k and a film thickness d, wherein 1.8≦n≦3.0; 0.5≦k≦0.9; and 15 nm≦d≦35 nm.
Claim 7
Dependent Claim 25 words
A method of forming a resist pattern according to claim 5, wherein said first layer is selected from a group consisting of W, Mo--Si, W--Si.
Claim 8
Dependent Claim 61 words
A method of forming a photoresist pattern according to claim 1, wherein said first layer is selected from a group consisting of a metal layer, a metal silicide layer, and a metal alloy layer, and said anti-reflective layer has a reflection refractive index n, an absorption refractive index k and a film thickness d, wherein 1.78≦n≦2.38; 0.55≦k≦1.15; and 20 nm≦d≦40 nm.
Claim 9
Dependent Claim 27 words
A method of forming a resist pattern according to claim 7, wherein said first layer is selected from a group consisting of Al, Al--Si, Al--Si--Cu and Cu.
Claim 10
Dependent Claim 46 words
A method of forming a photoresist pattern according to claim 1, wherein said first layer is a silicon layer, and said anti-reflective layer has a reflection refractive index n, an absorption refractive index k and a film thickness d, wherein 1.8≦n≦2.6; 0.1≦k≦0.8; and 20 nm≦d≦150 nm.
Claim 11
Dependent Claim 29 words
A method of forming a resist pattern according to claim 9, wherein said silicon is selected from a group consisting of single crystal silicon, polycrystalline silicon and amorphous silicon.

References Cited (Backward Citations)

US4407927A Cited
JPH01241125A Cited
JPH02148731A Cited
US5077185A Cited

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