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US5470357A
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Method of making a laminated lithium-ion rechargeable battery cell
Assignee: Valence Technology Inc
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Filing: 1995-04-26
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Granted: 1995-11-28
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Expires: 2015-04-26
Abstract
Abstract Li-ion rechargeable battery cell electrode and electrolyte/separator elements formulated as layers of plasticized polymeric matrix compositions are laminated with electrically conductive collector elements to form a unitary battery cell structure. Adhesion between the electrode and collector elements is enhanced by pretreatment of the collector elements in which a 0.25% to 3.0% solution of a polymeric material compatible with said matrix polymer is applied to a collector foil or grid and dried to form a coated film, and the resulting coated collector element is heated within the range of about 250° to 450° C. for about 5 to 60 seconds.
Inventors
- 👤 Caroline N. Schmutz
- 👤 Frough K. Shokoohi
- 👤 Jean-Marie Tarascon
- 👤 Paul C. Warren
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 12:24
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/28; H; H01; H01M; H01M10/00; H01M10/04; H01M10/0431; H01M10/05; H01M10/052; H01M10/056; H01M10/0564; H01M10/0565; H01M50/00; H01M50/40; H01M50/409; H01M50/411; H01M50/414; H01M50/426; H01M50/489; H01M50/497; H01M6/00; H01M6/14; H01M6/18; H01M6/181; H01M6/30; H01M6/32; H01M6/42; H01M6/46; C08J2327/00; C08J2327/02; C08J2327/12; C08J2327/16; H01M2300/00; H01M2300/0085; Y; Y02; Y02E; Y02E60/00; Y02E60/10; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49108; Y10T29/49115
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
112 words
A method of making a rechargeable battery structure which comprises arranging contiguously a positive current collector element, a positive electrode element, a separator element, a negative electrode element, and a negative current collector element characterized in that a) each of said electrode and separator elements comprises a flexible, polymeric matrix film composition, b) each of said collector elements comprises a flexible electrically-conductive foil which has been surface treated with a polymeric material compatible with the matrix composition of its contiguous electrode, and c) said method further comprises bonding each said element to contiguous elements at its respective interfaces by the application of heat and pressure to form a unitary flexible laminate structure.
Claim 2
Independent Claim
112 words
A method of making a rechargeable battery structure which comprises arranging contiguously a positive current collector element, a positive electrode element, a separator element, a negative electrode element, and a negative current collector element characterized in that a) each of said electrode and separator elements comprises a flexible, polymeric matrix film composition, b) each of said collector elements comprises a flexible electrically-conductive foil which has been surface treated with a polymeric material compatible with the matrix composition of its contiguous electrode, and c) said method further comprises bonding each said element to contiguous elements at its respective interfaces by the application of heat and pressure to form a unitary flexible laminate structure.
Claim 3
Dependent Claim
44 words
A method according to claim 1 characterized in that the surface treatment of a collector element comprises: a) coating the surface of said collector element with a solution comprising about 0.25% to 3.0% of said polymeric material, and b) drying to remove the solvent.
Claim 4
Dependent Claim
32 words
A method according to claim 1 wherein the surface treatment further comprises heating the coated collector element within the range of about 250° to 450° C. for about 5 to 60 seconds.
Claim 5
Dependent Claim
53 words
A method according to claim 3 wherein at least one of said collector element foils comprises an open-mesh grid and said method further comprises respectively bonding at least one of said positive and negative collector elements to said positive and negative electrode elements prior to bonding said electrode elements to said separator element.
Claim 6
Dependent Claim
47 words
A method according to claim 3 wherein said collector element surface is coated from a solution comprising about 0.5% to 1.5% of said polymeric material and said coated collector element is heated within the range of about 300° to 350° C. for about 5 to 30 seconds.
Claim 7
Dependent Claim
40 words
A method according to claim 5 wherein said collector element surface is coated from a solution comprising about 0.5% of said polymeric material and said coated collector element is heated at about 340° C. for about 5 to 20 seconds.
Claim 8
Dependent Claim
75 words
A method according to claim 2 wherein: a) at least one of said collector element foils comprises an open-mesh grid; b) said polymeric matrix composition comprises a copolymer of vinylidene fluoride with 8% to 25% by weight hexafluoropropylene and has homogeneously distributed therein 20 to 70% by weight of an organic plasticizer compatible with said copolymer; and c) said polymeric treatment material comprises a copolymer of vinylidene fluoride with 6% to 25% by weight hexafluoropropylene.
Claim 9
Dependent Claim
53 words
A method according to claim 7 characterized in that the surface treatment of a collector element comprises: a) coating the surface of said collector element by applying thereto a solution comprising about 3.0% each of said treatment copolymer and said matrix plasticizer, and b) drying said coated collector element to remove the solvent.
References Cited (Backward Citations)
US4714665A
Cited
US5219680A
Cited
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1998-11-27 | 1999-05-29 | 1999-11-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2002-11-27 | 2003-05-29 | 2003-11-28 | $3760.00 | Window Closed / Lapsed |
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