US5449714A
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Preparation of conductive silicone rubber composition
Assignee: Shin-Etsu Chemical Co Ltd
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Filing: 1993-11-30
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Granted: 1995-09-12
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Expires: 2013-11-30
Abstract
Abstract A conductive silicone rubber composition is prepared by mixing an organopolysiloxane having an aminoalkyl radical, an organopolysiloxane having a (meth)acryloxyalkyl or glycidoxyalkyl radical, and conductive carbon black to form silicone rubber composition (A) in which the carbon black is fixed, and then mixing it with a silicone rubber composition (B) comprising a dimethylpolysiloxane. The composition has stable resistivity in the semiconductive region independent of molding conditions.
Inventors
- 👤 Yoshio Inoue
- 👤 Susumu Sekiguchi
- 👤 Masaharu Takahashi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 09:36
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08K; C08K3/00; C08K3/02; C08K3/04; C08L83/08; C08G; C08G77/00; C08G77/04; C08G77/14; C08G77/20; C08G77/22; C08G77/26; C08G77/70
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
200 words
A method for preparing a conductive silicone rubber composition comprising: mixing (A) a silicone rubber composition comprising an organopolysiloxane of the average compositional formula (1), an organopolysiloxane of the average compositional formula (2), and conductive carbon black with (B) a silicone rubber composition comprising an organopolysiloxane of the average compositional formula (3) and free of conductive carbon black, wherein the average compositional formulae are R.sub.a.sup.1 R.sub.b.sup.2 SiO.sub.(4-a-b)/2 ( 1) wherein R 1 is a substituted or unsubstituted monovalent hydrocarbon radical, up to 95 mol % of the R 1 groups being methyl radicals, R 2 is a monovalent organic radical containing a primary amine, and letters a and b are positive numbers satisfying a+b=1.98 to 2.02, R.sub.c.sup.3 R.sub.d.sup.4 SiO.sub.(4-c-d)/2 ( 2) wherein R 3 is a substituted or unsubstituted monovalent hydrocarbon radical, R 4 is a monovalent organic radical containing an α,β-unsaturated carbonyl derivative or epoxy radical, and letters c and d are positive numbers satisfying c+d=1.98 to 2.02, and R.sub.e.sup.5 SiO.sub.(4-e)/2 ( 3) wherein R 5 is a substituted or unsubstituted monovalent hydrocarbon radical, at least 98 mol % of the R 5 groups being methyl radials, and letter e is a positive number of from 1.98 to 2.02.
Claim 2
Independent Claim
200 words
A method for preparing a conductive silicone rubber composition comprising: mixing (A) a silicone rubber composition comprising an organopolysiloxane of the average compositional formula (1), an organopolysiloxane of the average compositional formula (2), and conductive carbon black with (B) a silicone rubber composition comprising an organopolysiloxane of the average compositional formula (3) and free of conductive carbon black, wherein the average compositional formulae are R.sub.a.sup.1 R.sub.b.sup.2 SiO.sub.(4-a-b)/2 ( 1) wherein R 1 is a substituted or unsubstituted monovalent hydrocarbon radical, up to 95 mol % of the R 1 groups being methyl radicals, R 2 is a monovalent organic radical containing a primary amine, and letters a and b are positive numbers satisfying a+b=1.98 to 2.02, R.sub.c.sup.3 R.sub.d.sup.4 SiO.sub.(4-c-d)/2 ( 2) wherein R 3 is a substituted or unsubstituted monovalent hydrocarbon radical, R 4 is a monovalent organic radical containing an α,β-unsaturated carbonyl derivative or epoxy radical, and letters c and d are positive numbers satisfying c+d=1.98 to 2.02, and R.sub.e.sup.5 SiO.sub.(4-e)/2 ( 3) wherein R 5 is a substituted or unsubstituted monovalent hydrocarbon radical, at least 98 mol % of the R 5 groups being methyl radials, and letter e is a positive number of from 1.98 to 2.02.
Claim 3
Dependent Claim
21 words
The method of claim 1, wherein the monovalent organic radical containing a primary amine is an aminoalkyl radical or aminoaryl radical.
Claim 4
Dependent Claim
46 words
The method of claim 1, wherein R 1 of the organopolysiloxane of formula (1) consists essentially of up to 95 mol % methyl radicals, 5 to 20 mol % phenyl radicals, 0.001 to 10 mol % vinyl radicals, and 0.1 to 20 mol % aminopropyl radicals.
Claim 5
Dependent Claim
33 words
The method of claim 1, wherein the conductive carbon black is used in an amount of 1 to 50 parts by weight per 100 parts by weight of the organopolysiloxane of formula (1).
Claim 6
Dependent Claim
43 words
The method of claim 1, wherein the monovalent organic radical containing an α,β-unsaturated carbonyl derivative or epoxy radical is present in an amount of 0.5 to 2 mol per one mol of the amino radical in the organopolysiloxane of average compositional formula (1).
Claim 7
Dependent Claim
29 words
The method of claim 1, wherein R 5 of formula (3) consists essentially of at least 98 mol % methyl radicals and 0.001 to 2 mol % vinyl radicals.
Claim 8
Dependent Claim
24 words
The method of claim 1, wherein the silicone rubber compositions (A) and (B) are mixed in a weight ratio of from 5:95 to 95:5.
Claim 9
Dependent Claim
36 words
The method of claim 5, wherein the monovalent organic radical containing an α,β-unsaturated carbonyl derivative or epoxy radical is present in an equimolar amount to the amino radical in organopolysiloxane of the average compositional formula (1).
Claim 10
Dependent Claim
48 words
The method of claim 1, wherein the conductive silicone rubber composition provides, upon curing, a cured product having an electrical resistivity in the range of 10 3 to 10 10 Ω-cm, which is stabilized such that it varies only within one order of magnitude in the cured composition.
Claim 11
Independent Claim
208 words
A method for preparing a conductive silicone rubber composition comprising: mixing an organopolysiloxane of the average compositional formula (1): R.sub.a.sup.1 R.sub.b.sup.2 SiO.sub.(4-a-b)/2 ( 1) wherein R 1 is a substituted or unsubstituted monovalent hydrocarbon radical, up to 95 mol % of the R 1 groups being methyl radicals, R 2 is a monovalent organic radical containing a primary amine, and letters a and b are positive numbers satisfying a+b=1.98 to 2.02, an organopolysiloxane of the average compositional formula (2): R.sub.c.sup.3 R.sub.d.sup.4 SiO.sub.(4-c-d)/ 2 (2) wherein R 3 is a substituted or unsubstituted monovalent hydrocarbon radical, R 4 is a monovalent organic radical containing an α,β-unsaturated carbonyl derivative or epoxy radical, and letters c and d are positive numbers satisfying c+d=1.98 to 2.02, and conductive carbon black to prepare a silicone rubber composition (A), mixing said silicone rubber composition (A) with a conductive carbon black-free silicone rubber composition (B) comprising an organopolysiloxane of the average compositional formula (3): R.sub.e.sup.5 SiO.sub.(4-e)/2 ( 3) wherein R 5 is a substituted or unsubstituted monovalent hydrocarbon radical, at least 98 mol % of the R 5 groups being methyl radicals, and letter e is positive number of from 1.98 to 2.02, and adding thereto an organic peroxide as a radical reaction crosslinking agent.
Claim 12
Independent Claim
208 words
A method for preparing a conductive silicone rubber composition comprising: mixing an organopolysiloxane of the average compositional formula (1): R.sub.a.sup.1 R.sub.b.sup.2 SiO.sub.(4-a-b)/2 ( 1) wherein R 1 is a substituted or unsubstituted monovalent hydrocarbon radical, up to 95 mol % of the R 1 groups being methyl radicals, R 2 is a monovalent organic radical containing a primary amine, and letters a and b are positive numbers satisfying a+b=1.98 to 2.02, an organopolysiloxane of the average compositional formula (2): R.sub.c.sup.3 R.sub.d.sup.4 SiO.sub.(4-c-d)/ 2 (2) wherein R 3 is a substituted or unsubstituted monovalent hydrocarbon radical, R 4 is a monovalent organic radical containing an α,β-unsaturated carbonyl derivative or epoxy radical, and letters c and d are positive numbers satisfying c+d=1.98 to 2.02, and conductive carbon black to prepare a silicone rubber composition (A), mixing said silicone rubber composition (A) with a conductive carbon black-free silicone rubber composition (B) comprising an organopolysiloxane of the average compositional formula (3): R.sub.e.sup.5 SiO.sub.(4-e)/2 ( 3) wherein R 5 is a substituted or unsubstituted monovalent hydrocarbon radical, at least 98 mol % of the R 5 groups being methyl radicals, and letter e is positive number of from 1.98 to 2.02, and adding thereto an organic peroxide as a radical reaction crosslinking agent.
Claim 13
Dependent Claim
48 words
The method of claim 10, wherein the conductive silicone rubber composition provides, upon curing, a cured product having an electrical resistivity in the range of 10 3 to 10 10 Ω-cm, which is stabilized such that it varies only within one order of magnitude in the cured composition.
References Cited (Backward Citations)
US4387046A
Cited
US5082596A
Cited
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