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US5447613A Expired / Lapsed US ⏱️ 0.0 years remaining

Preventing of via poisoning by glow discharge induced desorption

Assignee: Teledyne Digital Imaging Inc
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Filing: 1991-12-18
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Granted: 1995-09-05
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Expires: 2011-12-18
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Abstract

Abstract PCT No. PCT/CA91/00448 Sec. 371 Date Jun. 21, 1993 Sec. 102(e) Date Jun. 21, 1993 PCT Filed Dec. 18, 1991 PCT Pub. No. WO92/11653 PCT Pub. Date Jul. 9, 1992.A method of fabricating multilevel semiconductor wafers including a spin-on glass planarization layer is described. Prior to sputtering of the interconnect layer and after application of the spin-on glass layer, the wafer is exposed to an intense glow discharge in such a way that it is bombarded in at least a partial vacuum with ions and/or electrons and/or photons while at a temperature that is between 400 DEG C. and 550 DEG C. and that is at least 25 DEG C. higher than the temperature to which the wafer is to be subjected during the subsequent sputtering step. In this way undesirable molecules can be desorbed from the spin-on glass layer so that they do not interfere with the subsequent sputtering step.

Inventors

  • 👤 Luc Ouellet

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 15:25
CPC Classifications
H; H10; H10P; H10P95/00; H10P95/08

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 160 words
In a method of fabricating a multilevel semiconductor wafer having a surface that is subjected to a sputtering step at a first temperature, said wafer including a dielectric layer containing volatile components, the improvement wherein immediately prior to carrying out said sputtering step, said wafer is subjected to a desorption step wherein heat is thermally applied to the wafer in an inert ambient and at least a partial vacuum to maintain the wafer at a second temperature, said desporption step being carried out in the presence of a glow discharge at the wafer surface at an RF power density of about 0.1 to 1 Wcm -2 such that wafer is bombarded with particles selected from the group consisting of: ions, electrons, and photons; so as to desorb said volatile components with the aid of heat and said glow discharge, and said second temperature being between 400° C. and 550° C. and at least 25° C. higher than said first temperature.
Claim 2
Dependent Claim 160 words
In a method of fabricating a multilevel semiconductor wafer having a surface that is subjected to a sputtering step at a first temperature, said wafer including a dielectric layer containing volatile components, the improvement wherein immediately prior to carrying out said sputtering step, said wafer is subjected to a desorption step wherein heat is thermally applied to the wafer in an inert ambient and at least a partial vacuum to maintain the wafer at a second temperature, said desporption step being carried out in the presence of a glow discharge at the wafer surface at an RF power density of about 0.1 to 1 Wcm -2 such that wafer is bombarded with particles selected from the group consisting of: ions, electrons, and photons; so as to desorb said volatile components with the aid of heat and said glow discharge, and said second temperature being between 400° C. and 550° C. and at least 25° C. higher than said first temperature.
Claim 3
Dependent Claim 20 words
The method of fabricating multilevel semiconductor wafers of claim 1, wherein said dielectric layer comprises a spin-on glass planarization layer.
Claim 4
Dependent Claim 31 words
The method of claim 2, wherein said glow discharge occurs in a magnetic field arranged to intensify the discharge near the wafer and maximize the particle densities at the wafer surface.
Claim 5
Dependent Claim 21 words
The method of claim 1, wherein a RF power frequency of about 13 Mhz is used to create the glow discharge.
Claim 6
Dependent Claim 54 words
The method of claim 1, wherein said wafer is placed over a back side hot plate supplying heat thereto, and the glow discharge occurs in argon, the wafer back side pressure being between about 0.27 to 27 dyn cm -2 so as to provide efficient heat transfer between the wafer and the hot plate.
Claim 7
Dependent Claim 47 words
The method of claim 1, wherein the wafer fabrication occurs in a cluster tool having separate vacuum chambers, the glow discharge desorption takes place in a preparation chamber dedicated to said desorption step, and after desorption the wafer is directly transferred to a sputtering chamber under vacuum.
Claim 8
Dependent Claim 29 words
The method of claim 1, wherein the wafers are brought to said second temperature in less than 60 seconds and exposed thereto in equilibrium for at least 120 seconds.
Claim 9
Dependent Claim 27 words
The method of claim 9, wherein said glow discharge occurs under a pressure of about 0.13 to 27 dyn cm -2 of argon in the preparation chamber.
Claim 10
Dependent Claim 30 words
The method of claim 1, wherein only one wafer is subjected to glow discharge desorption at a time so as to permit precise control over temperature and glow discharge parameters.
Claim 11
Dependent Claim 16 words
The method of claim 1, wherein the overall desorption time is less than about 200 seconds.
Claim 12
Dependent Claim 15 words
The method of claim 1, wherein the spin-on glass is phosphorus alloyed inorganic spin-on glass.

References Cited (Backward Citations)

US3661747A Cited
US4909314A Cited
US4722298A Cited
US4731293A Cited
US4816638A Cited

USPTO Annuity & Maintenance Windows

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