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US5443935A
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Electrophotographic photoreceptor
Assignee: Mitsubishi Chemical Corp
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Filing: 1993-04-30
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Granted: 1995-08-22
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Expires: 2013-04-30
Abstract
Abstract An electrophotographic photoreceptor comprising a conductive substrate having thereon a photosensitive layer comprising a binder resin having dispersed therein a phthalocyanine composition is disclosed, in which said binder resin is a curing fluorine resin, and said phthalocyanine composition comprises (A) an unsubstituted phthalocyanine compound and (B) a phthalocyanine derivative having a halogen atom(s) and/or electron attractive group(s) at the benzene nuclei, such that the ratio of the number of the halogen atom(s) and/or electron attractive group(s) to the total number of the phthalocyanine units in (A) and (B) is from 0.001 to 0.5. The photoreceptor has a low threshold value of photosensitive characteristics and exhibits high sensitivity in a digital behavior. Besides applicable to a digital recording system, the photoreceptor, when applied to a conventional PPC system, provides a sharp-edged high quality image.
Inventors
- 👤 Takashi Kojima
- 👤 Shinichi Suzuki
- 👤 Yasuyuki Shigematsu
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 16:31
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0664; G03G5/0696; G03G5/05; G03G5/0528; G03G5/0532; G03G5/0539; G03G5/0546; G03G5/0589; G03G5/0592
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
249 words
An electrophotographic photoreceptor comprising a conductive substrate having thereon a photosensitive layer comprising a binder resin having dispersed therein a phthalocyanine composition, in which said binder resin is a curable fluorine resin comprising a copolymer of a fluorinated ethylenically unsaturated monomer selected from the group consisting of fluorine-containing olefins, fluorinated alkyl vinyl ethers and fluorinated fatty acid vinyl esters with an ethylenically unsaturated monomer containing no fluorine atoms, and said phthalocyanine composition comprises (A) an unsubstituted phthalocyanine compound represented by formula (Ia) or (Ib): ##STR3## wherein M represents ah atom or compound residue capable of covalent bonding or coordinate bonding to the phthalocyanine ring, and (B) a phthalocyanine derivative represented by formula (IIa) or (IIb): ##STR4## wherein M is as defined above; and R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 , and R 16 , which may be the same or different, each represent a hydrogen atom, a halogen atom or an electron attractive group, provided that at least one of them represents a halogen atom or an electron attractive group, with the proviso that the ratio of the number of the halogen atom(s) and/or electron attractive group(s) to the total number of the phthalocyanine units in said unsubstituted phthalocyanine compound (A) and said phthalocyanine derivative (B) is from 0.001 to 0.5.
Claim 2
Dependent Claim
249 words
An electrophotographic photoreceptor comprising a conductive substrate having thereon a photosensitive layer comprising a binder resin having dispersed therein a phthalocyanine composition, in which said binder resin is a curable fluorine resin comprising a copolymer of a fluorinated ethylenically unsaturated monomer selected from the group consisting of fluorine-containing olefins, fluorinated alkyl vinyl ethers and fluorinated fatty acid vinyl esters with an ethylenically unsaturated monomer containing no fluorine atoms, and said phthalocyanine composition comprises (A) an unsubstituted phthalocyanine compound represented by formula (Ia) or (Ib): ##STR3## wherein M represents ah atom or compound residue capable of covalent bonding or coordinate bonding to the phthalocyanine ring, and (B) a phthalocyanine derivative represented by formula (IIa) or (IIb): ##STR4## wherein M is as defined above; and R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 , and R 16 , which may be the same or different, each represent a hydrogen atom, a halogen atom or an electron attractive group, provided that at least one of them represents a halogen atom or an electron attractive group, with the proviso that the ratio of the number of the halogen atom(s) and/or electron attractive group(s) to the total number of the phthalocyanine units in said unsubstituted phthalocyanine compound (A) and said phthalocyanine derivative (B) is from 0.001 to 0.5.
Claim 3
Dependent Claim
25 words
An electrophotographic photoreceptor as claimed in claim 1, wherein a weight ratio of said phthalocyanine composition to said binder resin is from 5:95 to 50:50.
Claim 4
Dependent Claim
41 words
An electrophotographic photoreceptor as claimed in claim 1, wherein said halogen atom or electron attractive group in said phthalocyanine derivative (B) is a chlorine atom, a bromine atom, a nitro group, a cyano group, a carboxyl group or a sulfo group.
Claim 5
Dependent Claim
44 words
An electrophotographic photoreceptor as claimed in claim 1, wherein said phthalocyanine composition comprises 100 parts by weight of said unsubstituted phthalocyanine compound and from 0.001 to 8 parts by weight of the phthalocyanine derivative having 1 to 6 halogen atom(s) and/or electron attractive group(s).
Claim 6
Dependent Claim
65 words
An electrophotographic photoreceptor as claimed in claim 1, wherein said phthalocyanine composition comprises 100 parts by weight of said unsubstituted phthalocyanine compound, from 0.001 to 3 parts by weight of the phthalocyanine derivative having 1 to 3 halogen atom(s) and/or electron attractive group(s), and from 0.01 to 8 parts by weight of the phthalocyanine derivative having 4 to 6 halogen atom(s) and/or electron attractive group(s).
Claim 7
Dependent Claim
43 words
An electrophotographic photoreceptor as claimed in claim 1, wherein said phthalocyanine composition is a composition obtained by dissolving the unsubstituted phthalocyanine compound and the phthalocyanine derivative in an organic or inorganic acid and adding a poor solvent to the solution to cause precipitation.
Claim 8
Dependent Claim
15 words
An electrophotographic photoreceptor as claimed in claim 6, wherein said acid is an organic acid.
Claim 9
Dependent Claim
33 words
An electrophotographic photoreceptor as claimed in claim 1, wherein said curable fluorine resin is a copolymer comprising from 25 to 75 mol % of a unit derived from said fluorinated ethylenically unsaturated monomer.
Claim 10
Dependent Claim
57 words
An electrophotographic photoreceptor as claimed in claim 1, wherein said ethylenically unsaturated monomer containing no fluorine atom has a group selected from the group consisting of a hydroxyl group, a carboxyl group, an acid anhydride group, an ester group, an amino group, a glycidyl group and a group into which any of these groups can be introduced.
Claim 11
Dependent Claim
30 words
An electrophotographic photoreceptor as claimed in claim 1, wherein M in formula (I) or (II) is selected from the group consisting of a hydrogen atom, Cu, Mg, VO and TiO.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1998-08-21 | 1999-02-20 | 1999-08-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2002-08-21 | 2003-02-20 | 2003-08-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2006-08-21 | 2007-02-20 | 2007-08-22 | $7700.00 | Window Closed / Lapsed |