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US5439574A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for successive formation of thin films

Assignee: Canon Anelva Corp
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Filing: 1994-07-19
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Granted: 1995-08-08
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Expires: 2014-07-19
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Abstract

Abstract The present invention provides a method for forming thin films successively by magnetron sputtering, a method achieving uniform thickness distribution of each film on a substrate by varying the composition of process gas with the vacuum chamber and a structural configuration therein kept unchanged. In the magnetron sputtering wherein thin films composed of particles sputtered out of the target [2] are deposited on a substrate surface with plasma maintained by applying perpendicularly intersecting electric and magnetic fields in the space defined between the target and substrate and by introducing process gas into the chamber, the magnetic flux density is varied with the composition ratio of process gas introduced into the vacuum chamber [1] by attaching magnetic field generators [3], [14]: for applying the magnetic field so that the magnetic flux density in the electrode space is adjustable.

Inventors

  • 👤 Masahiko Kobayashi
  • 👤 Nobuyuki Takahashi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 12:13
CPC Classifications
C; C23; C23C; C23C14/00; C23C14/22; C23C14/54; C23C14/548; C23C14/34; C23C14/3407; C23C14/35; C23C14/351; H; H01; H01J; H01J37/00; H01J37/32; H01J37/32431; H01J37/3266; H01J37/34; H01J37/3402; H01J37/3405

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 364 words
A method for successive deposition of at least two thin films of different materials in a metallization process in manufacturing a semiconductor device, comprising the following steps: (a) depositing on a substrate a first thin film comprised of particles sputtered out of a target by: (1) establishing in a system a plasma by creating mutually perpendicular electric and magnetic fields in a space between the target and the substrate; (2) introducing into the system a first process gas; and (3) applying an additional magnetic field of a first level with a variable electromagnet arranged on a side of the substrate opposite the target, the additional magnetic field being constant and extending through the substrate and is uniformly distributed over a surface of the substrate to produce a first magnetic flux density such that said first thin film is deposited at a uniform thickness on said substrate; (b) depositing on the first thin film a second thin film formed of at least two elements resulting from particles sputtered out of the target reacting with particles of a gas molecule in a second process gas comprising at least two different gases by: (1) establishing in the system a plasma by creating perpendicular electric and magnetic fields in the space between the target and the substrate; (2) introducing the second process gas into the system; and (3) adjusting the variable electromagnet to apply an additional magnetic field of a second level with the variable electromagnet, the additional magnetic field being constant and extending through the substrate and is uniformly distributed over a surface of the substrate to produce a second magnetic flux density such that said second thin film is deposited at a uniform thickness on the first thin film; wherein: (i) process (a) and process (b) are conducted in a continuous sequence; (ii) a distance between the target and the substrate is maintained fixed throughout process (a) and process (b); (iii) the magnetic field is maintained perpendicular to the electric field during both process (a) and process (b); and (iv) the magnetic flux density set during process (a) differs from that set during process (b) by varying the magnetic flux density of the additional magnetic field.
Claim 2
Independent Claim 364 words
A method for successive deposition of at least two thin films of different materials in a metallization process in manufacturing a semiconductor device, comprising the following steps: (a) depositing on a substrate a first thin film comprised of particles sputtered out of a target by: (1) establishing in a system a plasma by creating mutually perpendicular electric and magnetic fields in a space between the target and the substrate; (2) introducing into the system a first process gas; and (3) applying an additional magnetic field of a first level with a variable electromagnet arranged on a side of the substrate opposite the target, the additional magnetic field being constant and extending through the substrate and is uniformly distributed over a surface of the substrate to produce a first magnetic flux density such that said first thin film is deposited at a uniform thickness on said substrate; (b) depositing on the first thin film a second thin film formed of at least two elements resulting from particles sputtered out of the target reacting with particles of a gas molecule in a second process gas comprising at least two different gases by: (1) establishing in the system a plasma by creating perpendicular electric and magnetic fields in the space between the target and the substrate; (2) introducing the second process gas into the system; and (3) adjusting the variable electromagnet to apply an additional magnetic field of a second level with the variable electromagnet, the additional magnetic field being constant and extending through the substrate and is uniformly distributed over a surface of the substrate to produce a second magnetic flux density such that said second thin film is deposited at a uniform thickness on the first thin film; wherein: (i) process (a) and process (b) are conducted in a continuous sequence; (ii) a distance between the target and the substrate is maintained fixed throughout process (a) and process (b); (iii) the magnetic field is maintained perpendicular to the electric field during both process (a) and process (b); and (iv) the magnetic flux density set during process (a) differs from that set during process (b) by varying the magnetic flux density of the additional magnetic field.
Claim 3
Dependent Claim 75 words
The method according to claim 1, wherein: the steps of creating the magnetic field perpendicular to the electric field include positioning a permanent magnet on a backside of the target, the additional magnetic field applied to vary the magnetic flux density in each system is created by an electromagnet positioned on a backside of the substrate, and the magnetic flux density in the system is varied by varying an excitation current flow of the electromagnet.
Claim 4
Dependent Claim 28 words
The method according to claim 2, further comprising the step of selecting an outer diameter of the electromagnet that is substantially equal to a diameter of the substrate.
Claim 5
Dependent Claim 22 words
The method according to claim 1, wherein the first process gas is one of the two gases in the second process gas.
Claim 6
Dependent Claim 27 words
The method according to claim 4, wherein the magnetic flux density in the system is varied in proportion to a compositional variation of the second process gas.
Claim 7
Dependent Claim 29 words
The method according to claim 5, wherein the first process gas consists of argon gas and the second process gas comprises equal amounts of argon gas and nitrogen gas.
Claim 8
Dependent Claim 13 words
The method according to claim 6, wherein process (b) follows after process (a).
Claim 9
Dependent Claim 28 words
The method according to claim 7, wherein the target is made of titanium metal, the first thin film is titanium, and the second thin film is titanium nitride.
Claim 10
Dependent Claim 38 words
The method according to claim 8, wherein the excitation current applied to create the additional magnetic field during process ( a ) is larger than the excitation current applied to create the additional magnetic field during process (b).
Claim 11
Dependent Claim 28 words
The method according to claim 9, wherein an input power to the target during process (a) is different from the input power to the target during process (b).
Claim 12
Dependent Claim 25 words
The method according to claim 10, wherein the input power to the target during process (b) is higher than the input power in process (a).
Claim 13
Dependent Claim 76 words
The method according to claim 11, wherein the substrate is a semiconductor wafer eight inches in diameter, and process (a) and process (b) are carried out under the following conditions: ______________________________________ Ti film TiN film ______________________________________ Target-substance distance 60 mm Target diameter 14 inches Magnetic flux density Average 160 Average 40 Gauss Gauss Process gas and flow rate Ar 40 sccm Ar 30 sccm N.sub.2 30 sccm Input power to the target 4 kW 6kW ______________________________________
Claim 14
Independent Claim 244 words
A method of forming successive deposition layers of at least two thin films on a substrate by sputtering particles from a target, comprising the steps of: providing the target in a vacuum chamber; establishing a plasma in a space in the vacuum chamber between the target and the substrate by creating electric and magnetic fields in the space; depositing a first thin film layer on the substrate while: introducing into the vacuum chamber a first process gas; and applying a first additional magnetic field of a first level with a variable electromagnet arranged on a side of the substrate opposite the target, the additional magnetic field being constant and extending through the substrate and is uniformly distributed over a surface of the substrate such that said first thin film is deposited at a uniform thickness on said substrate; and depositing, in continuous succession with depositing the first thin film, a second thin film layer on the first thin film while: introducing into the vacuum chamber a second process gas; and applying a second additional magnetic field of a second level with the variable electromagnet, the additional magnetic field being constant and extending through the substrate and is uniformly distributed over a surface of the substrate such that said second thin film is deposited at a uniform thickness on the first thin film; wherein a distance between the target and the substrate is maintained fixed throughout the deposition of both the first and second layers.
Claim 15
Independent Claim 244 words
A method of forming successive deposition layers of at least two thin films on a substrate by sputtering particles from a target, comprising the steps of: providing the target in a vacuum chamber; establishing a plasma in a space in the vacuum chamber between the target and the substrate by creating electric and magnetic fields in the space; depositing a first thin film layer on the substrate while: introducing into the vacuum chamber a first process gas; and applying a first additional magnetic field of a first level with a variable electromagnet arranged on a side of the substrate opposite the target, the additional magnetic field being constant and extending through the substrate and is uniformly distributed over a surface of the substrate such that said first thin film is deposited at a uniform thickness on said substrate; and depositing, in continuous succession with depositing the first thin film, a second thin film layer on the first thin film while: introducing into the vacuum chamber a second process gas; and applying a second additional magnetic field of a second level with the variable electromagnet, the additional magnetic field being constant and extending through the substrate and is uniformly distributed over a surface of the substrate such that said second thin film is deposited at a uniform thickness on the first thin film; wherein a distance between the target and the substrate is maintained fixed throughout the deposition of both the first and second layers.
Claim 16
Dependent Claim 39 words
The method according to claim 13, wherein an input power to the target during the deposition of the first thin film layer is different from the input power to the target during the deposition of the second thin film.
Claim 17
Dependent Claim 39 words
The method according to claim 13, wherein an input power to the target during the deposition of the first thin film layer is lower than the input power to the target during the deposition of the second thin film.
Claim 18
Dependent Claim 20 words
The method according to claim 15, wherein the first additional magnetic field is stronger than the second additional magnetic field.
Claim 19
Dependent Claim 26 words
The method according to claim 16, wherein the first process gas consists of argon gas and the second process gas comprises argon gas and nitrogen gas.
Claim 20
Dependent Claim 20 words
The method of claim 16, wherein the first thin film is titanium and the second thin film is titanium nitride.
Claim 21
Dependent Claim 20 words
The method of claim 15, wherein the first thin film is titanium and the second thin film is titanium nitride.
Claim 22
Dependent Claim 20 words
The method according to claim 13, wherein the first additional magnetic field is stronger than the second additional magnetic field.
Claim 23
Dependent Claim 26 words
The method according to claim 20, wherein the first process gas consists of argon gas and the second process gas comprises argon gas and nitrogen gas.
Claim 24
Dependent Claim 20 words
The method of claim 20, wherein the first thin film is titanium and the second thin film is titanium nitride.
Claim 25
Independent Claim 232 words
A system for depositing thin films on a substrate, comprising: a vacuum chamber; a cathode assembly within said vacuum chamber, said cathode assembly including a target and a magnet; a power source connected to said cathode assembly; a substrate holder; a substrate attached to said substrate holder; an electromagnet within said substrate holder such that the substrate is positioned between the target and the electromagnet; a variable DC power source connected to said electromagnet; means for supplying at least two different process gases to said vacuum chamber; and control means for controlling said supplying means and said variable DC power source so that during a first deposition process a first process gas is introduced to the vacuum chamber and the electromagnet operates at a first power to produce an additional magnetic field that is constant and which extends through the substrate and is uniformly distributed over a surface of the substrate such that a first thin film is deposited at a uniform thickness on said substrate and during a second deposition process a second process gas is introduced into the vacuum chamber and the electromagnet operates at a second power to produce an additional magnetic field that is constant and which extends through the substrate and is uniformly distributed over a surface of the substrate such that a second thin film is deposited at a uniform thickness on the first thin film.
Claim 26
Independent Claim 232 words
A system for depositing thin films on a substrate, comprising: a vacuum chamber; a cathode assembly within said vacuum chamber, said cathode assembly including a target and a magnet; a power source connected to said cathode assembly; a substrate holder; a substrate attached to said substrate holder; an electromagnet within said substrate holder such that the substrate is positioned between the target and the electromagnet; a variable DC power source connected to said electromagnet; means for supplying at least two different process gases to said vacuum chamber; and control means for controlling said supplying means and said variable DC power source so that during a first deposition process a first process gas is introduced to the vacuum chamber and the electromagnet operates at a first power to produce an additional magnetic field that is constant and which extends through the substrate and is uniformly distributed over a surface of the substrate such that a first thin film is deposited at a uniform thickness on said substrate and during a second deposition process a second process gas is introduced into the vacuum chamber and the electromagnet operates at a second power to produce an additional magnetic field that is constant and which extends through the substrate and is uniformly distributed over a surface of the substrate such that a second thin film is deposited at a uniform thickness on the first thin film.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-08-07 1999-02-06 1999-08-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-08-07 2003-02-06 2003-08-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-08-07 2007-02-06 2007-08-08 $7700.00 Window Closed / Lapsed

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